Micro-FTIR Study on Structure of Macerals from Jurassic Coals in Northwestern China
CHANG Hai-zhou1,2,ZENG Fan-gui1*,LI Wen-ying1, LI Jun1,2,JIA Jian-bo1,XIE Ke-chang1
1. Key Laboratory of Coal Science and Technology for Ministry of Education and Shanxi Province，Research Group for Physical Chemistryof Minerals and Environmental Geochemistry, Department of Earth Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China 2. College of Chemistry and Chemical Engineering, Jinzhong College, Jinzhong 030600, China
Abstract：Jurassic coal in Northwest China is rich in resources and it is a necessary premise to reveal the chemical structure characteristics of the coal macerals in this region before the coal is put into reasonable and efficient use. Micro-FTIR technique was used to investigate the chemical composition and structures of vitrinite semifusinite and fusinite from Jurassic coal in Northwestern China. The results show that vitrinite and semifusinite have more aliphatic hydrogen, but fusinite has more aromatic hydrogen and C=O structure. The aliphatic hydrogen in semifusinite is higher than that in fusinite and it is this structure characteristic of semifusinite that led to the richer inertinite but higher reactivity of the Northwestern China coal. Not only vitrinite but also semifusinite and fusinite with weaker reducibility have less aliphatic hydrogen and more C=O structures than those with stronger reducibility. The different intensity of oxidation in the process of coalification is one of the causes that led to different type of reducibility.
Key words：Jurassic coal in north-western China;Macerals;Micro-FTIR;Chemical structure;Reducibility
常海洲1,2,曾凡桂1*,李文英1,李 军1,2,贾建波1,谢克昌1. 西北地区侏罗纪煤显微组分结构的Micro-FTIR研究[J]. 光谱学与光谱分析, 2008, 28(07): 1535-1538.
CHANG Hai-zhou1,2,ZENG Fan-gui1*,LI Wen-ying1, LI Jun1,2,JIA Jian-bo1,XIE Ke-chang1. Micro-FTIR Study on Structure of Macerals from Jurassic Coals in Northwestern China. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(07): 1535-1538.
