Traceability of Wine Varieties Using Near Infrared Spectroscopy Combined with Cyclic Voltammetry
LI Meng-hua1, LI Jing-ming2*, LI Jun-hui1, ZHANG Lu-da1, ZHAO Long-lian1*
1. College of Information & Electrical Engineering, China Agricultural University, Beijing 100083, China 2. College of Food Science & Nutrition Engineering, China Agricultural University, Beijing 100083, China
Abstract:To achieve the traceability of wine varieties, a method was proposed to fuse Near-infrared (NIR) spectra and cyclic voltammograms (CV) which contain different information using D-S evidence theory. NIR spectra and CV curves of three different varieties of wines (cabernet sauvignon, merlot, cabernet gernischt) which come from seven different geographical origins were collected separately. The discriminant models were built using PLS-DA method. Based on this, D-S evidence theory was then applied to achieve the integration of the two kinds of discrimination results. After integrated by D-S evidence theory, the accuracy rate of cross-validation is 95.69% and validation set is 94.12% for wine variety identification. When only considering the wine that come from Yantai, the accuracy rate of cross-validation is 99.46% and validation set is 100%. All the traceability models after fusion achieved better results on classification than individual method. These results suggest that the proposed method combining electrochemical information with spectral information using the D-S evidence combination formula is benefit to the improvement of model discrimination effect, and is a promising tool for discriminating different kinds of wines.
Key words:Red wine;Variety;Near Infrared Spectroscopy;Cyclic Voltammetry;D-S evidence theory
李梦华1,李景明2*,李军会1,张录达1,赵龙莲1* . 近红外光谱法与循环伏安电化学法联用进行葡萄酒品种溯源研究 [J]. 光谱学与光谱分析, 2015, 35(06): 1551-1555.
LI Meng-hua1, LI Jing-ming2*, LI Jun-hui1, ZHANG Lu-da1, ZHAO Long-lian1* . Traceability of Wine Varieties Using Near Infrared Spectroscopy Combined with Cyclic Voltammetry. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(06): 1551-1555.
[1] CHEN Yu-qing(陈玉庆). Liquor-Making Science &Technology(酿酒技术), 2004, 31(5): 311. [2] LI Hua(李 华). Wine Tasting Glossary(葡萄酒品尝学). Beijing: Science Press(北京:科学出版社), 2006. [3] LAI Yu-kun, WANG Wei(赖宇坤,王 炜). Electrochemistry(电化学), 2011, 17(1): 102. [4] Paul A Kilmartin, Zou Honglei, Andrew L. Waterhouse. Am. J. Enol. Vitic., 2002,53(4): 294. [5] Olga Makhotkina, Paul A Kilmartin. Journal of Electroanalytical Chemistry, 2009, 633: 165. [6] Paul A Kilmartin, Zou Honglei, Andrew L. Waterhouse. J. Agric. Food Chem., 2001, 49: 1957. [7] LIANG Ying-ping, LIU Xing-zhi, LI Jing-ming, et al(梁迎萍,刘行知,李景明, 等). Liquor-Making Science & Technology(酿酒科技), 2009, 7 (181):43. [8] YAN Yan-lu, ZHAO Long-lian, YANG Shu-ming, et al(严衍禄,赵龙莲,杨曙明,等). Foundation of NIR Spectral Analysis and Its Application(近红外光谱分析基础与应用). Beijing: China Light Industry Press(北京: 中国轻工业出版社), 2005. [9] YANG Feng-bao, WANG Xiao-xia(杨风暴,王肖霞). Combination Method of Confliction Evidence in D-S Evidence Theory(D-S证据理论的冲突证据合成方法). 2nd Ed(第2版). Beijing: National Defence Industry Press(北京:国防工业出版社),2010. [10] Tian Junfeng,Zhai Jianqiang,Du Ruizhong. Journal of Electronics (China), 2005, 30(6): 261. [11] ZHUO Li-bo, WANG Ping(赵立波,王 平). Microcomputer Information(微计算机信息), 2010, 26(7-1):120. [12] LUN San-lan, CHEN Ming-dong(陆三兰,程铭东). Microelectronics & Computer(微电子学与计算机), 2011, 28(1): 95.