| 光谱学与光谱分析 |
|
|
|
|
|
| Spectrophotometry Analysis of Different Valence State of Vanadium in Vanadium Battery Electrolyte |
| CHEN Fu-yu1, CHEN Hui2, HOU Shao-yu2, LIU Jian-guo1*, YAN Chuan-wei1 |
1. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2. Shenyang Ke-Jin New Material Co., Ltd., Shenyang 110015, China |
|
|
|
|
Abstract In the present paper, oxalic acid was used to reduce V(Ⅴ) ion to V(Ⅳ) ion, then its complex with V(Ⅳ) was formed. By this method, four valence states of vanadium ions had different characteristic absorption peaks in the UV-Visible range. Based on these characteristic absorption peaks, qualitative and quantitative spectrophotometric analysis methods for different valence states of vanadium in vanadium battery electrolyte were established. The results showed that the related coefficients of four standard curves of different valence states were greater than 0.999 0, linearity ranges were 0.326~2.445, 0.326~2.445, 0.720~5.403, and 1.784~13.437 g·L-1, respectively. The measurement of samples suggested that the spectrophotometric analysis method was suitable for analyzing the concentration of valence states of vanadium with the RSDs (n=6) in the range of 0.594%~3.535%.
|
|
Received: 2011-01-05
Accepted: 2011-04-15
|
|
|
|
Corresponding Authors:
LIU Jian-guo
E-mail: jgliu@imr.ac.cn
|
|
[1] Zhong S, Skyllas-Kazacos M. Journal of Power Sources, 1992, 39: 1.
[2] Fabjan Ch., Garche J, Harrer B, et al. Electrochimica Acta, 2001, 47: 825.
[3] Iwasa S, Wei Y, Fang B, et al. Battery Bimonthly, 2003, 33(6): 339.
[4] Oriji G, Katayama Y, Miura T. Electrochimica Acta, 2004, 49: 3091.
[5] Gattrell M, Park J, MacDougall B, et al. Journal of the Electrochemical Society, 2004, 151: A123.
[6] Oriji G, Katayama Y, Miura T. Journal of Power Sources, 2005, 139: 321.
[7] Chakrabarti M H, Dryfe R A W, Roberts E P L. Electrochimica Acta, 2007, 52: 2189.
[8] Wen Y H, Cheng J, Zhang H M, et al. Batttery Bimonthly, 2008, 38: 247.
[9] Al-Fetlawi H, Shah A A, Walsh F C. Electrochimica Acta, 2009, 55: 78.
[10] Al-Fetlawi H, Shah A A, Walsh F C. Electrochimica Acta, 2010, 55: 3192.
[11] Shah A A, Al-Fetlawi H, Walsh F C. Electrochimica Acta, 2010, 55: 1125.
[12] PENG Sheng-qian, CAI Shi-ming, XU Guo-zhen, et al(彭声谦, 蔡世明, 许国镇, 等). Physical Testing and Chemical Analysis(Part B：Chemical Analysis)(理化检验·化学分册), 1998, 34(7): 291.
[13] TIAN Bo, YAN Chuan-wei, QU Qing, et al(田 波, 严川伟, 屈 庆，等). Battery Bimonthly(电池), 2003, 33(4): 261.
[14] LIU Su-qin, SANG Yu, LI Lin-de, et al(刘素琴, 桑 玉, 李林德, 等). Physical Testing and Chemical Analysis(Part B：Chemical Analysis)(理化检验·化学分册), 2007, 43(12): 1077.
[15] Wuhan University(武汉大学). Analytical Chemistry(Ver.4)(分析化学, 第4版). Beijing: Higher Education Press(北京：高等教育出版社), 2000. 175.
[16] CHEN Guo-zhen, HUANG Zhi-xian, LIU Wen-yuan, et al(陈国珍, 黄贤智, 刘文远，等). Ultraviolet-Visisble Light Spectrophotometric Method(First Book)[紫外-可见分光光度法(上册)]. Beijing: Atomic Energy Press(北京：原子能出版社), 1987. 45.
|
| [1] |
ZHANG Rong1, 2, DUAN Ning1, 3, JIANG Lin-hua1, 3*, XU Fu-yuan3, JIN Wei3, LI Jian-hui1. Study on Optical Path Optimization for Direct Determination of
Spectrophotometry of High Concentration Hexavalent Chromium
Solution by Ultraviolet Visible Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1829-1837. |
| [2] |
YAO Shan1, ZHANG Xuan-ling1, CAI Yu-xin1, HE Lian-qiong1, LI Jia-tong1, WANG Xiao-long1, LIU Ying1, 2*. Study on Distribution Characteristics of Different Nitrogen and
Phosphorus Fractions by Spectrophotometry in Baiyangdian
Lake and Source Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1306-1312. |
| [3] |
LIU Qin-rong1, DU Zi-wei1, LI Jia-zhen1, WANG Yi-shuo1, 3*, GU Xuan2, CUI Xiu-mei2. Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3618-3624. |
| [4] |
LI Zhen-xia1, SHEN Huan-huan1, GAO Miao-miao1, QI Jiao1, LI Qing-yan2*. Analysis of Lycopene in Different Solvents by Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(04): 1114-1117. |
| [5] |
YANG Ze-ming1, 2, LI Cai1*, LU Gui-xin1, CAO Wen-xi1. A Study of Fast Detection of Nitrite in Seawater Based on Sequential Injection Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 589-595. |
| [6] |
LINGYUN Xia-fei1, 2, GAO Chao1, 2, FAN Jing-shuang1, 2, Lü Hai-xia1, 2*, YU Yan1, 2. Synthesis of Hyperbranched Polyamidoamine (PAMAM) Grafted Chitosan and Its Adsorption for Heavy Metal and Dyes Studied with Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3583-3587. |
| [7] |
CHEN Jing1, 2, 4, PENG Jiao-yu1, 2, BIAN Shao-ju1, 3, GAO Dan-dan1, 3, DONG Ya-ping1, 2*, LI Wu1, 3. Optimization of Determination of CO2-3 and HCO-3 in Boron-Containing Brine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2194-2199. |
| [8] |
LI Yun1,2,3, ZHANG Ji1,2, LIU Fei4, XU Fu-rong3, WANG Yuan-zhong1,2*, ZHANG Jin-yu1,2,3*. Prediction of Total Polysaccharides Content in P. notoginseng Using FTIR Combined with SVR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1696-1701. |
| [9] |
WU Xin1，2, LI Guang-lin1*, WEN Zhi-yu3. Study and Determination the Concentration of CNO-Ion of the QPQ with the Sequential Injection Spectrophotometric Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1824-1828. |
| [10] |
CAO Xuan1, 2，ZHANG Shu-wei1, 2，CHU Dong-zhi1, 2，WU Ning1, 2，MA Hai-kuan1, 2，MA Ran1, 2. Development of Lab-on-Chip Spectrophotometric Silicate Sensor in situ Analysis of Seawater[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 895-900. |
| [11] |
HE Qiu-ju1，2, WANG Li-qin1*, ZHANG Ya-xu1. Study of Mechanism of Aluminum Sizing Precipitant on Xuan Paper Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 418-423. |
| [12] |
ZHU Hong-qiu, GONG Juan, LI Yong-gang*, CHEN Jun-ming. A Spectrophotometric Detecting Method of Trace Cobalt under High Concentrated Zinc Solution[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3882-3888. |
| [13] |
GONG Hong-ling1, LIU Yan-hui2*, TANG Yan-lin2*, HU Lin2. Effects of Temperature on DNA Condensation Detected with Temperature-Changed Ultraviolet Spectrum Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1831-1837. |
| [14] |
LIU Qian3, CHEN Wen-juan1,2, JING Bo1,2, ZHANG Jian1,2, YANG Meng-ying3, CHEN Wu3, YIN Xian-qing1,3*. Spectrum Analysis of Trace Hydrogen Peroxide in Electrochemical Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1656-1660. |
| [15] |
XIE Ying-ke1,2,3, WEN Qun1,2*, WEN Zhi-yu1,2, MO Zhi-hong1,2, WEI Kang-lin1,2. On-Line Determination of Chemical Oxygen Demand and Total Phosphorus in Water by Using Fenton Reagents via a Micro-Spectrometer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1642-1648. |
|
|
|
|
