Abstract:In order to solve the premature rupture of degradable mulch film due to degradation, the stability and degradation of PPC plastic film were studied under different mulching methods. The six mulching methods in the field were as follow: single-layer black PPC plastic film (SB), single-layer white PPC plastic film (SW), double black PPC plastic film (DB), double-white PPC plastic film (DW), double-layer mulch which upper layer was black and the lower layer was white (DBW), the double layer mulch which upper layer was white and the lower layer was a black (DWB). The infrared spectrum characteristics, mechanical properties and molecular weight of film periods were determined at a different time to judge the degradation of the plastic film under different treatments. The results showed that plastic film was exposed to conditions for a long time, and the toughness of plastic film has become worse. The main chain in the molecular structure was broken, furthermore, the relative intensity of the absorption peak of the C—H bond and C—O bond decreases with the increase of time. Due to the degradation of mulch film under the action of water molecules and microorganisms, the relative intensity of theC═O stretching vibration peak and C—O—C antisymmetric absorption peak increased in different degrees. Due to the adhesion of molecular chain activity under sunlight, the stability of double-layer plastic film was higher than that of single-layer plastic film. Therefore, the decreasing trend of peak intensity for black and white double-layer plastic film DWB and DBW was more stable than that for single mulching film. The degradation degree was more slowly. The molecular weight and mechanical properties of each treatment showed a downward trend. The molecular weight. Tensile strength and elongation at the break of the double-layer plastic film were significantly higher than that of single-layer plastic film treatment. The stability of DWB and DBW treatments was stronger than that for the single mulching film within 30~150 days. The elongation at break and tensile strength of DWB and DBW treatments were 117.66%~120.39%, 151.69%~175.20% and 18.28~13.95, 15.35~9. 81 MPa at 150 days. The average molecular weights and number average molecular weights of DWB and DBW treatments were 72 663, 66 555 and 62 416, 66 555 g·mol-1. Comprehensive analysis showed that black and white double-layer plastic film could slowly cause the rupture of the plastic film caused by the degradation of PPC plastic film, Which could improve the time for the performance of water conservation and soil moisture conservation and better take advantage of the double-layer mulch film. After the optimization of the coverage methods of PPC plastic film, PPC plastic film could maintain its stability during the crop growth period, and it also could be degraded like a single layer mulch film after the crop growth period, which provided a theoretical basis for the further use of PPC film in agricultural production.
[1] YU Wang, WANG Chao-yun, YI Yong-jian, et al(余 旺, 王朝云, 易永健, 等). Plastics Science and Technology(塑料科技), 2019, 47(12): 156.
[2] YAN Chang-rong, HE Wen-qing, XUE Ying-hao, et al(严昌荣, 何文清, 薛颖昊, 等). Chinese Journal of Biotechnology(生物工程学报), 2016, 32(6): 748.
[3] MEI Li, DONG Wen-yi, ZHOU Ji-hua, et al(梅 丽, 董雯怡, 周继华, 等). Journal of China Agricultural University(中国农业大学学报) , 2021, 26(10): 54.
[4] MIN Wen-hao, WANG Chun-li, WANG Li-wei, et al(闵文豪, 王春丽, 王莉玮, 等). Environmental Science(环境科学), 2022, 43(1): 560.
[5] LI Xia, GU Wen-jie, YANG Shao-hai, et al(李 夏, 顾文杰, 杨少海, 等). Acta Microbiologica Sinica(微生物学报), 2019, 59(1): 56.
[6] JIN Tuo, XUE Ying-hao, ZHANG Ming-ming, et al(靳 拓, 薛颖昊, 张明明, 等). Ecology and Environment(生态环境学报), 2020, 29(2): 411.
[7] Cao Y J, Cheng Z D, Zheng B H, et al. Journal of Anhui Agricultural Sciences, 2015, 43(6): 258.
[8] Zhang Zhiyou, Xie Peigeng, Dai Minghua. Hans Journal of Agricultural Sciences,2018, 8(8): 848.
[9] LI Kai-yu, XIAO Ji-bing, YANG Ning, et al(李开宇, 肖继兵, 杨 宁, 等). Soil and Fertilizer Sciences in China(中国土壤与肥料), 2019,(5): 194.
[10] ZHAN Yi-chuan, SHAO Yu-lan, ZONG De-qin(张一川, 邵榆岚, 宗德琴). Modern Agricultural Science and Technology(现代农业科技), 2016,(22): 155.
[11] JIN Jing, LU Yao(金 璟, 路 遥). Ecological Economy(生态经济), 2021, 37(7): 111.
[12] Pan Hongwei. Korean Journal of Chemical Engineering, 2017, 34(5): 1294.
[13] Oluwadamilola Phillips, Jared M Schwartz, Paul A Kohl. Polymer Degradation and Stability,2016, 125: 129.
[14] CAI Yi, GAO Feng-xiang, ZHANG Ya-ming, et al(蔡 毅, 高凤翔, 张亚明, 等). Journal of Functional Polymers(功能高分子学报), 2020, 33(1): 70.
[15] YANG Li-li, CHEN Ye, YAN Xiao-guang, et al(杨莉莉, 陈 野, 闫晓光, 等). Food Science(食品科学), 2016, 37(2): 214.
[16] FENG Huan, ZHANG Feng-hua, HE Wen-qing, et al(冯 欢, 张凤华, 何文清, 等). Journal of Huazhong Agricultural University(华中农业大学学报), 2019, 38(3): 65.
[17] SONG Xing-yang, WANG Qi, LI Fu-chun, et al(宋兴阳, 王 琦, 李富春, 等). Acta Ecologica Sinica(生态学报), 2017, 37(3): 798.
[18] TANG Wen-xue, MA Zhong-ming, WEI Tao, et al(唐文雪, 马忠明, 魏 焘, 等). J Agric Sci Technol(中国农业科技导报), 2016, 18(5): 126.
[19] LONG Shi-fang, ZHU Qi-hong, ZHOU Jian-li, et al(龙世方, 朱奇宏, 周建利, 等). Research of Agricultural Modernization(农业现代化研究), 2019, 40(2): 349.
[20] YANG Zuo-jun, ZOU Hui-ping, LIN Jun-feng, et al(杨左军, 邹慧萍, 林君峰, 等). Plastics Science and Technology(塑料科技), 2019, 47(10): 132.
[21] XUE Ying-hao, SUN Zhan-xiang, JU Xue-hai, et al(薛颖昊, 孙占祥, 居学海, 等). China Plastics(中国塑料), 2020, 34(5): 87.
[22] Gu Xiaobo, Li Yuannong, Du Yadan. Soil & Tillage Research, 2017, 171: 42.
[23] Shashwat N, Apurba K Das, Mukesh Kumar P, et al. Environmental Challenge,2021, 5: 100280.
[24] OUYANG Chun, MA Xiao-na, ZHANG Yan-fang, et al(欧阳春, 马晓娜, 张延芳, 等). Journal of Aeronautical Materials(航空材料学报), 2017, 37(1): 93.
[25] SI Peng, HAO Ni-yuan, LIU Yang, et al(司 鹏, 郝妮媛, 刘 阳, 等). Plastics Science and Technology(塑料科技), 2015, 43(10): 68.
[26] Kurt Gökçe, Kasgoz Alper. Journal of Applied Polymer Science, 2021, 138(30): 50722.
[27] SANG Lian-yong, YAN Hua, HU Zhi-de, et al(桑练勇, 晏 华, 胡志德, 等) . China Plastics(中国塑料), 2018, 32(11): 116.
[28] FENG Chen, FENG Liang-shan, LIU Qi, et al(冯 晨, 冯良山, 刘 琪, 等). Scientia Agricultura Sinica(中国农业科学), 2021, 54(9): 12.
[29] Datta D, Halder G. Process Safety and Environmental Protection, 2019, 124: 39.
[30] QU Ping, GUO Bao-hua, WANG Hai-bo, et al(曲 萍, 郭宝华, 王海波, 等). Transactions of the Chinese Society of Agricultural Engineering(农业工程学报), 2017, 33(17): 194.
[31] XIAN Jian-hua, ZHANG Feng-xian, YANG Ye-long, et al(谢建华, 张凤贤, 杨业龙, 等). Jiangsu Agricultural Sciences(江苏农业科学), 2017, 45(15): 78.
[32] ZHU Wen-yue, WU Jing-gui, et al(朱文悦, 吴景贵). Acta Agriculturae Boreali-Occidentalis Sinica(西北农业学报), 2020, 29(8): 1250.