Abstract：Atmospheric particulate matter has become the primary pollutant of urban air. Due to the difficulty and high technical requirements of accurately determining the chemical composition of atmospheric particulate matter, corresponding reference materials are needed to ensure the accuracy and traceability of the measurement results. This article summarized the research progress of atmospheric particulate reference materials domestic and overseas in terms of source composition, sample collection, preparation technology, target components and analysis technics. The problems with domestic reference materials of atmospheric particulates were analyzed, including a few matrix types, backward sampling and preparation technology, and shortage of samples. Based on the foreign research experience and China’s major needs for environmental monitoring and governance, research designs were made to ensure the representativeness and practicability of reference materials of atmospheric particulates. The innovation is that based on the composition and source analysis results of atmospheric particulate matter, main source substances should be collected in the study area, and the combination of source substances will be prepared according to the target matrix and content requirements, finally a series of target content candidates sample will be obtained.
Key words：Reference material; Atmospheric particulates; Component analysis; Research progress and design
潘含江，顾铁新，刘 妹，杨 榕，赵 凯，顾 雪. 大气颗粒物成分分析标准物质研究进展与思路[J]. 光谱学与光谱分析, 2022, 42(12): 3659-3664.
PAN Han-jiang, GU Tie-xin, LIU Mei, YANG Rong, ZHAO Kai, GU Xue. Research Progress and Design on Reference Materials of Atmospheric Particulates. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3659-3664.
[1] Kim K H, Kabir E, Kabir S. Environment International, 2015, 74: 136.
[2] Mukherjee A, Agrawal M. Environmental Chemistry Letters, 2017, 5: 283.
[3] Zhu Y H, Huang L, Li J Y, et al. Environment International, 2018, 115: 343.
[4] SHAO Xuan-yi, WANG Xiao-qi, ZHONG Yi-sheng, et al(邵玄逸, 王晓琦, 钟嶷盛, 等). Environmental Science(环境科学), 2021, 42(9): 4095.
[5] LIU Huan-jia, JIA Meng-ke, LIU Yong-li, et al(刘桓嘉, 贾梦珂, 刘永丽, 等). Environmental Science(环境科学), 2021, 42(9): 4140.
[6] Wang Y, Liu H W, Mao G Z, et al. Journal of Cleaner Production, 2017, 165: 1436.
[7] Zhang Z Z, Wang W X, Cheng M M, et al. Atmospheric Environment, 2017, 159: 147.
[8] DANG Ying, ZHANG Xiao-ling, RAO Xiao-qin, et al(党 莹, 张小玲, 饶晓琴, 等). Environmental Science(环境科学), 2021, 42(8): 3622.
[9] DAO Xu, LI Jian-jun, TANG Gui-gang, et al(刀 谞, 李健军, 唐桂刚, 等). Environmental Monitoring in China(中国环境监测), 2019, 35: 16.
[10] Leung P Y, Wan H T, Billah M B, et al. Environmental Pollution, 2014, 194: 188.
[11] TAN Jing，LIU Qiong-yu，JIANG Jun-ting，et al(谈 静, 刘琼玉, 姜郡亭, 等). Journal of Jianghan University·Natural Science Ed.(江汉大学学报·自然科学版), 2014, 42: 9.
[12] Fassett J D, MacDonald B S. Fresenius’ Journal of Analytical Chemistry, 2001, 370: 838.
[13] Zeisler R, Murphy K E, Becker D A. et al. Analytical and Bioanalytical Chemistry, 2006, 386: 1137.
[14] Mitkus R J, Powel J L, Zeisler R, et al. Toxicology in Vitro, 2013, 27: 2289.
[15] Mori I, Sun Z J, Ukachi M, et al. Analytical and Bioanalytical Chemistry, 2008, 391: 1997.
[16] Heller-Zeisler S F, Ondov J M, Zeisler R. Biological Trace Element Research, 1999, 71: 195.
[17] Nishikawa M, Batdorj D, Ukachi M, et al. Analytical Methods, 2013, 5: 4088.
[18] Perez P E, Held A, Charoud-Got J. Development of Particulate Matter Certified Reference Materials (PM10 CRMs). Final Report. 2008, EN, ISBN 978-92-79-08347-1.
[19] HUANG Lin-yan, FANG Li-ping, ZHAO Ya-xian, et al(黄林艳, 房丽萍, 赵亚娴, 等). The Administration and Technique of Environmental Monitoring(环境监测管理与技术), 2017, 29: 2.
[20] Sysalová J, Kučera J, Kotlík B, et al. Analytical and Bioanalytical Chemistry, 2001, 373: 195.
[21] Heller-Zeisler S F, Fajgelj A, Bernasconi G, et al. Fresenius’ Journal of Analytical Chemistry, 1998, 360: 435.
[22] Oster C, Labarraque G, Fisicaro P. Analytical and Bioanalytical Chemistry, 2015, 407: 3035.
[23] Klouda G A, Filliben J J, Parish H J, et al. Aerosol Science and Technology, 2005, 39: 173.
[24] Poster D L, Maria J L, Schantz M M, et al. Polycyclic Aromatic Compounds, 1999, 14: 23.
[25] Dyg S, Anglov T, Christensen J M. Analytica Chimica Acta, 1994, 286(3): 273.
[26] Shang H T, Fan X H, Kubwabo C, et al. Environmental Science and Pollution Research volume, 2019, 26: 7453.
[27] Michele M Schantz, Danielle Cleveland, N Alan Heckert, et al. Analytical and Bioanalytical Chemistry, 2016, 408: 4257.
[28] Currie L A, Benner B A, Kessler J D, et al. Journal of Research of the National Institute of Standards and Technology, 2002, 107(3): 278.
[29] Itoh N, Inagaki K, Narukawa T, et al. Analytical & Bioanalytical Chemistry, 2011, 401(9): 2909.
[30] YAN Hui-fang, XU Bo-hong, XIAO Hong-rui, et al(闫慧芳, 徐伯洪, 萧宏瑞, 等). Chinese Journal of Industrial Hygiene and Occupational Diseases(中华劳动卫生与职业病杂志)，1995, 2: 122.
[31] DAO Xu, ZHANG Lin-lin, WANG Chao, et al(刀 谞, 张霖琳, 王 超, 等). Environmental Chemistry(环境化学), 2015, 34: 60.
[32] YUN Long, LI Cheng-liu, ZHANG Ming-di, et al(云 龙, 李成柳, 张明棣, 等). Environmental Science(环境科学), 2021, 42(9): 4191.
[33] WANG Yi-ya, WANG Yi-min(王祎亚, 王毅民). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(3): 696.
