REN Dong-wen1, BAO De-cai1, 2, WANG Wei1,MA Xiao-jun1*
1. Lab Biomedical Materials Engineering, Dalian Institute of Chemical Physics, Graduate School of Chinese Academy of Sciences, Dalian 116023, China 2. College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000, China
Abstract：The degree of N-deacetylation (DD) is an important property of chitosan. In the present article the reaction of N-acetylation was applied to prepare six chitosan samples with various DDs. The samples were studied by FTIR and XRD to investigate their IR absorbance characteristics and crystallinity, from which the DDs and crystallinity index (CrI) of chitosans were also determined respectively. The influence of N-acetylation on DD and CrI was also discussed，and it could be found from FTIR that the N-acetylation reaction became difficult for the remaining amino group in chitosan molecule as the reaction proceeded. XRD also indicated that the crystalline zone was broken by N-acetylation gradually，and another kind of crystal form appeared instead.
Key words：Chitosan;N-acetylation;Degree of deacetylation;Crystallinity
任东文1,包德才1, 2,王为1,马小军1* . N-乙酰化壳聚糖的FTIR和XRD研究[J]. 光谱学与光谱分析, 2006, 26(07): 1217-1220.
REN Dong-wen1, BAO De-cai1, 2, WANG Wei1,MA Xiao-jun1* . Study on N-Acetylated Chitosans by FTIR and XRD. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(07): 1217-1220.
[1] Tomihata K, Ikada Y. Biomaterials, 1997, 18: 567. [2] Shi Xin-yuan, Tan Tian-wei. Chinese J. Chem. Eng., 2003, 11(1): 94. [3] Chenite A, et al. Biomaterials, 2000, 21: 2155. [4] Chang K L B, et al. Carbohyd. Res., 1997, 303: 327. [5] Hirano S, et al. Carbohyd. Res., 1976, 47: 315. [6] Khor E. Chitin: Fulfilling a Biomaterials Promise. Elsevier, Amsterdam, 2001. [7] Prashanth K V H, et al. Carbohyd. Polym., 2002, 50: 27. [8] Samuels R J. J. Polym. Sci. Polym. Phys., 1981 19: 1081. [9] Aiba S. Int. J. Biol. Macromol., 1991, 13: 40. [10] MA Xiao-li, YAO Zi-hua(马晓莉, 姚子华). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(3): 456.
