1. State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074, China
2. Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China
Abstract:Isotope analysis has attracted much attention in various industrial fields dominated by the nuclear industry, and it has promoted the development of geology, materials science, chemistry and other related disciplines. In recent years, the optical isotope analysis method has attracted increasing attention. Mass spectrometry methods, such as multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS), thermal ionization mass spectrometry (TIMS) and isotope ratio mass spectrometry (IRMS), are the standard methods of isotopic analysis. However, they typically require complex sample pretreatment procedures and frequent instrumental maintenance. In this regard, optical isotope analysis methods possess their unique advantages.They can even meet the on-site real-time and rapid isotope analysis, which has already shined in nuclear industry isotope analysis and traditional stable isotope analysis. With the further development of key components of spectroscopy instruments and data processing methods, the performance of spectroscopy analysis, such as sensitivity, resolution and precision, has been greatly improved, so that optical isotope analysis methods have been developed rapidly and applied to the isotope analysis of environmental and geological samples. This article reviews the progress of the optical isotope analysis methods, classified into emission spectroscopy (atomic emission spectroscopy, molecular emission spectroscopy and Raman spectroscopy) and absorption spectroscopy (atomic absorption and molecular absorption) from the perspective of the principle of spectroscopic analysis. It mainly focuses on the basic principle, development history and important progress of these methods, and the advantages, and limitations compared with mass spectrometry are also briefly described. It also discussed the prospects of optical isotope analysis,especially the technical difficulties that still need to be broken through. This review will provide a reference for understanding the development of optical isotope analysis.
[1] Nielsen S G, Bekaert D V, Auro M. Nature Communications, 2021, 12(1): 1817.
[2] Bai Y, Stout L, Unal-Tosun G, et al. ACS Earth and Space Chemistry, 2020, 4(12): 2327.
[3] Suryanarayana M V. Scientific Reports, 2021, 11(1): 6118.
[4] XIN Ren-xuan(辛仁轩). Plasma Atomic Emission Spectrometry(等离子体发射光谱分析). Beijing:Chemical Industry Press (北京:化学工业出版社), 2018.
[5] Zhou F Y, He D, Miao X, et al. Analytical Chemistry, 2021, 93(19): 7196.
[6] Krachler M, Wegen D H. Journal of Analytical Atomic Spectrometry, 2012, 27(2): 335.
[7] Touchet K, Chartier F, Hermann J, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2020, 168: 105868.
[8] Lu X, Zhao J, Liang X, et al. Environmental Science & Technology Letters, 2019, 6(3): 165.
[9] Zanatta M B T, Nakadi F V, Resano M, et al. Journal of Analytical Atomic Spectrometry, 2019, 34(11): 2280.
[10] Krachler M, Alvarez-Sarandes R, Rasmussen G. Analytical Chemistry, 2016, 88(17): 8862.
[11] Vigneau O, Arnal N, Felines N. Journal of Radioanalytical and Nuclear Chemistry, 2016, 307(3): 2347.
[12] Zolfonoun E, Ahmadi S J. Spectrochimica Acta Part B: Atomic Spectroscopy, 2013, 81: 64.
[13] Chan G C Y, Choi I, Mao X, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2016, 122: 31.
[14] Rinaldi C, Pozzi M, Boggio N, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2020, 167: 105841.
[15] Harilal S S, Brumfield B E, Lahaye N L, et al. Applied Physics Reviews, 2018, 5: 021301.
[16] Chan G C Y, Martin L R, Trowbridge L D, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2021, 176: 106036.
[17] Wood J C, Shattan M B. Applied Spectroscopy, 2021, 75(2): 199.
[18] Li G, Hou H, Ran P, et al. Journal of Analytical Atomic Spectrometry, 2020, 35(7): 1320.
[19] Kautz E J, Devaraj A, Senor D J, et al. Optics Express, 2021, 29(4): 4936.
[20] Krachler M, Alvarez-Sarandes R, Carbol P, et al. Microchemical Journal, 2013, 110: 425.
[21] Kautz E J, Rönnebro E C E, Devaraj A, et al. Journal of Analytical Atomic Spectrometry, 2021, 36: 1217.
[22] Russo R E, Bol′shakov A A, Mao X, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2011, 66(2): 99.
[23] Mao X, Bol’shakov A A, Perry D L, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2011, 66(8): 604.
[24] Mao X, Bol’shakov A A, Choi I, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2011, 66(11-12): 767.
[25] Dong M, Mao X, Gonzalez J J, et al. Analytical Chemistry, 2013, 85(5): 2899.
[26] Bol′Shakov A A, Mao X, Jain J, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2015, 113: 106.
[27] Hou H, Chan G C Y, Mao X, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2015, 113: 113.
[28] Hou H, Chan G C, Mao X, et al. Analytical Chemistry, 2015, 87(9): 4788.
[29] Hou H, Mao X, Zorba V, et al. Analytical Chemistry, 2017, 89(14): 7750.
[30] Sarkar A, Mao X, Russo R E. Spectrochimica Acta Part B: Atomic Spectroscopy, 2014, 92: 42.
[31] Mao X, Chan G C Y, Zorba V, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2016, 122: 75.
[32] Zhu Z H, Li J M, Hao Z Q, et al. Optics Express, 2019, 27(2): 470.
[33] Delgado T, García-Gómez L, Cabalín L M, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2021, 179: 106114.
[34] Ran P, Li G, Hou H. Spectrochimica Acta Part B: Atomic Spectroscopy, 2021, 179: 106093.
[35] Liu K, Zhou R, Zhang W, et al. Journal of Analytical Atomic Spectrometry, 2021, 36(3): 607.
[36] Choi S U, Han S C, Lee J Y, et al. Journal of Analytical Atomic Spectrometry, 2021, 36: 1287.
[37] Amiri S H, Darbani S M R, Saghafifar H. Spectrochimica Acta Part B: Atomic Spectroscopy, 2018, 150: 86.
[38] Sarkar A, Mao X, Chan G C Y, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2013, 88: 46.
[39] Choi S U, Han S C, Yun J I. Spectrochimica Acta Part B: Atomic Spectroscopy, 2019, 162: 105716.
[40] Drori R, Holmes-Cerfon M, Kahr B, et al. Proceedings of the National Academy of Sciences of the United States of America, 2017, 114(44): 11627.
[41] Noguchi N, Okuchi T. Icarus, 2020, 335: 113401.
[42] Zarei A, Klumbach S, Keppler H. ACS Earth and Space Chemistry, 2018, 2(9): 925.
[43] Hull G, Mcnaghten E D, Coffey P, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2021, 177: 106051.
[44] Xing P, Dong J, Yu P, et al. Analytica Chimica Acta, 2021, 1178: 338799.
[45] ZHAO Wen-ya, MIN Hong, LIU Shu, et al(赵文雅,闵 红,刘 曙,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(7): 1998.
[46] Winckelmann A, Nowak S, Richter S, et al. Analytical Chemistry, 2021, 93(29): 10022.
[47] Miyabe M, Oba M, Jung K, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2017, 134: 42.
[48] Kuwahara A, Aiba Y, Yamasaki S, et al. Journal of Analytical Atomic Spectrometry, 2018, 33(7): 1150.
[49] Han L, Xia H, Pang T, et al. Infrared Physics & Technology, 2018, 91: 37.
[50] Sakai S, Matsuda S, Hikida T, et al. Analytical Chemistry, 2017, 89(21): 11846.
[51] Waechter H, Mohn J, Tuzson B, et al. Optics Express, 2008, 16: 9239.
[52] Zhou S, Liu N, Zhang L, et al. Spectrochimica Acta, Part A, 2018, 205: 79.
[53] Nakadi F V, Da Veiga M a M S, Aramendía M, et al. Journal of Analytical Atomic Spectrometry, 2015, 30(7): 1531.
[54] Nakadi F V, Da Veiga M a M S, Aramendía M, et al. Journal of Analytical Atomic Spectrometry, 2016, 31(7): 1381.
[55] Abad C, Florek S, Becker-Ross H, et al. Spectrochimica Acta Part B: Atomic Spectroscopy, 2017, 136: 116.