| 光谱学与光谱分析 |
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| FTIR and XRD Analysis Studies of Intercalation of Kaolinite with Benzamide |
| ZHANG Sheng-hui1,QIANG Ying-huai1,OU Xue-mei1,XIA Hua2 |
1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221008, China
2. College of Materials Science and Chemistry Engineering, China University of Geoscience, Wuhan 430074, China |
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Abstract Benzamide was intercalated into kaolinite by replacing DMSO pre-intercalated. Pure kaolinite-benzamide intercalation compounds were obtained by washing resulting products with acetone. The analysis of XRD shows that the basal spacing of kaolinite-benzamide intercalation compounds increased to 1.437 nm from 0.717 nm of kaolinite. The analysis of FTIR shows that intercalation caused the shifts of the inner surface OH stretching bands from 3 696 and 3 657 cm-1 of the raw kaolinite to 3 701 and 3 651 cm-1 of the kaolinite-benzamide intercalation compounds, respectively, and the blue shift of CO stretching bands from 1 659 cm-1 of benzamdie to 1 640 cm-1 of the kaolinite-benzamide intercalation compounds, and the NH vibrations at 3 368 and 3 172 cm-1 of benzamdie shifted to 3 474 and 3 184 cm-1, respectively. These changes in IR bands implied the breaking of the H-bonds between layers of kaolinite and the formation of new H-bonds between the inner-surface hydroxyls of the kaolinite and the benzamide in the intercalation compounds. The experimental results show that the intercalation reaction comes to equilibrium rapidly during 30 min, and the highest intercalation ratio occurs when the reaction temperature is 180 ℃. Washed by acetone, the residual benzamide and that adsorbed on the surface of the resulting products could be eliminated without significant influence on the structure of the intercalation compounds.
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Received: 2008-03-28
Accepted: 2008-06-30
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Corresponding Authors:
ZHANG Sheng-hui
E-mail: shenghui_zhang@163.com
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[1] CHEN Xing-guo，YANG Chu-luo，QIN Jin-gui(陈兴国，杨楚罗，秦金贵). Chemistry Bulletin(化学通报)，2000，(7):1.
[2] Olejnik S，Aylmore L A G，Pasner A M，et al. Journal of Physical Chemistry，1968，72(1):241.
[3] Kristof J，Horvath E，Frost R L，et al. Journal of Thermal Analysis and Calorimetry，2001，63:279.
[4] Olejnik S，Posner A M，Quirk J P. Journal of Colloid and Interface Science，1971，37(3):536.
[5] Cruz M D R，Franco F. Clays and Clay Minerals，2000，48(1):63.
[6] Frost R L，Kristof J，Schmidt J M，et al. Spectrochimiac Scta Part A，2001，57:603.
[7] Komori Y，Sugahara Y，Kuroda K. Applied Clay Science，1999，15(1-2):241.
[8] LI Yan-feng，PAN Xiao-bing，LI Gang，et al(李彦锋，潘晓兵，刘 刚，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005，25(10):1736.
[9] Takenawa R，Komori Y，Hayashi S，et al. Chemistry of Materials，2001，13:3741.
[10] WANG Bao-xiang，ZHAO Xiao-peng，YAO Yuan(王宝祥，赵晓鹏，姚 远). Science in China Ser E:Engineering and Materials Science(中国科学E·工程科学材料科学)，2005，35(9):911.
[11] Gardolinski J E，Ramos L P，Wypych F，et al. Jourmal of Colloid and Interface Science，2000，221:284.
[12] ZHANG Sheng-hui，YANG Wei，XIA Hua(张生辉，杨 薇，夏 华). Journal of China Ceramic Society(硅酸盐学报)，2004，132:631.
[13] Brindley G W，Brown G. Crystal Structures of Clay Minerls and Their X-Ray Identification. London:Mineralogical Society，1980.
[14] Frost R L，Kristof J，Horvath E，et al. Thermochimica Acta，1999，327:155.
[15] Xie Xiulan，Hayashi S. Journal of Physical Chemistry B，1999，103(29):5949.
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