| 光谱学与光谱分析 |
|
|
|
|
|
| Quantitative Analysis of Alloy Steel Based on Laser Induced Breakdown Spectroscopy with Partial Least Squares Method |
| CONG Zhi-bo, SUN Lan-xiang*, XIN Yong, LI Yang, QI Li-feng, YANG Zhi-jia |
| Laboratory of Industrial Control Network and System, Shenyang Institute of Automation, Chinese Academy of Sciences, Shenyang 110016, China |
|
|
|
|
Abstract In the present paper both the partial least squares (PLS) method and the calibration curve (CC) method are used to quantitatively analyze the laser induced breakdown spectroscopy data obtained from the standard alloy steel samples. Both the major and trace elements were quantitatively analyzed. By comparing the results of two different calibration methods some useful results were obtained: for major elements, the PLS method is better than the CC method in quantitative analysis; more importantly, for the trace elements, the CC method can not give the quantitative results due to the extremely weak characteristic spectral lines, but the PLS method still has a good ability of quantitative analysis. And the regression coefficient of PLS method is compared with the original spectral data with background interference to explain the advantage of the PLS method in the LIBS quantitative analysis. Results proved that the PLS method used in laser induced breakdown spectroscopy is suitable for quantitative analysis of trace elements such as C in the metallurgical industry.
|
|
Received: 2013-04-19
Accepted: 2013-08-13
|
|
|
|
Corresponding Authors:
SUN Lan-xiang
E-mail: sunlanxiang@sia.cn
|
|
[1] Monfort G, Bellavia L, Vanderheyden B, et al. Metallurgical Analysis(冶金分析), 2012, 32(11): 6.
[2] XIE Cheng-li, LU Ji-dong, LI Yong, et al(谢承利，陆继东，李 勇，等). Journal of Huazhong University of Science and Technology·Natural Science(华中科技大学学报·自然科学版), 2008, 36(10): 114.
[3] CUI Zhi-feng, ZHANG Xian-yi, YAO Guan-xin, et al(崔执凤, 张先燚, 姚关心, 等). Journal of Atomic and Molecular Physics(原子与分子物理学报), 2007, 24(1): 25.
[4] SUN Lan-xiang, YU Hai-bin, CONG Zhi-bo, et al(孙兰香, 于海斌, 丛智博, 等). Chinese Journal of Scientific Instrument(仪器仪表学报), 2011, 32(11): 2602.
[5] YU Ling-yan, LOU Hong-gang, RUAN Zou-rong,et al(俞凌燕, 楼洪刚, 阮邹荣, 等). Chinese Journal of Clinical Pharmacolog and Therapeutics(中国临床药理学与治疗学), 2012, 17(9): 1022
[6] DU Min, WU Zhi-sheng, LIN Zhao-zhou, et al(杜 敏，吴志生，林兆洲，等). Chinese Journal of Pharmaceutical Analysis(药物分析杂志), 2012, 32(10): 1796
[7] CHEN Qiu-ling, WU Gan-jun(陈秋玲，吴干俊). China Safety Science Journal(中国安全科学学报), 2012, 22(10): 8.
[8] Wang Zhe, Yuan Tingbi, Lui Siulung, et al. Frontiers of Physics, 2012, 7(6): 708.
[9] Yao Shunchun, LU Jidong, DONG Meirong, et al. Applied Spectroscopy, 2011, 65(10): 282A, 1087.
[10] TIAN Ye, WANG Zhen-nan, HOU Hua-ming, et al(田 野，王振南，侯华明，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32(8): 2027.
[11] CONG Zhi-bo, SUN Lan-xiang, XIN Yong, et al(丛智博, 孙兰香, 辛 勇，等). Metallurgical Analysis(冶金分析), 2011, 31(4): 9.
[12] SUN Lan-xiang, YU Hai-bin, CONG Zhi-bo, et al(孙兰香, 于海斌, 丛智博, 等). Acta Optica Sinica(光学学报), 2010, 30(9): 2757.
[13] Berglund A, Wolds S. Journal of Chemometrics, 1997, 11(2): 141.
[14] Tripathi M M, Krishnan S R, Srinivasan K K, et al. Fuel, 2012, 93: 684. |
| [1] |
LI Yu1, ZHANG Ke-can1, PENG Li-juan2*, ZHU Zheng-liang1, HE Liang1*. Simultaneous Detection of Glucose and Xylose in Tobacco by Using Partial Least Squares Assisted UV-Vis Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 103-110. |
| [2] |
LIU Jia1, 2, GUO Fei-fei2, YU Lei2, CUI Fei-peng2, ZHAO Ying2, HAN Bing2, SHEN Xue-jing1, 2, WANG Hai-zhou1, 2*. Quantitative Characterization of Components in Neodymium Iron Boron Permanent Magnets by Laser Induced Breakdown Spectroscopy （LIBS）[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 141-147. |
| [3] |
HE Yan1, TAO Ran1, YANG Ming-xing1, 2*. The Spectral and Technology Studies of Faience Beads Unearthed in Hubei Province During Warring States Period[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3700-3709. |
| [4] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1，ZHAO Yan-jie1*，NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
| [5] |
YANG Wen-feng1, LIN De-hui1, CAO Yu2, QIAN Zi-ran1, LI Shao-long1, ZHU De-hua2, LI Guo1, ZHANG Sai1. Study on LIBS Online Monitoring of Aircraft Skin Laser Layered Paint Removal Based on PCA-SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3891-3898. |
| [6] |
LIN Hong-jian1, ZHAI Juan1*, LAI Wan-chang1, ZENG Chen-hao1, 2, ZHAO Zi-qi1, SHI Jie1, ZHOU Jin-ge1. Determination of Mn, Co, Ni in Ternary Cathode Materials With
Homologous Correction EDXRF Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3436-3444. |
| [7] |
HUANG Li, MA Rui-jun*, CHEN Yu*, CAI Xiang, YAN Zhen-feng, TANG Hao, LI Yan-fen. Experimental Study on Rapid Detection of Various Organophosphorus Pesticides in Water by UV-Vis Spectroscopy and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3452-3460. |
| [8] |
LI Zhong-bing1, 2, JIANG Chuan-dong2, LIANG Hai-bo3, DUAN Hong-ming2, PANG Wei2. Rough and Fine Selection Strategy Binary Gray Wolf Optimization
Algorithm for Infrared Spectral Feature Selection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3067-3074. |
| [9] |
SUN Cheng-yu1, JIAO Long1*, YAN Na-ying1, YAN Chun-hua1, QU Le2, ZHANG Sheng-rui3, MA Ling1. Identification of Salvia Miltiorrhiza From Different Origins by Laser
Induced Breakdown Spectroscopy Combined with Artificial Neural
Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3098-3104. |
| [10] |
LIU Shu1, JIN Yue1, 2, SU Piao1, 2, MIN Hong1, AN Ya-rui2, WU Xiao-hong1*. Determination of Calcium, Magnesium, Aluminium and Silicon Content in Iron Ore Using Laser-Induced Breakdown Spectroscopy Assisted by Variable Importance-Back Propagation Artificial Neural Networks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3132-3142. |
| [11] |
JIA Hao1, 3, 4, ZHANG Wei-fang1, 3, LEI Jing-wei1, 3*, LI Ying-ying1, 3, YANG Chun-jing2, 3*, XIE Cai-xia1, 3, GONG Hai-yan1, 3, DING Xin-yu1, YAO Tian-yi1. Study on Infrared Fingerprint of the Classical Famous
Prescription Yiguanjian[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3202-3210. |
| [12] |
WANG Wei-en. Analysis of Trace Elements in Ophiocordyceps Sinensis From
Different Habitats[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3247-3251. |
| [13] |
KONG De-ming1, LIU Ya-ru1, DU Ya-xin2, CUI Yao-yao2. Oil Film Thickness Detection Based on IRF-IVSO Wavelength Optimization Combined With LIF Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2811-2817. |
| [14] |
WANG Yan1, HUANG Yi1, 2*, YANG Fan1, 2*, WU Zhong-wei2, 3, GUAN Yao4, XUE Fei1. The Origin and Geochemical Characteristics of the Hydrothermal Sediments From the 49.2°E—50.5°E Hydrothermal Fields of the Southwest Indian Ocean Ultra-Slow Spreading Ridge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2868-2875. |
| [15] |
CHEN Chao-yang1, 2, LIU Cui-hong1, 2, LI Zhi-bin3, Andy Hsitien Shen1, 2*. Alexandrite Effect Origin of Gem Grade Diaspore[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2557-2562. |
|
|
|
|
