Mass Spectrometric Methods for Colorative Mechanism Analysis of Yaozhou Porcelain Glaze
XIAO Yuan-fang, HE Miao-hong, ZHANG Shu-di, HANG Wei*
Department of Chemistry and Ministry of Education Key Lab of Spectrochemical Analysis & Instrumentation, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Abstract:An in-house-built femtosecond laser ionization time-of-flight mass spectrometry (fs-LI-TOFMS) has been applied to the multi-elemental analysis of porcelain glaze from Yaozhou kiln. The samples are selected representing products of different dynasties, including Tang, Five, Song, Jin, and Ming Dynasty. For exploring the colorative mechanism of Yaozhou porcelain through the elemental analysis of the glaze, the effects of all potential coloring elements, especially transition elements, were considered. There was a speculation that the typical Co-Cr-Fe-Mn recipe was used in the fabrication of Yaozhou black glaze; the low content of Fe and high content of Ni resulted in the porcelain of white glaze; an increase content of P could lead the porcelain to be yellow-glazed. Undoubtedly, this research is an important supplement to the study of the colorative mechanism of the Yaozhou porcelain system.
Key words:Yaozhou kiln;Laser ionization mass spectrometry;Coloring elements;Colorative mechanism
[1] ZHU Jian-feng, SHI Pei, WANG Fen, et al(朱建锋,施 佩,王 芬,等). Journal of Shanxi University of Science & Technology(Natural Science)(陕西科技大学学报·自然科学版), 2014, 32(2): 36. [2] LIANG Fu-liu, LUO Hong-jie(梁福鎏,罗宏杰). Journal of the Chinese Ceramic Society(硅酸盐学报),1997,25(1): 78. [3] LI Guo-xia, GAO Zheng-yao, ZHAO Wei-juan, et al(李国霞,高正耀,赵维娟,等). Science of Conservation and Archaeology(文物保护与考古科学),2004, 16: 1. [4] YANG Da-wei, JI Yong, LI Rong-wu, et al(杨大伟,冀 勇,李融武,等). Journal of Ceramics(陶瓷学报),2010, 31: 190. [5] LI Rong-wu, LI Guo-xia, ZHAO Wei-juan, et al(李融武,李国霞,赵维娟,等). Journal of Beijing Normal University(Natural Science)(北京师范大学学报·自然科学版),2003,39: 201. [6] Yoonyeol Yoon, Taesam Kim, Myeongkwon Yang, et al. Microchemical Journal, 2001, 68: 251. [7] Allayth Aldrabee, Abdul-Halim Wriekat. Microchemical Journal,2011,99: 289. [8] Resano M, Pérez-Arantegui J, Garcia-Ruiz E, et al. Journal of Analytical Atomic Spectrometry, 2005, 20: 508. [9] Zhang Bochao, Zou Dongxuan, Huang Rongfu, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2013, 85: 13. [10] FANG Tao, WU Jun, WU Jun-ming, et al(方 涛,吴 隽,吴军明,等). Journal of Ceramics(陶瓷学报),2011, 32(1): 41. [11] Wu Jun, Zhang Maolin, Wu Junming, et al. Science China Technological Sciences, 2011, 54: 99. [12] HUANG Zhao-bai(黄照柏). Ceramic Research and Vacational Education(陶瓷研究与职业教育),1980,4: 003. [13] REN Yun-peng, ZHANG Jin-zhao(任允鹏,张金钊). Shandong Ceramics(山东陶瓷),2013, 6: 3. [14] Zhang Bin, Gao Zhengyao, Zhao Weijuan, et al. Applied Clay Science, 2004, 25: 161. [15] Peng H Y, Xie Z, He J F, et al. Journal of Physics: Conference Series, IOP Publishing, 2013, 430: 012136. [16] Zhu Tiequan, Sun Weidong, Zhang Hong, et al. Archaeometry, 2012, 54: 475. [17] LUO Hong-jie, LI Jia-zhi(罗宏杰,李家治). Bulletin of the Chinese Ceramic Society(硅酸盐通报),1995, 14: 50. [18] LIU Shi-ming, ZENG Ling-ke, SHUI An-ze, et al(刘世明,曾令可,税安泽,等). Ceramics(陶瓷),2007, 5: 32. [19] Jong-Young Kim, Hyunggoo No, A Young Jeon, et al. Ceramics International, 2011, 37: 3389.