Synthesis and Spectral Properties of Tailed Sercine Tetraphenylporphyrin Cobalt Complex
NI Chun-lin1 ，ZHOU Chun-qiong1，ZHOU Yu1，HE Zhi-ke2, YUAN Liang-jie2
1. College of Chemistry and Life Science，Three Gorges University，Yichang 443003，China 2. College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072，China
Abstract：A new tailed sercine tetraphenylporphinatozinc, 5-(p-butoxyphenyl-10,15,20-trichlorophenyl)porphine and cobalt complex(Co[Ser-TPP]) was synthesized and characterized by elementary analysis, UV, IR , 1HNMR and Raman spectra. The electronic absorption spectra of axial coordination reactions of Co[Ser-TPP] with pyridine, 4-methylpyridine, 4-aminopyridine, 4，4-bipyridine，imidazole，1-methylimidazole and 2-methylimidazole were inverstigated. The results showed that the changes of electronic absorption spectra of Co[Ser-TPP] could be attributed to the axial coordination reactions of Co[Ser-TPP] with pyridine and imidazole series.
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