Abstract:The nanocrystalline ZrO2∶Pr3+and ZrO2∶Pr3+,Sm3+ powders with room temperature sharp characteristic emissions were prepared by coprecipitation method. Luminescence properties of nanocrystalline ZrO2∶Pr3+ with different sintering temperatures and doping concentrations were studied. The energy transfer between the nanocrystalline ZrO2 host and the dopants was observed. The different Pr3+ concentration dependence of emission intensities of levels 3P0 and 1D2 was discussed. The dependence on Pr3+ concentration in nanocrystalline ZrO2∶Pr3+,Sm3+ of the emission intensity of 4G5/2—6H7/2 transitions of Sm3+ ions and the energy transfer between Pr3+ and Sm3+ ions were investigated and discussed.
Key words:Photoluminescence;Coprecipitation method;Nanocrystalline ZrO2∶Pr3+;ZrO2∶Pr3+;Sm3+;Energy transfer
[1] Ian M. Thomas. SPIE., 1994, 2288: 50. [2] Pereyra-perea E, Estrada M R, Garcia M. J. Phys. D, 1998, 31: L7. [3] Patra A, Friend C S, Kapoor R, et al. J. Phys. Chem. B, 2002, 106: 1909. [4] LIU Huang-qing, et al(刘晃清,等). Chin. J. Lumin.(发光学报), 2002, 23(6): 628. [5] LIU Huang-qing, QIN Guan-shi, LIN Hai-yan, et al(刘晃清,秦冠仕,林海燕, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(1): 9. [6] QI Ze-ming, WANG Zheng, LI Fu-li, et al(戚泽明,王 征,李福利, 等). Chin. J. Lumin.(发光学报), 2002, 23(3): 301. [7] Petrik N G, Taylor D P, Orlando T M. J. Appl. Phys., 1999, 85: 6770. [8] Savoini B, Munoz Santiuste J E, Goznales R. Phys. Rev. B, 1997, 56: 5856.