| 光谱学与光谱分析 |
|
|
|
|
|
| Indirect Study of Zinc-Cystine Complex Reaction by FAAS |
| LIU Wen-han1,WU Xiao-qiong1,CHEN Dan1,XIAO Shan-mei2 |
1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, China
2. Jinhua College of Profession & Technology, Jinhua 321017, China |
|
|
|
|
Abstract Each state of cystine and zinc ion in aqueous solution under different pH conditions was calculated by computer, and the scatter diagram was given. Under the influence of solution pH, the mechanism of complex reaction in indirectly determining cystine by flame atomic absorption spectrometry with ZnS was studied. The soluble complex ion is composed of 0 valence cystine Cys-Cys+-,-1 valence cystine Cys-Cys+- and -2 valence cystine Cys-Cys2- with Zn(OH)2. The theoretical analysis from computing and scatter diagram dovetail very well with the data determined from the experiments. The structure of soluble zinc-cystine complex ion is, [(COO-)CH(NH+3)CH2S—SCH2CH(NH+3)COO-]Zn(OH)2, [(COO-)CH(NH+3)CH2S—SCH2CH(NH2)COO-]Zn(OH)2 and [(COO-)CH(NH2)CH2S—SCH2CH(NH2)COO-]Zn(OH)2.
|
|
Received: 2006-10-28
Accepted: 2007-01-09
|
|
|
|
Corresponding Authors:
LIU Wen-han
E-mail: liuwh@mail.hz.zj.cn
|
|
[1] LIU Wen-han, ZHANG Qing-xin, ZHANG Qing-yi, et al(刘文涵, 章庆新, 张清义，等). Journal of Instrumental Analysis(分析测试学报),2003,22(4): 58.
[2] LIU Wen-han, SHAN Wei-guang, GAO Yun-fang, et al(刘文涵, 单伟光, 高云芳，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2003,23(6): 1191.
[3] LIU Wen-han, ZHANG Dan, LI Zu-guang, et al(刘文涵, 张 丹, 李祖光, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005,25(6): 968.
[4] LIU Wen-han, ZHANG Dan, ZHENG Jian-zhen, et al(刘文涵, 张 丹, 郑建珍, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2006,26(1): 147.
[5] LIU Wen-han, SHAN Sheng-yan, ZHANG Dan, et al(刘文涵, 单胜艳, 张 丹, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005,25(10): 1717.
[6] LIU Wen-han，WU Xiao-qiong，ZHENG Jian-zhen，et al(刘文涵，吴小琼，郑建珍，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2007,27(1): 180.
[7] Dean Ed J A. Lange’s Handbook of Chemistry, Thirteenth Edition, McGraw-Hill Book Company, 1985. 5.
[8] David R Lide, ed., CRC Handbook of Chemistry and Physics, Internet Version 2005, <http://www.hbcpnetbase.com>,CRC Press, Boca Raton, FL,2005: 8-14 “Dissociation Constants of Organic Acids and Bases”.
[9] Group of Analysis Chemistry of University of Hangzhou(杭州大学化学系分析化学教研室编). Handbook of Analysis Chemistry(Chemsitry)(分析化学手册·第一分册化学分册), the Second Edition(第2版). Chemistry Industry Publishing House(化学工业出版社), 1997. 148. |
| [1] |
LI Xing-xing, ZHANG Xiang, HUANG Xue-song*. Interaction Between Three Sulfur-Containing Amino Acids in Garlic and Bovine Serum Albumin Determined by Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3483-3488. |
| [2] |
LI Ling1, 2, 3, NAI Xue-ying1, 2*, CHAI Xiao-li1, 2, 3, LIU Xin1, 2, GAO Dan-dan1, 2, DONG Ya-ping1, 2. Optimization of Determination Method of Lithium in Oil-Field Water Based on DOE[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2617-2621. |
| [3] |
WENG Wen-ting, CAI Lu, HAN Ji-yu, MAO Ke-jun, XIE Xiao-lan. Preparation and Application of Fluorescent Cystine Aggregated Nanoclusters[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3428-3433. |
| [4] |
LINGYUN Xia-fei1, 2, GAO Chao1, 2, FAN Jing-shuang1, 2, Lü Hai-xia1, 2*, YU Yan1, 2. Synthesis of Hyperbranched Polyamidoamine (PAMAM) Grafted Chitosan and Its Adsorption for Heavy Metal and Dyes Studied with Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3583-3587. |
| [5] |
LUO Dan, ZHOU Guang-ming*, ZHANG Lu-tao, ZHANG Cai-hong. Analysis of Indomethacin by Surface Enhanced Raman Spectroscopy Based on L-Cys@Ag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(10): 3112-3116. |
| [6] |
ZHANG Cai-hong, ZHOU Guan-ming*, ZHANG Lu-tao, LUO Dan, YU Lu, GAO Yi. An Application to Quantitative Analysis of Hg(Ⅱ) with L-Cysteine Molecular Probe by Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 117-122. |
| [7] |
ZHANG Cai-hong, ZHOU Guang-ming*, CHENG Hong-mei, ZHANG Lu-tao, YU Lu, GAO Yi. Surface Enhanced Raman Spectroscopy Study of Complexes of Metal Ions with L-Cysteine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2079-2086. |
| [8] |
YAO Shi-xiang1, 2, XIE Jiao1, ZENG Kai-fang1, 2*. Comparative Analysis of Several Mineral Elements Contents in Vascular Bundle of Satsuma Mandarin and Ponkan Mandarin Fruit[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(04): 1250-1253. |
| [9] |
ZHAO Fang-biao2, SONG Nai-zhong1, NING Wei-kun2, JIA Qiong1* . Synthesis of Magnetic Metal Organic Framework Fe3O4@NH2-MIL-53(Al) Materials and Application to the Adsorption of Lead [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(09): 2439-2443. |
| [10] |
Medine Abduwayit, Ismayil Nurulla, Shawket Abliz* . Preparation of Polyacrylonitrile/Natural Sand Composite Materials and Analysis of Adsorption Properties of Pb(Ⅱ) on It by FAAS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(02): 539-542. |
| [11] |
ZHANG Li-ying2, TAN Fang-wei1, LU Jian-ping1*, TANG Yan-kui3 . Indirect Determination of Cr(Ⅲ) and Cr(Ⅵ) in Milks by Hydride Generation-Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(08): 2211-2214. |
| [12] |
LIN Jian-mei, YAO Jun-xue*, ZHAO Wen-yan . Determination of Trace Lead in Water and Milk Tea Powder Samples with Organic Coprecipitation-Flame Atomic Absorption Spectrometric [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(05): 1357-1359. |
| [13] |
LU Jian-ping1, GENG Guo-xing1, TANG Yan-kui2, LU Zhi-yong1 . Butanol Extraction Combined with Dilute Hydrochloric Acid Dissolution-Atomic Fluorescence Spectrometric Method for Indirect Determination of Molybdenum in Chinese Herbal Medicine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(12): 3295-3298. |
| [14] |
LU Jian-ping1, GENG Guo-xing1, LU Zhi-yong1, TANG Yan-kui2 . Indirect Determination of Iodine with Methyl Isobutyl Ketone (MIBK) Extraction by Atomic Fluorescence Spectrometer [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(05): 1394-1396. |
| [15] |
Shawket Abliz, Abderyim Sopahun, Ismayil Nurulla*. Analysis of the Adsorption Properties of Lead Ion onto Natural Sand Particles by Flame Atomic Absorption Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(11): 3126-3129. |
|
|
|
|
