新型罗丹明酰胺杯芳烃-Sb<SUP>3+</SUP>配合物探针对钙离子的响应

doi:10.3964/j.issn.1000-0593(2010)05-1305-05

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Abstract A new fluorescence probe based on the rhodamine B amide-armed homotrioxacalix[3]arene (1) has been synthesized, and its Ca²⁺-selective chromogenic properties were investigated in acetonitrile Tris-HCl buffer (pH 7) solution by UV-Vis and fluorescence spectroscopies. Upon the addition of Sb³⁺ ion, the spirocyclic ring of 1 was opened and a significant fluorescence enhancement and colorimetric change was observed. However, addition of Ca²⁺ ion to the solution of 1-Sb³⁺ complex leads to a strong fluorescence quenching of the original 1-Sb³⁺ complex. The phenomenon exhibited a pronounced Ca²⁺ selective fluoroionophoric behavior over other coexistent metal ions and provided the ratiometric determination as well as naked-eye detection of Ca²⁺ ions.

Key words：Rhodamine B;homotrioxacalix[3]arene;Fluorescence and colorimetric probe;Sb3+;Ca²⁺

Received: 2009-06-28 Accepted: 2009-09-29

ZTFLH:

O657.3

Corresponding Authors: MU Lan E-mail: sci.lmou@gzu.edu.cn

Cite this article:

ZHANG Wen-juan,WU Chong,ZENG Xi, et al. A New Probe for Ca²⁺ Based on the Rhodamine B Amide Armed Homotrioxacalix[3] Arene-Sb³⁺ Complex [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(05): 1305-1309.

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https://www.gpxygpfx.com/EN/10.3964/j.issn.1000-0593(2010)05-1305-05 OR https://www.gpxygpfx.com/EN/Y2010/V30/I05/1305

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