Abstract：The conductivity of the porous polymer solid electrolyte blended with PVDF and PMMA，which was made by a micro-wave hot-cross-linking method，reached 2.05×10-3 S·cm-1 at room temperature. The polymer solid electrolyte was analyzed and investigated by FTIR. The results show that the PVDF, PMMA and LiClO4 in the polymer solid electrolyte were not simply blended, but certain kind of effect eｘisted which was strengthened only when the polymer solid electrolyte came into being.
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