| 光谱学与光谱分析 |
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| Determination of 27 Elements in Tobacco by ICP-MS Using Microwave Digestion for Sample Preparation |
| HU Qing-yuan1,2,LI Li3,SHI Jie4,CHEN Zai-gen2,WANG Fang2, WANG An1 |
1.Anhui Institute of Optics and Mechanics, Chinese Academy of Sciences, Hefei 230031, China
2.China National Tobacco Quality Supervision & Test Center, Zhengzhou 450001, China
3.Technical Research and Development Center, China Tobacco Chuanyu Industrial Corporation, Chengdu 610066，China
4.Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China |
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Abstract While the organic and biologically active components in tobacco smoke are well characterized, it is also important to know which inorganic elements are contained in tobacco. In the present paper, the determination of Be, Na, Mg, K, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Mo, Ag, Cd, Sn, Cs, Ba, Hg, Tl, Pb, Th and U in tobacco leaves was studied by inductively coupled plasma mass spectrometry. Samples were digested in a mixture of nitric acid and hydrogen peroxide by closed-vessel microwave digestion. The instrumental operating conditions were optimized for the measurement of above 17 elements. Ge, In and Bi were used as internal standard elements to compensate matrix effect and signal drift. The precision of measurement ranges from 1.28% to 9.18% in terms of relative standard deviation. The recoveries for spiking tobacco samples and the limits of detection are in the range of 93.64%-108.9% and 0.356 3 ng·L-1-1.725 μg·L-1,respectively. The results of experiment show that the method can meet the requirements of trace analysis.
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Received: 2005-12-19
Accepted: 2006-04-06
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Corresponding Authors:
HU Qing-yuan
E-mail: huqy@ztri.com.cn
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| Cite this article: |
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HU Qing-yuan,LI Li,SHI Jie, et al. Determination of 27 Elements in Tobacco by ICP-MS Using Microwave Digestion for Sample Preparation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(06): 1210-1213.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2007/V27/I06/1210 |
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