| 光谱学与光谱分析 |
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| Determination of Trace Metal Elements in Zanthoxylum Nitidum by ICP-AES |
| QIN Jiao-lan, CHEN Zhen-feng, LIU Yan-cheng, LIANG Hong |
| Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education), School of Chemistry & Chemical Engineering of Guangxi Normal University, Guilin 541004, China |
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Abstract The contents of twenty microelements were determined in the root, stem and leaf of traditional Chinese herbs, Zanthoxylum nitidum by ICP-AES (inductively coupled plasma-atomic emission spectrometry) analytical technology. For such method, their recovery ratio obtained by standard addition method ranged between 89% and 107.5%, and most of RSDs were lower than 4%, with good correction and precision. The analytical results show that there exist different contents from the different parts of the plant. There are most rich elements such as Mg, Na, K, and Ca in its three parts, while Mn, Zn, Fe, Cu, Co, Sr and some toxic elements Cd, Cr, Pb and Bi were also detected; four elements, Se, V, Mo and Hg, were not detected in all parts. There exist many kinds of metal elements benefiting human being health, which may provide useful information for the usage of the herbs and for the study of the relationship between the elements in Chinese traditional medicine and its bioactivities.
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Received: 2008-08-08
Accepted: 2008-11-12
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Corresponding Authors:
QIN Jiao-lan
E-mail: qinjiaolan508@163.com
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[1] WANG Heng-shan, OU Shang-yao, PAN Ying-ming, et al(王恒山，欧尚瑶，潘英明，等). Natural Product Research and Development(天然产物研究与开发), 2006, 18(2): 251.
[2] XIE Yun-feng (谢云峰). Shizhen Medicine and Medica Research(李时珍国医国药), 2000, 11(1): 1.
[3] HUANG Zhi-xun, LI Zhi-he(黄治勋, 李志和). Acta Chimica Sinica(化学学报), 1980, 38(6): 535.
[4] LIU Shao-hua, QIN Qing-yun, TANG Xian-lan(刘绍华，覃青云，唐献兰). Journal of Guangxi Academy of Sciences(广西科学院学报), 2005, 21(2): 130.
[5] MIAO Jian, GAO Qi, XU Si-lai(苗 健，高 琦，许思来). Trace Element and Related Disease(微量元素与相关疾病). Zhengzhou: Henan Medical University Press(郑州: 河南医科大学出版社)，1997. 239.
[6] CAO Zhi-quan(曹治权). Guangdong Trace Elements Science(广东微量元素科学)，1997, 4(7): 9.
[7] CAO Zhi-quan, SUN Zuo-min, SUN Ai-zhen(曹治权，孙作民，孙爱贞). Trace Elements and Traditional Chinese Medicine(微量元素与中医药). Beijing：The Traditional Chinese Medicine Press of China(北京：中国中医药出版社), 1993. 85.
[8] ZHUGE Chun-ying(诸葛纯英). Guangxi Journal of Traditional Chinese Medicine(广西中医药), 1989, 12(5): 46.
[9] KONG Xiang-rui(孔祥瑞). The Effect of Trace Element in Nutrition, Physiology and Clinical Application(必需微量元素的营养、生理及临床意义). Hefei: Anhui Science and Technology Press(合肥: 安徽科技出版社), 1982. 51.
[10] CAI Mei-qin(蔡美琴). Medicine and Nutrition(医学营养学). Shanghai: The Press of Scientific Technology and Publication in Shanghai(上海：上海科学技术文献出版社), 2001. 31.
[11] GUO Zi-jian, SUN Wei-yin(郭子建，孙为银). Bioinorganic Chemistry(生物无机化学). Beijing: Science Press(北京：科学出版社)，2006. 2.
[12] RUI Li-xin(芮立新). Studies of Trace Elememets and Health(微量元素与健康研究), 1995, 12(1): 18.
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