| 光谱学与光谱分析 |
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| Determination of Se in Blood and Tissue of Animal Samples by Normal ICP-MS and ICP-MS with Octupole Reaction System |
| WANG Ying-feng1,LIU Cui-mei1,LIU Shao-qing1,SHI Yan-zhi1*,CHEN Yu-hong2 |
1. The Analysis Test Center，Capital Normal University，Beijing 100048，China
2. Agilent Technologies Co.Ltd.，Beijing 100022，China |
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Abstract The Se in the blood and tissue of animal samples was determined by ICP-MS instrument. The method was not only proved simple and rapid, but also showed satisfying precision and low detection limit. The optimum conditions of ICP-MS for the method were investigated. Results by the digestion method, the isotopes selection, and the difference between the normal ICP-MS without ORS (Octopole Reaction System) and the ICP-MS with ORS were compared, which afford reference to the determination of the same kinds of sample. The standard materials were determined to proved the reliability of the normal ICP-MS and the ORS-ICP-MS methods. The ORS-ICP-MS can effectively remove the interference based on polyatomic ions, so the the detection limits were lowed, and the accuracy was improved. The detection limits of the method for normal ICP-MS is 0.024 ng·g-1 and that for ORS-ICP-MS is 0.004 6 ng·g-1, the RSDs are between 1.8% and 5.5%, and the recoveries of the method are in the range of 90.8%-107.2%.
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Received: 2007-05-06
Accepted: 2007-08-20
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Corresponding Authors:
SHI Yan-zhi
E-mail: bjshifa@sohu.com
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