Abstract:A new Schiff base containing sulphur, 1-phenyl-3-methyl-4-(α-furoyl)pyrazolone-5-thiosemicarbazone (HL) and its Zn(Ⅱ), Cd(Ⅱ) and Co(Ⅱ) complexes have been synthesized. On the basis of elemental analysis and molar conductance, the general formulae of the complexes, [ZnL2]·1.5H2O, [CdL2]·C2H5OH and [CoL2]·H2O, were given. They were characterized by IR, UV-Visible, 1H NMR, 13C NMR and magnetic moments. The results show that the metal ions exhibit coordination of six in the complexes. The antibacterial experiments indicate that they have high antibacterial activities against S. aureus, B. subtilis, E. coli, E. carotovora, and C. flaccumfaciens.
[1] LI Jin-zhou et al. J. Rare Earths, 2000, 18(3): 233. [2] LI Jin-zhou et al(李锦州等). Chinese J. of Inorg. Chem.(无机化学学报), 2001, 17(6): 888. [3] LI Jin-zhou, AN Yu-mei, YU Wen-jin,SHA Jing-quan(李锦州,安郁美,于文锦,沙靖全). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(6): 938. [4] Geary W J. Coord. Chem. Rev., 1971, 7: 81. [5] Faniran J A et al. J. Inorg. Nucl. Chem., 1974, 36: 1547. [6] Ueno K et al. J. Phys. Chem., 1955, 59: 988. [7] Mital S P et al. Synth. Seact. Inorg. Met. Org. Chem., 1981, 11(6): 547. [8] Biradar N S et al. J. Inorg. Nucl. Chem., 1974, 36: 1915. [9] Figgis B N et al. J. Pro. Inorg. Chem., 1964, 6: 192. [10] Khoo L E, Smith F E. Polyhedron, 1982, 1(2): 213. [11] XIE Xiao-juan et al(谢筱娟等). Chinese J. of Appl. Chem.(应用化学), 1992, 9(6): 52.