| 光谱学与光谱分析 |
|
|
|
|
|
| Spectroscopic Studies on Transition Metal Ions in Colored Diamonds |
| MENG Yu-fei1，PENG Ming-sheng1，CHEN Wen-xuan2 |
1. Institute of Gemstones and Mineral Materials, Zhongshan University, Guangzhou 510275, China
2. State Key Laboratory of Optoelectronic Materials and Technologies, Zhongshan University, Guangzhou 510275，China |
|
|
|
|
Abstract Transition metals like nickel, cobalt and iron have been often used as solvent catalysts in high pressure high temperature (HPHT) synthesis of diamond, and nickel and cobalt ions have been found in diamond lattice. Available studies indicated that nickel and cobalt ions could enter the lattice as interstitial or substitutional impurities and form complexes with nitrogen. Polarized microscopy, SEM-EDS, EPR, PL and FTIR have been used in this study to investigate siｘ fancy color natural and synthetic diamonds in order to determine the spectroscopic characteristics and the existing forms of transition metal ions in colored diamond lattice. Cobalt-related optical centers were first found in natural chameleon diamonds, and some new nickel and cobalt-related optical and EPR centers have also been detected in these diamond samples.
|
|
Received: 2003-01-26
Accepted: 2003-06-30
|
|
|
|
Corresponding Authors:
MENG Yu-fei
|
|
| Cite this article: |
|
MENG Yu-fei,PENG Ming-sheng,CHEN Wen-xuan. Spectroscopic Studies on Transition Metal Ions in Colored Diamonds[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(07): 769-774.
|
|
|
|
| URL: |
|
http://www.gpxygpfx.com/EN/Y2004/V24/I07/769 |
[1] CHEN Feng, WANG Ming-zai, WANG San-xue et al(陈 丰，王明再，王三学等). Chinese Science Bulletin(科学通报)，1992，37(19)：1782.
[2] CHEN Feng, DING Zhen-hua, WANG San-xue et al(陈 丰，丁振华，王三学等). Chinese Science Bulletin(科学通报)，1996，41(14)：1304.
[3] ZHAO Lei, LU Feng-xiang, ZHENG Jian-ping et al(赵 磊，路凤香，郑建平等). Chinese Science Bulletin(科学通报)，1995，40(12)：1114.
[4] Yin L Ｗ, Wang N Ｗ, Zou Z D et al. Appl. Phys. A，2000，71：473.
[5] Yin Long-wei, Li Mu-sen, Sun Dong-sheng et al. Materials Letters，2001，1：21.
[6] Collins A T，Spear P M. J. Phys. D: Appl. Phys.，1982，15：L183.
[7] Collins A T. Diam. Relat. Mater.，2000，9：417.
[8] Noble C J, Pawlik Th, Spaeth J M. J. Phys.: Condens. Matter，1998，10：11781.
[9] Nadolinny Ｖ A, Yelisseyev A P, Baker J M et al. J. Phys.: Condens. Matter，1999，11：7357.
[10] 林 冰. 金刚石结构中的氮与金刚石颜色的关系. 中山大学硕士学位论文，2001.
[11] PENG Ming-sheng, LIN Bing, PENG Zhuo-lun(彭明生，林 冰，彭卓伦). Bulletin of Mineralogy Petrology and Geochemistry(矿物岩石地球化学通报)，1999，18(4)：395.
[12] PENG Minｇ-shenｇ，LIN Binｇ(彭明生，林 冰). 21st Centｕrｙ-oriented Proｇress in Science and Technoloｇｙ and Development of Social Economｙ-Ｖolｕme One(面向21世纪的科技进步和社会经济发展(上)). Beijinｇ：China Science and Techonolｇｙ Press(北京：中国科学技术出版社)，1999. 187.
[13] PENG Ming-sheng, YANG Zhi-jun, LIN Bing(彭明生，杨志军，林 冰). Geological Journal of China Universities(高校地质学报)，2000，6(2)：145.
[14] PENG Ming-sheng, YANG Zhi-jun, YUAN Zhi-zhong(彭明生，杨志军，苑执中). Acta Mineralogica Sinica(矿物学报)，2001，21(3)：312.
[15] YANG Zhi-jun, PENG Ming-sheng, XIE Xian-de(杨志军，彭明生，谢先德). Mineral Resources and Geology(矿产与地质)，2001，5(2)：141.
[16] YANG Zhi-jun, PENG Ming-sheng, YUAN Zhi-zhong(杨志军，彭明生，苑执中). Acta Mineralogica Sinica(矿物学报)，2001，21(3)：393.
[17] De Weerdt Filip, Van Royen Jef. Diam. Relat. Mater.，2001，10：474.
[18] Lawson Simon C, Fisher David, Hunt Damian C et al. J. Phys.: Condens. Matter，1998，10：6171.
[19] Kanda H, Watanabe Ｋ. Diam. Relat. Mater.，1999，8：1463.
[20] Iakoubovskii Ｋ, Adriaenssens G J. Diam. Relat. Mater.，2002，11：125.
|
| [1] |
WANG Tao1, 2, LIU Jian-xun2, GE Xiao-tian2, WANG Rong-xin2, SUN Qian2, NING Ji-qiang2*, ZHENG Chang-cheng3*. Fine Photoluminescence Spectroscopic Characterization of Interfacial Effects on Emission Properties of InGaN/GaN Multiple Quantum Wells in a Blue-Light Laser Diode Structure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1179-1185. |
| [2] |
CHEN Cai-yun-fei, LI Li-ping*. The Application of Photoluminescence Spectra on Identification of Different Types of Pearls[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 20-25. |
| [3] |
ZHAO Tong1, WANG Ya-mei1,2, LIU Ling1, LI Yan1,3*. Gemological and Spectral Characteristics of Mexican Red Blue Amber[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2618-2625. |
| [4] |
REN Jiang-bo1,2, WANG Fen-lian1,2*, HE Gao-wen1, 2, ZHANG Xin3, DENG Xi-guang1,2, YU Hong-xia4. μ-XRF Analysis and Data Mining of Deep-Sea Co-Rich Ferromanganese Nodules in Western Pacific[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1834-1840. |
| [5] |
SHI Ang-ang1, YU Hong-xia2, GU Min-fen1*, YANG Zhong-lin3, YANG Xue1. FTIR Spectroscopy of Core@Shell Structured Nickel-Hydrazine Nanocomposites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3136-3140. |
| [6] |
JI Bang1,2, ZHAO Wen-feng3, DUAN Jie-li4, FU Lan-hui1, MA Li-zhe3, YANG Zhou1*. Spectral Characteristics of Ag3PO4/GO on Nickel Foam and Photocatalytic Degradation of Ethylene Under Visible Light[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2743-2750. |
| [7] |
YAN Jun1,2, SUN Qing2, YAN Xue-jun1, FANG Shi-bin1, SHENG Jia-wei2, ZHANG Jian2*. The Categories of the UV-Vis Reflectance Spectra of Seawater Cultured Black Pearl and Its Unique PL Spectral Characteristics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2781-2785. |
| [8] |
ZHENG Bao-feng1, YANG Xiao-yun2，3, MIN Chun-gang2，3, CUI Xiao-ying2，3, DONG Kun2，3*. Study on Raman Spectra and Fluorescence Spectra of Dy3Al2(AlO4)3 in Aluminosilicate Substrates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 809-812. |
| [9] |
ZHENG Bao-feng1, YANG Xiao-yun2,3, MIN Chun-gang2,3, CUI Xiao-ying2,3, DONG Kun2,3*. Study on Raman Spectra and Fluorescence Spectra of Tb-Doped Aluminosilicates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2371-2376. |
| [10] |
NIE Li-xing, CHANG Yan, DAI Zhong, MA Shuang-cheng*. A New Method for Determination of Polysorbate 80 in Shengmai Injection Based on Absorption Coefficient[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 199-203. |
| [11] |
ZHANG Gui-yin1, SONG Huan1, LIU Yang1, REN Zhi1, ZHENG Hai-ming2. Investigation on the Properties of Laser Induced Ni Plasma[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2578-2582. |
| [12] |
ZHU Hong-qiu, GONG Juan, LI Yong-gang*, CHEN Jun-ming. A Spectrophotometric Detecting Method of Trace Cobalt under High Concentrated Zinc Solution[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3882-3888. |
| [13] |
GONG Hong-ling1, LIU Yan-hui2*, TANG Yan-lin2*, HU Lin2. Effects of Temperature on DNA Condensation Detected with Temperature-Changed Ultraviolet Spectrum Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1831-1837. |
| [14] |
ZHANG Yi-ting1, WANG Cui-cui1, FAN Meng-li1, CAI Wen-sheng1, SHAO Xue-guang1，2* . Quantitative Analysis of Heave Mental Ion Based on Portable NIR Spectrometer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(12): 4100-4104. |
| [15] |
WANG He-lin1,2, ZHANG Yu1,2*, LIU Wen-yan1, WANG Guo-guang2, ZHANG Tie-qiang2 . Study of PL Spectra of PbSe Quantum Dots for IC Chip Temperature Dependence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(05): 1169-1172. |
|
|
|
|
