光谱学与光谱分析 |
|
|
|
|
|
Application of Fluorescence Spectra and Matrix Analysis in the Classification of Edible Vegetable Oils |
WU Xi-jun1, TIAN Rui-ling2, SUN Meng-fei1, PAN Zhao1 |
1. Measurement Technology and Instrumentation Key Lab of Hebei Province, Yanshan University, Qinghuangdao 066004, China 2. School of Science, Yanshan University, Qinhuangdao 066004, China |
|
|
Abstract The fluorescence spectra of 42 vegetable oil samples are measured with FS920 fluorescence spectrometer, including 36 pure vegetable oil samples, 3 blend oil samples and 3 mixed oil samples. The fluorescence matrixs (EEMs) are normalized to determine representative excitation wavelength and matrix analysis model of vegetable oils. Vegetable oils are divided into three categories by analyzing representative emission spectra and contour maps in the range of emission wavelength from 260 to 750 nm, and excitation wavelengths from 250 to 550 nm. Applying matrix analysis model to identify pure vegetable oils, blend oils and mixed oils, the correct classification rate is 100% for pure vegetable oils, the composition is close to actual for mixed oils, and the conclusion of soybean and rapeseed oil as base for blend oils is reached. The results demonstrate the capability of the combination of fluorescence spectra technology and matrix analysis model for differentiating and characterizing vegetable oils.
|
Received: 2015-06-07
Accepted: 2015-10-10
|
|
Corresponding Authors:
WU Xi-jun
E-mail: WUXijun@ysu.edu.cn
|
|
[1] CHEN Hua-cai, WANG Zhi-lan, LIU Fu-li(陈华才, 王志岚, 刘福莉). Journal of the Chinese Cereals and Oils Association(中国粮油学报), 2008, 23(5): 180. [2] BI Yan-lan, REN Xiao-na, PENG Dan, et al(毕艳兰, 任小娜, 彭 丹, 等). Chinese Journal of Analytical Chemistry(分析化学). 2013, 41(9): 1366. [3] HUANGFU Zhi-peng, XUE Ya-lin, LIU Yuan-fa, et al(皇甫志鹏, 薛雅琳, 刘元法, 等). Journal of the Chinese Cereals and Oils Association(中国粮油学报), 2013, 28(2): 117. [4] ZENG Dong-dong, QI Yu-tang, GONG Ren, et al(曾冬冬, 齐玉堂, 龚 任, 等). China Oils and Fats(中国油脂) , 2013, 38(7): 16. [5] WANG Ying-hui, LIU Yu-lan, LI Shi-jun(王莹辉, 刘玉兰, 李时军). China Oils and Fats(中国油脂), 2013, 38(12): 28. [6] John H Kalivas, Constantinos A Georgiou, Marianna Moira, et al. Food Chemistry, 2014, 148: 289. [7] Francis Alarcón, María E Báez, Manuel Bravo, et al. Talanta, 2013, 103: 361. [8] Wang Jianyao, Wu Hailong, Sun Yanmei, et al. Journal of Chromatography B, 2014, 947-948: 32. [9] QIU Ru-bin, ZHANG Ru-ping, LIN Shui-dong, et al(邱如斌, 章汝平, 林水东, 等). Chinese Journal of Spectroscopy Laboratory(光谱实验室), 2011, 28(2): 777. [10] LI Bin, ZHANG Tao, JIA Er-hui(李 彬, 张 涛, 贾二惠). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2015, 35(2): 429.
|
[1] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
[2] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
[3] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[4] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
[5] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
[6] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
[7] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2,WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
[8] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[9] |
SHEN Ying, WU Pan, HUANG Feng*, GUO Cui-xia. Identification of Species and Concentration Measurement of Microalgae Based on Hyperspectral Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3629-3636. |
[10] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
[11] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
[12] |
SUN Cheng-yu1, JIAO Long1*, YAN Na-ying1, YAN Chun-hua1, QU Le2, ZHANG Sheng-rui3, MA Ling1. Identification of Salvia Miltiorrhiza From Different Origins by Laser
Induced Breakdown Spectroscopy Combined with Artificial Neural
Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3098-3104. |
[13] |
ZHAO Ling-yi1, 2, YANG Xi3, WEI Yi4, YANG Rui-qin1, 2*, ZHAO Qian4, ZHANG Hong-wen4, CAI Wei-ping4. SERS Detection and Efficient Identification of Heroin and Its Metabolites Based on Au/SiO2 Composite Nanosphere Array[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3150-3157. |
[14] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
[15] |
LUAN Xin-xin1, ZHAI Chen2, AN Huan-jiong3, QIAN Cheng-jing2, SHI Xiao-mei2, WANG Wen-xiu3, HU Li-ming1*. Applications of Molecular Spectral Information Fusion to Distinguish the Rice From Different Growing Regions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2818-2824. |
|
|
|
|