| 光谱学与光谱分析 |
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| Spectral Characteristics of Ce3+ in Alkali-Alkaline Earth Borate System |
| WANG Zhi-jun, LI Pan-lai*, GUO Qing-lin, YANG Zhi-ping, CHEN Jin-zhong |
| College of Physics Science & Technology, Hebei University, Baoding 071002, China |
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Abstract Alkali-alkaline earth borate LiCaBO3∶Ce3+, LiSrBO3∶Ce3+ and LiBaBO3∶Ce3+ were investigated by solid-state method. CaCO3(99.9%), SrCO3(99.9%), BaCO3(99.9%), Li2CO3(99.9%), Na2CO3(99.9%), K2CO3(99.9%), H3BO3(99.9%) and CeO2(99.9%) were used as starting materials, After these individual materials were blended and ground thoroughly in an agate mortar, the homogeneous mixture was heated at 700 ℃ for 2 h in a reduced atmosphere (5∶95(H2/N2)), and these three phosphors were obtained. The excitation and emission spectra of these phosphors were measured by a SHIMADZU RF-540 fluorescence spectrophotometer. The spectral characteristics of Ce3+ in alkali-alkaline earth borate LiCaBO3, LiSrBO3 and LiBaBO3 were investigated. The emission spectra of Ce3+ in these three phosphors all exhibited a dissymmetrical band, and the emission peaks were located at 428, 436 and 440 nm, respectively. The excitation spectra for 428, 436 and 440 nm emission of these three phosphors showed a dissymmetrical band at 364, 369 and 370 nm, respectively. The effects of Li+, Na+ and K+ on the emission intensities of these three phosphors were studied. The results show that the emission intensities of these phosphors were enhanced, and the maximal emission intensity of doping Li+ is higher than that of Na+ and K+.
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Received: 2009-03-06
Accepted: 2009-06-08
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Corresponding Authors:
LI Pan-lai
E-mail: lipanlai@sohu.com
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[1] LI Pan-lai, WANG Zhi-jun, YANG Zhi-ping, et al(李盼来, 王志军, 杨志平, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2009, 29(1): 244.
[2] Ho Seong Jang, Jong Hyuk Kang, Yu-Ho Wonm Sora Lee, et al. Applied Physics Letters, 2007, 90: 071908.
[3] Joung Kyu Park, Chang Hae Kim, Seung Hyok Park, et al. Applied Physics Letters, 2004, 84(10): 1647.
[4] Liu Ru-shi, Liu Yu-huan, Nitin C Bagkar, et al. Applied Physics Letters, 2007, 91: 061119.
[5] Piao Xiaoqing, Machida Ken-ichi, Horikawa Takashi, et al. Journal of The Electrochemical Society, 2008, 155: J17.
[6] Sivakumar V, Varadaraju U V. Journal of The Electrochemical Society, 2007, 154(5): J167.
[7] Hu Yunsheng, Zhuang Weidong, Ye Hongqi, et al. Journal of Alloys and Compounds, 2005, 390: 226.
[8] Tang Yu-sheng, Hu Shu-fen, Lin Chun-che, et al. Applied Physics Letters, 2008, 93: 131114.
[9] Hu Yunsheng, Zhuang Weidong, Ye Hongqi, et al. Journal of Luminescence, 2005, 111: 139.
[10] Yang Zhiping, Wang Shaoli, Yang Guangwei, et al. Materials Letters, 2007, 61(30): 5258.
[11] Guo Chongfeng, Luan Lin, Xu Yan, et al. Journal of the Electrochemical Society, 2008, 155: J310.
[12] Chang Chun-kuei, Chen Teng-ming. Applied Physics Letters, 2007, 91: 081902.
[13] Vengala B Rao, Rambabu U, Buddhudu S. Physica B, 2007, 391: 339.
[14] Manam J, Sharma S K. Journal of Materials Science, 2004, 39(20): 6203.
[15] Li Panlai, Wang Zhijun, Yang Zhiping, et al. Materials Letters, 2009, 63: 751.
[16] WANG Zhi-jun, LI Pan-lai, WANG Ying, et al(王志军, 李盼来, 王 颖, 等). Acta Physica Sinica(物理学报), 2009, 58(2): 1257.
[17] Sun L D, Qian C, Liao C S, et al. Solid State Communications, 2001, 119: 393.
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