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| Review on the Application of X-Ray Fluorescence Spectrometry in Halogen Elements Analysis in Geological Materials |
| LI Xiao-li1, GAO Xin-hua2, WANG Yi-min3*, DENG Sai-wen3, WANG Yi-ya3, LI Song3 |
1. Institute of Geophysical and Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China
2. Central Iron & Steel Research Institute, Beijing 100081, China
3. National Research Center for Geoanalysis, Beijing 100037, China
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Abstract Halogen elements fluorine, chlorine, bromine and iodine are widely distributed in the geosphere, hydrosphere and biosphere. They are mineral resources and information indicators of many geoscience studies, closely related to human life. Halogen element analysis is an important part of the geological analysis, and the XRF analytical method occupies an important position in the halogen group element analysis today. A total of 137 articles of determination of halogen elements fluorine, chlorine, bromine and iodine by X-ray fluorescence spectrometer in geological materials were collected from 1988 to 2020. Based on the brief description of the natural forms of existence, analytical technology, characteristics of fluorine, chlorine, bromine, iodine X-ray spectrum and the conditions of modern X-ray fluorescence spectrometry instruments, the application of X-ray fluorescence spectrometry in fluorine, chlorine, bromine and iodine analysis was reviewed. Sample types include: halide mineral (halogen as main component）, rock (halogen as minoror trace component), ore, marine sample, coal and oil, natural brine, biological sample and geochemical survey sample based on soil and sediment. For minerals of F and Cl as principal components, the accuracy (RSD) can reach <0.5% level; F，Cl，Br and I, in trace elements, the detection limit levels (powder tablet preparation) in most literature are : <50, <20, <1.0 and <10 μg·g-1 respectively. So far, two papers have reported the determination of the F，Cl，Br and I elements in the pressed pellet successively. Whether for geological analysis, or for X-ray fluorescence spectrometry analysis, it is significant progress. The article finally points out that X-ray fluorescence spectrometry has become an important method for analyzing halogen elements in geological materials. Due to its unique advantages of simple, rapid, economic, pollution-free and simultaneous determination of multiple elements, it will play a greater role in the analysis of halogen elements in the future. At the same time, it also reminds the instability of Cl in determination and the typical significance of halogen element analysis in XRF analysis. There were 154 citations in the paper.
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Received: 2021-02-19
Accepted: 2021-05-18
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Corresponding Authors:
WANG Yi-min
E-mail: wym7852@126.com
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