Synthesis, Characterization and Fluorescent Properties of o, m, p-(Methacrylamido) Benzoic Acid
JIN Zheng-neng1,LU Jian-mei1, 2*,XU Qing-feng1,WANG Li-hua1
1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University，Suzhou 215006, China 2. Jiangsu Polytechnic University, Changzhou 213016, China
Abstract：o, m, p-(Methacrylamido)benzoic acid (o, m, p-MAABA) was synthesized from o, m, p-aminobenzoic acid (o, m, p-ABA), elemental analysis and 1H NMR were used to confirm these compounds. The fluorescent properties of the compounds were investigated. The result showed that o, p-MAABA has λexmax at 358 nm while m-MAABA has λexmax at 324 nm. Excited at λexmax, o-MAABA had the strongest fluorescence, while p-MAABA had the weakest, and all of them were round at 420 nm.
[1] Pope M，Kallmann H P，Magnante P. J. Chem. Phys.，1968, 38: 2042. [2] Tang C W，Vanslyke S A. Appl. Phys. Lett.，1987, 51: 913. [3] Li J Y，Liu D，Ma C，et al. Adv. Mater.，2004, 16(17): 1538. [4] De Silve A P，Gunaratne H Q N，Gunnlaugsson T，et al, Chem. Rev.，1997, 97(5): 1515. [5] Pei J，Yu W L，Huang W，et al. Macromolecules，2000, 33(7): 2462. [6] Moylan C R，McNelis B J，Nathan L C，et al. Org. Chem.，2004, 69(24): 8239. [7] Tirapattur S, Belletete M，Drolet N，et al. Macromolecules，2002, 35(23)：8889. [8] Tanto B，Guha S，Martin C M，et al. Macromolecules，2004，37(25)：9438. [9] Belfield K D，Morales A R，Kang B S，et al. Chem. Mater.，2004, 16(23)：4634. [10] Chen C T，Chiang C L，Lin Y C，et al. Org. Lett.，2003, 5(8)：1261. [11] Swanson S A，Wallraff G M，Chen J P，et al. Chem. Mater.，2003, 15(12)：2305. [12] Lee M T，Yen C K，Yang W P，et al. Org. Lett.，2004, 6(8)：1241. [13] LIU Hai-bin(刘海滨). Foreign Oilfield Engineering(国外油田工程)，2001, 17(9)：53. [14] ZHANG Xiao-lin，HAN Qing(张效林，韩 卿). Paper Chemicals(造纸化学品)，2003, 15(3)：11. [15] YAN Rui-xuan(严瑞瑄). Water-Soluble Polymer(水溶性高分子). Beijing: Chemical Industry Press(北京：化学工业出版社), 1998. 159. [16] Chen W M，Yuan Y，Yan L F. Materials Research Bulletin，2000，35(5)：807. [17] Choudhary V，Mishra A. J. Appl. Polym. Sci.，2000, 78(2)：259. [18] Ling Q D，Kang E T，Huang W. Macromolecules，2003, 36(19)：6995. [19] LIU Jun-feng, TENG Feng, XU Zheng, et al(刘峻峰，腾 枫，徐 征，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2004, 24(5)：519. [20] LU Jian-mei，DAI Wei-quan, JI Shun-jun, et al(路建美，戴魏荃，纪顺俊，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(6): 990. [21] Bain D I，Smalley R K. J. Chem. Soc.(c), 1968, 1593. [22] Hamruo Y，Geib S J，Hamilton A D. J. Am. Chem. Soc.，1996, 118(32)：7529.
