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| Study on the Compositional Characteristics and Colour of Oil Spot Glaze of Jian Kiln in the Song Dynasty Based on Spectral Analysis |
| JIANG Cai-shui1, WU Jun-ming1*, ZHOU Jian-er1, BAO Qi-fu1, LIU Kun2, ZHENG Nai-zhang1 |
1. Archaeology and Cultural Heritage Institute, Jingdezhen Ceramic University, Jingdezhen 333403, China
2. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
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Abstract Black-glazed porcelain holds a significant place in the history of Chinese ceramics, with Song dynasty Jian kiln oil spot glazes being highly esteemed for their distinctive colors and patterns. To elucidate the compositional characteristics and underlying causes of the varying colors in oil spot glazes, we employed energy dispersive X-ray fluorescence (EDXRF), colorimetry, scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS), micro-focused Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) to analyze the composition, microstructure, and firing processes of these glazes. The results indicate that the Si/Al ratio of Song dynasty Jian kiln oil spot glazes ranges from 6.77 to 11.15, distinct from other Jian ware glazes. These oil spot glazes are characterized by high silicon, high potassium, low calcium, low iron, and low titanium content, suggesting a unique formulation. There is a significant difference in elemental distribution inside and outside the crystalline spots, with calcium, iron, titanium, and phosphorus being enriched within them, playing a crucial role in their formation. No significant differences were observed in the chemical composition of oil spot glazes with different colors, indicating that composition is not the primary determinant of coloration. Instead, analysis of iron ion valence states in the glaze and body color suggests that the firing atmosphere is a key factor influencing the type and size of precipitated crystals. When the Fe2+/Fe3+ ratio is high, the body color tends to be darker, indicating a predominantly reducing atmosphere. The silver-white spots are caused by strong light reflection from aggregated ε-Fe2O3 nanocrystals or α-Fe2O3 crystalline films. Conversely, when the Fe2+/Fe3+ ratio is low, the body color tends to be reddish, indicating an oxidizing atmosphere. The brownish-yellow and reddish-brown spots primarily result from the chemical color of 5～10 μm snowflake-shaped ε-Fe2O3 and α-Fe2O3 crystals. The coupling effect between chemical and structural colors can modulate the glaze's coloration. Yellow-green spots with a blue tint arise mainly from Rayleigh scattering of 100～200 nm ε-Fe2O3 particles coupled with chemical color, while silver-white spots with a reddish-brown tint result from total reflection by α-Fe2O3 crystalline films coupled with chemical color. This study elucidates the composition and structural characteristics of Song dynasty Jian kiln oil spot glazes, revealing their diverse coloration mechanisms. These findings provide important insights into the technological aspects of Jian black-glazed porcelain and have implications for the innovation and development of iron-based crystalline glazes.
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Received: 2024-05-21
Accepted: 2024-09-05
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Corresponding Authors:
WU Jun-ming
E-mail: woshiwxb@126.com
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[1] YE Wen-cheng(叶文程). Archaeology(考古), 1964, (4): 191.
[2] LI De-jin（李德金）. Archaeology（考古）, 1990, (12): 1095.
[3] LI Jian-an(栗建安). Archaeology（考古）, 1995, (2): 148.
[4] LI Kai(李 凯). Palace Museum Journal(故宫博物院院刊), 2022, (4): 92.
[5] LI Jia-zhi(李家治). Chinese History of Sci-Tech: Volume of Ceramics(中国科学技术史: 陶瓷卷). Beijing: Science Press(北京: 科学出版社), 1998. 206.
[6] CHEN Xian-qiu, HUANG Rui-fu, ZHOU Xue-lin, et al(陈显求, 黄瑞福, 周学林, 等). Journal of Jingdezhen Ceramics Institute(景德镇陶瓷学院学报), 1995, (1): 26.
[7] Dejoie C, Sciau P, Li W D, et al. Scientific Reports, 2014, 4: 4941.
[8] JIANG Cai-shui, FANG Yuan, BAO Qi-fu, et al(江财水, 方 圆, 包启富, 等). Chinese Ceramics(中国陶瓷), 2023, 59(4): 68.
[9] SHI Pei, JIN Zhi-wei, WANG Fen, et al（施 佩, 金志伟, 王 芬, 等）. Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2022, 42(5): 1628.
[10] LI Mei, LI Wei-dong, LU Xiao-ke, et al(李 玫, 李伟东, 鲁晓珂, 等). Journal of the Chinese Ceramic Society(硅酸盐学报), 2020, 48(7): 1134.
[11] Shi X, Yu Y, Sun Q, et al. RSC Advances, 2019, 9(71): 41927.
[12] LIU Han, ZHOU Jian-er, BAO Qi-fu, et al(刘 韩, 周健儿, 包启富, 等). Journal of the Chinese Ceramic Society(硅酸盐学报), 2018, 46(9): 1287.
[13] Shi P, Wang F, Zhu J, et al. Ceramics International, 2018, 44(14): 16407.
[14] Holé C, Ren Z, Wang F, et al. Materials Today Communications, 2022, 33: 104329.
[15] LI Ji-yuan, LIU Chen, ZHANG Hong(李计元, 刘 晨, 张 虹). China Ceramic Industry(中国陶瓷工业), 2023, 30(3): 18.
[16] YANG Zhong-tang, LI Yue-qin, WANG Zhi-hai, et al(杨钟堂, 李月琴, 王志海, 等). Northwestern Geology（西北地质）, 1996, (2): 49.
[17] Stoch P, Goj P, Ciecińska M, et al. Ceramics International, 2020, 46(11): 19146.
[18] Lopez-Sanchez J, Serrano A, Del Campo A, et al. Chemistry of Materials, 2015, 28(2): 511. |
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