光谱学与光谱分析 |
|
|
|
|
|
Assay of Three Kinds of Aluminum Fractions (Ala, Alb and Alc) in Polynuclear Aluminum Solutions by Al-Ferron Timed Spectrophotometry and Demarcation of Their Time Limits |
WANG Chen-yi1,2, ZHANG Cai-hua1, BI Shu-ping1*, ZHANG Zhen-chao3, YANG Wei-hua3 |
1. Department of Chemistry, Nanjing University, Nanjing 210093, China 2. Department of Chemistry, Huzhou Teachers College, Huzhou 31300, China 3. Department of Chemistry, Xuzhou Normal University, Xuzhou 221009, China |
|
|
Abstract Al-Ferron timed spectrophotometry assay is a basic method in the study on the formation of polynuclear hydroxyl aluminum species and their transformation laws in aqueous systems. In actual working process, this methodology has some dogmatism and arbitrariness in the time limits demarcation of the three kinds of aluminum fractions (Ala, Alb and Alc) in polynuclear aluminum solutions, which makes this kind of classification rougher, and the experimental results non-reproducible. The reason for this difference is that the specific species within Ala, Alb and Alc have different reaction mechanism and dynamics, and that specific species of Alb having different OH/Al ratios have different reaction rates with ferron. In this paper, the ExpAssoc distribution was applied to quantitatively fit the Al-Ferron reaction dynamics curve, and the extrapolation method was used to survey the 1 min measured value [Ala] of monomeric Al, which is hard to obtain in manual manipulation. The time demarcation between Alb and Alc should reach the point of the experimental data curve up to horizontal platform. The microwave-radiated technology was used to fast assay the total aluminum concentration [AlT]. With these methods, the contents of monomeric Ala, polynuclear Alb and gel Alc can be conveniently and quantitatively measured. It offers a novel method for surmounting the arbitrariness in the measurement of the three kinds of aluminum fractions and the repetitive calculation of Ala and Alb.
|
Received: 2003-07-22
Accepted: 2003-11-28
|
|
Corresponding Authors:
BI Shu-ping
|
|
Cite this article: |
WANG Chen-yi,ZHANG Cai-hua,BI Shu-ping, et al. Assay of Three Kinds of Aluminum Fractions (Ala, Alb and Alc) in Polynuclear Aluminum Solutions by Al-Ferron Timed Spectrophotometry and Demarcation of Their Time Limits[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(02): 252-256.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2005/V25/I02/252 |
[1] Smith R W. ACS Advances in Chem. Series, 1971, 106: 250. [2] Smith R W,Hem J D. Effect of Ageing on Aluminum Hydroxide Complexes in Dilute Aqueous Solutions, U. S. G. S., Water Supply Paper, 1827D. Washington:Government Printing Office, 1972. [3] Jardine P M,Zelazny L W. Soil Sci. Soc. Am. J., 1986, 50: 895. [4] Duffy S J,Vanloon G W. Environ Sci. & Technol., 1994, 28: 1950. [5] Wang C Y, Bi S P,Luo M B. Review in Analytical Chemistry, 2003, 22(1): 53. [6] TANG Hong-xiao(汤鸿霄). Acta Scientiae Circumstantiae(环境科学学报), 1998, 18(1): 1. [7] LU Jian-hang, LIU Wei-ping(卢建杭,刘维屏). Environmental Chemistry(环境化学), 1998, 17(6): 576. [8] LUAN Zhao-kun,TANG Hong-xiao (栾兆坤, 汤鸿霄). Acta Scientiae Circumstantiae (环境科学学报), 1997, 17(3): 321. [9] SHI Bao-you, TANG Hong-xiao (石宝友, 汤鸿霄). Acta Scientiae Circumstantiae(环境科学学报), 2000, 20(4): 391. [10] Shen Y H,Dempsey B A. Environment International, 1998, 24: 899. [11] Changui C, Stone W E E, Vielvoye L,Dereppe J M. J. Chem. Soc. Dalton Trans., 1990, 1723. [12] Bertsch P M, Barnhisel R I, Thomas G W, Layton W J,Smith S L. Anal. Chem., 1986, 58: 2583. [13] Kerven G L, Larsen P L,Blamey F P C. Soil Sci. Soc. Am. J., 1995, 59:765. [14] Denney D Z,Hsu P H. Clay and Clay Minerals, 1986, 34(5): 604. [15] Parker D R,Bertsch P M. Environ. Sci. Technol., 1992, 26: 908. [16] Wang W Z,Hsu P H. Clays and Clay Minerals, 1994, 42(3): 356. [17] Bersillon J L,Hsu P H,Flessinger F. Soil Sci. Soc. Am. J., 1980, 44: 630. [18] Irving H M, Miles M G,Pettit L D. Anal. Chim. Acta, 1967, 38: 475. [19] FENG Li, LUAN Zhao-kun,TANG Hong-xiao (冯 利, 栾兆坤, 汤鸿霄). Environmental Chemistry(环境化学), 1993, 12(5): 373. [20] Tsai P P,Hsu P H. Soil Sci. Soc. Am. J., 1984, 48: 935. [21] Clarke N, Danielsson L G,Sparen A. Pure & Appl. Chem., 1996, 68: 1597. [22] LUAN Zhao-kun, FENG Li,TANG Hong-xiao(栾兆坤, 冯 利, 汤鸿霄), Acta Scientiae Circumstantiae(环境科学学报), 1995, 15(1): 39. [23] Snodgrass W J, Clark M M,?melia C R. Water Res., 1984, 18: 479. [24] Bertsch P M,Parker D R. Aqueous Polynuclear Aluminum Species, in The Environmental Chemistry of Aluminum, Sposito, G (Ed.). New York:Lewis Publishers, 1996. Chap. 4, 117. [25] Jardine P M,Zelazny W. Soil Sci. Soc. Am. J., 1987, 51: 889. [26] Parker D R, Zelazny L W,Kinraide T B. Soil Sci. Soc. Am. J., 1988, 52: 67. |
[1] |
JIANG Bo1, 3, HUANG Jian-hua2*, LIU Wei2. Multi-Element Analysis of Wild Chinese Honeylocust Fruit by Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3859-3864. |
[2] |
MI Hai-peng1, ZHU Hong-ming1, LI Gen-rong1, YU Xiang1, MA Bing-bing2, ZHOU Xi-lin2, WANG Ya-sen2, SU Zhong-hua2, DENG Xiong2. Determination of Pb, Cr, Cd, and As in Aluminum-Plastic Packaging Materials via Inductively Coupled Plasma-Mass Spectrometry with Microwave Digestion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 646-650. |
[3] |
ZHAO Liang-cheng1, JIANG Yun-jun1, GUO Xiu-ping1, LI Xing1, WANG Yi-dan3, GUO Xiao-biao1, LU Feng1, LIU Hua-jie2*. Optimization of ICP-AES and ICP-MS Techniques for the Determination of Major, Minor and Micro Elements in Lichens [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3320-3325. |
[4] |
ZHANG Ling-li1, 2, DING Yu-long1, 3, ZHANG Mei1, 3, GUI Duan1, 3, NING Xi2, 3, LI Jun1, 3, WU Yu-ping1, 3* . Determination of Trace Elements in the Melon of Indo-Pacific Humpback Dolphins (Sousa chinensis) with ICP-MS [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3326-3331. |
[5] |
CHEN Lin-wei, CAI Hao*, WANG Qin, QIAO Feng-xian, QIN Kun-ming, CAI Bao-chang . Elemental Analysis of Nine Herbal Drugs for Nourishing Blood by Inductively Coupled Plasma Atomic Emission Spectroscopy with Microwave Digestion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(07): 2358-2362. |
[6] |
WANG Xiao-wei1, LIU Jing-fu2, GUAN Hong3, WANG Xiao-yan1, SHAO Bing1*, ZHANG Jing1, LIU Li-ping1, ZHANG Ni-na1. Determination of Total Sulfur Dioxide in Chinese Herbal Medicines via Triple Quadrupole Inductively Coupled Plasma Mass Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 527-531. |
[7] |
CHEN Qian1, WU Xi2, HOU Xian-deng2, XU Kai-lai1* . Simultaneous Determination of Sn and S in Methyltin Mercaptide by Microwave-Assisted Acid Digestion and ICP-OES[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(09): 2393-2396. |
[8] |
DING Yu-long1, NING Xi1, 2, GUI Duan1, MO Hui3, LI Yu-sen1, WU Yu-ping1* . Determination of Trace Elements in Marine Cetaceans by ICP-MS and Health Risk Assessment [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(09): 2407-2411. |
[9] |
ZHANG Liu-yi1, FU Chuan1*, YANG Fu-mo1,2, YANG Ji-dong1, HUANG Yi-min1, ZHANG Qiang1, WU Bing-yu1 . Determination of Metal Elements in PM2.5 by ICP-OES with Microwave Digestion [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(11): 3109-3112. |
[10] |
YUAN Jun-jie1, XIE You-zhuan1*, HAN Chen1, SUN Wei1, ZHANG Kai1, ZHAO Jie1, LU Xiao2, LU Jian-xi2, REN Wei3. Determination of Trace Element Silver in Animal Serum, Tissues and Organs by Microwave Digestion-ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(09): 2533-2537. |
[11] |
CHEN Li-dan1, ZHAO Yan-ru2. Application of Microwave Digestion/AAS in Detecting Crankshaft Bearing Knock [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(06): 1683-1687. |
[12] |
CHEN Zhao-qiong1, 2, FANG Chen1, AI Ying-wei1*, GAO Hong-ying1, PAN Dan-dan1, LI Xin-yue1 . Determination of Heavy Metals in Artificial Soil on Railway Rock-Cut Slopes by Microwave Digestion-AAS [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(08): 2215-2218. |
[13] |
NIE Xi-du1, FU Liang2* . Study on the Determination of 14 Inorganic Elements in Coffee by Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(07): 1953-1956. |
[14] |
ZHU Qian-hua . Determination of Impurity Elements in the Positive Electrode Material LiMn2O4 by Inductively Coupled Plasma Mass Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(05): 1350-1353. |
[15] |
LIU Hong-wei1, XIE Hua-lin2*, NIE Xi-du1, 3 . Study on the Determination of Trace Elements in Bitter Almond by Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(05): 1354-1356. |
|
|
|
|