光谱学与光谱分析 |
|
|
|
|
|
Depth Profiles of High-Density Polyethylenes Filled with Different Inorganic Fillers during Natural Photo-Oxidation by Infrared Microscopy |
YANG Rui1, WANG Kun-hua1, YU Jian1, SONG Yuan-yuan2, WANG Hong-kai2 |
1. Department of Chemical Engineering, Tsinghua University, Beijing 100084, China 2. Beijing Shimadzu Analysis Center, Beijing 100020, China |
|
|
Abstract The natural photo-oxidation degradation of HDPE filled with different inorganic fillers was carried out, and the depth profiles of the standard samples were characterized by infrared microscopy (IM) and scanning electron spectroscopy (SEM). The results show that HDPE filled with different inorganic fillers show different depth profiles. For HDPE and CaCO3-filled HDPE, there are no cracks on the cross sections, and the carbonyl indexes remain nearly zero from the surface to the interior. For HDPE filled with black mica, mica, kaolin and diatomite, there are more or less parallel, comb-like cracks on the cross sections, and the carbonyl indexes show decreasing trends from the surface to the interior. Furthermore, the transition points in CI curves are basically consistent with the formation of cracks in these samples. The UV absorbances of these inorganic fillers demonstrate the relationship between the photo-oxidation of HDPE and the relative absorbances of inorganic fillers. This implies that the UV absorbance of the inorganic filler may be responsible for the occurrence of cracks and oxidation in the standard samples.
|
Received: 2005-03-26
Accepted: 2005-07-08
|
|
Corresponding Authors:
YANG Rui
|
|
Cite this article: |
YANG Rui,WANG Kun-hua,YU Jian, et al. Depth Profiles of High-Density Polyethylenes Filled with Different Inorganic Fillers during Natural Photo-Oxidation by Infrared Microscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 821-824.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2006/V26/I05/821 |
[1] Pages P, Carrasco F, Saurina J, et al. Appl. Polym. Sci., 1996, 60(2): 153. [2] Satoto R, Subowo W S, Yusiasih R, et al. Polym. Degrad. Stab., 1997, 56(3): 275. [3] WU Shi-shan,XU Xi(吴石山, 徐 僖). Chinese J. Applied Chem.(应用化学), 2001, 18(9): 758. [4] Carrasco F, Pages P, Pascual S, et al. Eur. Polym. J., 2001, 37(7): 1457. [5] Costa L, Luda M P, Trossarelli L. Polym. Degrad. Stab., 1997, 58(1-2): 41. [6] Anna P, Bertalan Gy, Marosi Gy, et al. Polym. Degrad. Stab., 2001, 73(3): 463. [7] Kaci M, Cimmino S, Di Lorenzo M L, et al. J. Macromol. Sci., Pure Appl. Chem., 1999, A36(2): 253. [8] Allen N S, Katami H. Polym. Degrad. Stab., 1996, 52(3): 311. [9] Liu M, Horrocks A R. Polym. Degrad. Stab., 2002, 75(3): 485. [10] Kiathamjornwong S, Pabunruang T, Wongvisetsirikul N, et al. J. Sci. Soc. Thailand, 1997, 23(3): 135. [11] SHEN Jing-wei, LIU Yue-jian(沈经纬, 刘跃建). Chem. J. Chinese Universities(高等学校化学学报), 1995, 16(7): 1146. [12] Sanchez-Solis A, Estrada M R. Polym. Degrad. Stab., 1996, 52(3): 305. [13] Yang R, Yu J, Liu Y, et al. Polymer Degradation and Stability,2005,88(2):333. |
[1] |
YANG Ling-yue1, YAN Sheng-wu2, 3, WANG Hao-tian1, ZHANG Yu-ting1, WANG Ren-yun4, YANG Ming-xing1, WANG Chao-wen1*. Spectral Characteristics of Two Kinds of Nanhong Agate Imitations[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 835-840. |
[2] |
LONG Chu1,HE Li-yan1,HOU Shun-yu1,ZHAO Bo-wen2,TU Cai2,LÜ Xiao-yu2. The Characteristics of Hydrous Mineral Inclusions in Low-Temperature Heated Corundum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1530-1536. |
[3] |
ZHANG Xin-bo1, CONG Long-zhuang1, YANG Lan-lan1, DU Zhong-lin1, WANG Yao1, WANG Yan-xin1, HUANG Lin-jun1, GAO Fan1, Laurence A. Belfiore2, TANG Jian-guo1*. Optimal Fluorescence Property of CdSe Quantum Dots and Electrospinning Polyvinylpyrrolidone Hybrid Microfibers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 990-996. |
[4] |
YANG Chuan-xiao, GONG Wei-bin, TANG Fan, SUN Xiang-ying. Determination of Sodium Hexametaphosphate by Ratiometric Fluorescence Method Based on Formaldehyde Functionalized Polyethyleneimine/Eosin Y System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 454-459. |
[5] |
YANG Chao1, ZHU Zhen2, LI Jing4, SUN Yun-heng5, OUYANG Xue-yan1, WANG Jia-wei2, HUANG Qian1, DING Gang3, WANG Yao-sheng1*, JIANG Feng1*. Changes of Tumor Cell Components Induced by Pain-Related Neuropeptides SP Investigated by Synchrotron Radiation Infrared Microscopic Imaging Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3579-3584. |
[6] |
XIAO Qing, WEI Shu-ya*, FU Ying-chun. Feasibility Study on Quantitative Analysis of Ancient Lacquer Films by Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2962-2967. |
[7] |
JIANG Xin-cheng1, SHI Lin-hong1, LUO Bin2, WANG Dong-mei1, WANG Zhao-li3, FAN Mei-kun1, GONG Zheng-jun1*. Transmission Surface Enhanced Infrared Spectroscopy Based on AgNPs-Cu Foam Substrate for the Detection of Thiram Pesticides[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1809-1814. |
[8] |
LAO Wan-li, LI Gai-yun*, CHEN Yi, XIANG Qin, WANG Chao, HUANG An-min. Qualitative and Quantitative Analysis of Two Types of Wood Plastic Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(09): 2807-2811. |
[9] |
SHAO Tian, LUO Ze-min, CHEN Tao, Andy Hsitien Shen*. The Micro Mid-Infrared Spectral Study on Quench of Natural and Synthetic Ametrine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(09): 2749-2756. |
[10] |
LI Xiao-xiao1, YANG Zhi-jun1, 2*, HUANG Shan-shan1, CHEN Yao-ming1, ZENG Xuan1, ZHOU Wen-xiu1. FTIR Spectra and LA-ICP-MS Research of Growth Zones in Sapphire Bands from Changle, Shandong Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 407-412. |
[11] |
WEI Peng-lian1, HUANG Yan-hui2, LIU Rong1, AN Xin1, FEI Ben-hua1* . Research on Chemical Constituents of Bamboo Fiber Cell Wall Based on Nano-IR Technology [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(01): 103-108. |
[12] |
ZHOU Han-guo1,2, GUO Jian-chun1, LI Jing3*, LIU Si-meng4, PENG Cheng-le3, HOU Jiang-peng3 . Characterizing Fracture Characteristics of Heterogeneous Oil and Gas Reservoir by Using Microscopic Infrared Spectroscopy Technique ——Taking Carbonate Reservoir of the Wumishan Formation of Jixian System in Renqiu Burried Hill as an Example[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(12): 3926-3930. |
[13] |
LI Li-xia1, 2, CAO Bing1, 2*, SUN Yu-meng1, 3, LI Hong-yan1, 2, XIAO Qiang1, 2, NI Xiao-hui1, 2, YI Wen-ping1, 2 . Infrared Spectrum Studies of Coatings under Irradiation of Sunlight and Ultraviolet [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3159-3162. |
[14] |
JIANG Zhi-quan, HU Ke-liang . Authentication of Trace Material Evidence in Forensic Science Field with Infrared Microscopic Technique [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 706-710. |
[15] |
JIANG Bo, HU Wen-zhong*, LIU Chang-jian, ZHENG Wei, QI Xiao-hui, JIANG Ai-li, WANG Yan-ying . Qualitative Determination of Organic Vapour Using Violet and Visible Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3454-3458. |
|
|
|
|