| 光谱学与光谱分析 |
|
|
|
|
|
| Study on Adsorption and Desorption Characteristics of Cd2+ and Cu2+ on the Surface Sediments of Sanhuhekou of Yellow River by Using ICP-MS |
| ZUO Hang1,3, CHEN Yi-zhen1, CHEN Jian-hua1, GUO Yang1, WANG Ru-ming1, FANG Fang1, ZHAO Jia-ying1, LIU Ying1,2* |
1. College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
2. Beijing Engineering Research Center of Food Environment and Public Health, Minzu University of China, Beijing 100081, China
3. China National Environmental Monitoring Centre, Beijing 100012, China |
|
|
|
|
Abstract In order to study the interaction mechanism between Cd2+, Cu2+ and surface sediments in the upper reaches of the Yellow River, the surface sediment of Sanhuhekou (YRSSM) was chosen as research object with inductively coupled plasma mass spectrometry (ICP-MS) as analysis method. The adsorption reaction condition such as liquid-solid ratio, reaction time and pH were optimized, and the adsorption and desorption characteristics of Cd2+ and Cu2+ onto the surface sediments under the optimized experimental conditions were studied. The results showed that the adsorption capacity of Cu2+ was greater than that of Cd2+, the equilibrium absorption capacity were 0.88 and 0.13 mg·g-1 under each optimum experimental condition, respectively. The adsorptions of Cu2+ and Cd2+ were in accord with the pseudo-second-order kinetic, while adsorption rate of Cu2+ was also greater than that of Cd2+. The adsorption thermodynamics data were in accordance with the Freundlich model and the fitting. Results showed that the adsorption process of Cu2+ and Cd2+ belonged to the preferential adsorption, and were endothermic and spontaneous processes. The desorption process showed that the Elovich equation were suitable for Cd2+ and Cu2+ and belonged to the heterogeneous diffusion. Multi-ions competitive adsorption and desorption experiments indicated that Cu2+ was influenced more by co-existing ion. The study revealed not only the mechanism of adsorption and desorption between Cd2+, Cu2+ and surface sediment in Sanhuhekou, but also the influence of coexisting ions on the adsorption and desorption characteristics. The results demonstrated that the distribution mechanism of heavy metals between solid-liquid phases, and provided a theoretical basis for the migration ability of heavy metals. It also had a guiding significance for establishing heavy metals preventive and control measures of the study area.
|
|
Received: 2016-07-13
Accepted: 2016-11-15
|
|
|
|
Corresponding Authors:
LIU Ying
E-mail: liuying4300@163.com
|
|
[1] MA Xiao-ling, LIU Jing-jun, ZUO Hang, et al(马小玲, 刘菁钧, 左 航, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2015, 35(4): 1062.
[2] Guan Q Y, Wang L, Pan B T, et al. Chemosphere，2016, 144: 29.
[3] SHEN Xian-chen, FENG Hui-hua, WANG Feng-rong, et al(申献辰, 冯惠华, 王凤荣, 等). Journal of Water Conservancy(水利学报), 1997, 11: 49.
[4] ZHAO Rong, NI Jin-ren, SUN Wei-ling，et al(赵 蓉, 倪晋仁, 孙卫玲, 等). Acta Scientiae Circumstantiae (环境科学学报), 2003, 23(4): 441.
[5] WANG Xiao-li, BAO Hua-ying, GUO Bo-shu(王晓丽，包华影，郭博书). Environmental Science(环境科学), 2009, 30(3): 720.
[6] XIA Xing-hui, ZHANG Jun, SHA Yu-juan(夏星辉，张 菊，沙玉娟). Environmental Science(环境科学), 2010, 31(4): 969.
[7] Wang J, Zhang P, Yang L, et al. Chinese Journal of Chemical Engineering, 2015, 23(9): 1542.
[8] Alexandre T P, Laurence T B, Lauro T K, et al. Desalination, 2011, 275 (2): 187.
[9] Saeedreza H, Amity G Zimmer-Fausta, Aislinn D, et al. Environ. Pollut.，2016, 215: 290.
[10] TANG Hai, LIU Gui-zhong, YAN You-bin(唐 海, 刘桂中, 颜酉斌). Chinese Journal of Environmental Engineering(环境工程学报), 2012, 6(4): 1245.
[11] Mehwish M, Haq N B, Munawar I. Journal of Environmental Management，2016, 176: 21.
[12] Shariatmadari H, Shirvani M, Jafari A. Geoderma, 2006, 132: 261. |
| [1] |
LIU Yu-ying1, 2, WANG Xi-yuan1, 2*, MEI Ao-xue1, 2. Green Preparation of Biomass Carbon Quantum Dots for Detection of Cu2+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 248-253. |
| [2] |
CHEN Shuo-ran, HUANG Su-qin, HAN Peng-ju*, YE Chang-qing, SONG Sa-sa, WANG Xiao-mei*. Preparation of 9,10-Diphenylanthracene Derivative and Its Detection for Cu2+ by Up/Down-Conversion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(12): 3769-3775. |
| [3] |
GUO Chen-hui1, LIU Ying1, 2*. A Comparative Study on the Accumulated Degree and Exchange Ability of Phosphorus in Surface Sediments from Gansu, Ningxia and Inner Mongolia Sections of the Yellow River in Different Water Periods by Using Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1586-1592. |
| [4] |
FANG Fang1, JI Yu-shan1, BAI Na1, LI Xiang1, LIU Ying1, 2*. Study on Adsorption and Desorption Characteristics of Cd2+ and Zn2+ on the Surface Sediments of Taihu Lake by Using ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1889-1895. |
| [5] |
JI Yu-shan1, FANG Fang1, WANG Hui-bin1, MA Xiao-yan1, LIU Ying1,2*. Distribution of Phosphorus Fractions and Kinetics Characteristics in Surface Sediments of Taihu Lake by Using Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1508-1513. |
| [6] |
FANG Fang1, JI Yu-shan1, LI Xiang1, BAI Na1, LIU Ying1,2*. Assessment of Pollution and Heavy Metals in Filtered Water and Surface Sediments of Taihu Lake by Using ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1245-1250. |
| [7] |
GUO Hui1,2, YANG Ke-ming1*, ZHANG Wen-wen1, LIU Cong1, XIA Tian1. Spectra Recognition of Corn Pollution Degree under Copper and Lead Ion Stress[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 212-217. |
| [8] |
GUO Chen-hui1, LI He-xiang1, FANG Fang1, JI Yu-shan1, XING Yun-xin1, FAN Yi-bing1, LIU Ying1,2*. Study on Distribution of Phosphorus Fractions and Adsorption-Desorption Characteristics in Surface Sediments of the Yellow River by Molybdenum Antimony Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 218-223. |
| [9] |
ZHOU Gao2, FENG Feng1, 2*, CHEN Ze-zhong1, BAI Yun-feng1, CAI Hu2, GUO Fang-fang1, LI Rong2, HAN Wen-qiang2. Synthesis of a Novel Fluorescent Probe and Its Application for Selectively Identifing Cu2+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2799-2803. |
| [10] |
TIAN Meng-jing1, JIA Jia1, QIAO Yu1, WU Ting-yan1, LI He-xiang1, LIU Ying1, 2*. Study on Adsorption and Desorption Characteristics of Pb(Ⅱ) and Cr(Ⅵ) onto the Surface Sediments of Hequ Section of the Yellow River with ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1902-1907. |
| [11] |
MA Xiao-ling1, DENG Feng-yu1, LIU Ying1,2* . Study on Spatial Distribution and Seasonal Variations of Trace Metal Contamination in Sediments from the Three Adjacent Areas of the Yellow River Using HR-ICP-MS [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2705-2711. |
| [12] |
HU Xiao-jun, ZHANG Zhi . The Preparation and Properties Study of Micellar Thiacalixarenes Self-Assembled Fluorescent Chemosensor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 567-570. |
| [13] |
MA Xiao-ling1, LIU Jing-jun1,3, ZUO Hang1,4, HUANG Fang1, LIU Ying1, 2* . Study on Speciation Analysis and Ecological Risk Assessment of Heavy Metals in Surface Sediments in Gansu, Ningxia and Inner Mongolia Sections of the Yellow River in Wet Season with HR-ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 1062-1067. |
| [14] |
LIU Jing-jun, LAI Zi-juan, LIU Ying* . Study on Speciation and Fractionation of Rare Earth Elements in Surface Sediments in Gansu, Ningxia and Inner Mongolia Sections of Yellow River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(03): 798-803. |
| [15] |
WANG Sheng-mian1, 2, WU Meng1, LIANG Ai-hui1*, JIANG Zhi-liang1* . DNAzyme Cracking-Nanogold Resonance Rayleigh Scattering Spectral Method for the Determination of Trace Cu2+ [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(01): 147-150. |
|
|
|
|
