利用光谱学分析探究高温木叶黑釉瓷的实验模拟

doi:10.3964/j.issn.1000-0593(2024)08-2381-07

摘要
参考文献
相关文章 (9)

全文: PDF (28007 KB)
输出: BibTeX | EndNote (RIS)

摘要：高温木叶黑釉瓷作为一种兼具雅致和审美特点的文化符号，因其独特的装饰效果逐渐成为中国茶道文化中备受青睐的陶瓷器具。然而，其配烧技术至今仍然神秘莫测，虽得到学者们的持续关注仍未完全披露其形成和机理。为此，采用实验模拟方法并结合光谱学分析，通过利用样品色调角h°、饱和度C^*以及反射光谱曲线和超景深显微镜观察分析釉面显微结构及其与黑釉呈色之间的关系，揭示了黑釉呈色和木叶纹清晰展现的机理，并基于传统黑釉筛选出了一组最佳的釉料配烧参数，其中Si/Al摩尔比在10.14~10.47，MgO摩尔量为0.19~0.22，CaO摩尔量为0.42~0.47，施釉厚度在0.7~0.9 mm之间可使黑釉呈现出最稳定的色泽和清晰度，并且木叶纹装饰较为理想。研究结果表明，合理的釉料配方组成及施釉厚度等对于黑釉的色调呈现和木叶纹清晰装饰具有至关重要的作用，同时，所采用的光谱学分析方法和实验模拟方法可以有效地辅助陶瓷行业中的釉料配方优选研发，有望提高制瓷工艺的精细化和智能化水平。同时，实现了对木叶黑釉显微结构与反射光谱曲线特征的解析，凸显了光谱学分析方法在陶瓷泥釉料研发方面的应用前景，有助于促进陶瓷文化的发展，为珍贵文化遗产的保护、传承和发扬提供理论支持，具有重要的实际应用价值。

关键词：木叶黑釉；光谱学分析；实验模拟；配方筛选；反射光谱曲线

Abstract：Leaf pattern decoration on black glaze porcelain in High temperature,a cultural symbol combining elegance and aesthetic features, has gradually become a favored ceramic utensil in Chinese tea ceremony culture because of its unique decorative effect. However, its blending technology is still mysterious, and its formation and mechanism have not been fully disclosed under the continuous attention of scholars. Therefore, the mechanism of black glaze color and leaf pattern was revealed by using an experimental simulation method combined with spectroscopic analysis technology, and the relationship between glaze micro-structure and black glaze color was observed and analyzed by using sample hue angle h°, saturation C^*, reflection spectrum curve and ultra-depth of field microscope. Based on traditional black glaze, a group of optimum glaze firing parameters was screened out, in which the Si/Al molar ratio was 10.14~10.47, MgO molar amount was 0.19~0.22, CaO molar amount was 0.42~0.47, and glaze thickness was 0.7~0.9 mm, which made black glaze show the most stable color and clarity, and leaf pattern decoration was ideal. The results show that the reasonable composition of glaze and glaze thickness is very important for the color presentation of black glaze and the clear decoration of the leaf pattern. At the same time, the spectroscopic analysis method and experimental simulation method adopted in this paper can effectively assist the research and development of glaze formula optimization in the ceramic industry, which is expected to improve the refinement and intelligence level of the porcelain-making process. At the same time, it realizes the analysis of microstructure and reflection spectrum curve characteristics of leaf pattern decoration on black glaze porcelain, highlights the application prospect of spectroscopic analysis method in the research and development of ceramic clay glaze, promotes the development of ceramic culture, and provides theoretical support for the protection, inheritance, and development of precious cultural heritage. It has important practical application value.

Key words：Leaf pattern decoration on black glaze porcelain; Spectroscopic analysis; Experimental simulation; Formula screening; Reflection spectral curve

收稿日期: 2023-05-08 修订日期: 2023-11-03

中图分类号:

TQ174.67

基金资助: 江西省高校人文社会科学重点基地项目(JD20081)，江西陶瓷文物遗存保护暨御窑研究协同创新中心项目(JXYY2105)，江西省研究生创新专项资金项目(YC2023-B243)，国家社科基金冷门绝学研究专项项目(22VJXG025)资助

作者简介: 熊露，1986年生，景德镇陶瓷大学古陶瓷研究中心副教授 e-mail: x_lu1986@sina.com

引用本文:

熊露，袁寅洁，李丹，杨轩，季然，李其江，吴军明. 利用光谱学分析探究高温木叶黑釉瓷的实验模拟[J]. 光谱学与光谱分析, 2024, 44(08): 2381-2387.
XIONG Lu, YUAN Yin-jie, LI Dan, YANG Xuan, JI Ran, LI Qi-jiang, WU Jun-ming. Experimental Simulation of Leaf Pattern Decoration on Black Glaze Porcelain at High Temperature Based on Spectroscopic Analysis. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(08): 2381-2387.

链接本文:

https://www.gpxygpfx.com/CN/10.3964/j.issn.1000-0593(2024)08-2381-07 或 https://www.gpxygpfx.com/CN/Y2024/V44/I08/2381

[1] The Chinese Ceramic Society(中国硅酸盐学会). History of Chinese ceramics(中国陶瓷史). Beijing: Cultural Relics Press(北京: 文物出版社), 1982.
[2] JIANG Peng-fei, LI Qi-jiang, WU Jun-ming, et al(江鹏飞, 李其江, 吴军明, 等). Journal of Ceramics(陶瓷学报), 2012，33(3): 347.
[3] OUYANG Shi-bin, LI Yan-fei, OUYANG Zhi-chuan(欧阳世彬, 李燕飞, 欧阳之川). Journal of Ceramics(陶瓷学报), 1996，7(4): 27.
[4] WU Yue(伍跃). Guide to the Identification of Ancient Porcelain (1st ed)[古瓷鉴定指南（初编）]. Beijing: Beijing Yanshan Press(北京: 北京燕山出版社), 1991.
[5] ZHANG Fu-kang(张福康). Journal of Ceramics(陶瓷学报)，1986，7(1): 109.
[6] ZHU Gui-hong, ZHOU Jian-er, CAO Chun-e, et al(祝桂洪，周健儿，曹春娥，等). Fundamentals of Ceramic Glaze Preparation(陶瓷釉配制基础). Beijing：China Light Industry Press(北京: 中国轻工业出版社), 1989.
[7] YU Jia-dong，LIU Yang(余家栋, 刘杨). Jizhou Kiln/Series of Ancient Famous Kiln in China(吉州窑/中国古代名窑系列丛书). Nanchang: Jiangxi Fine Arts Publishing House(南昌: 江西美术出版社)，2016. 5.
[8] ZHAO Ting, CHI Hai-tao, LIU Yi-ren, et al(赵婷, 池海涛, 刘奕忍, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(3): 750.
[9] WU Ya-qing(吴雅清). Physical Testing and Chemical Analysis(Part B: Chemical Analysis)[理化检验(化学分册)]，2021, 57(2): 132.
[10] AO Jing-qiu, XU Zhuo-long(敖镜秋, 许作龙). China Ceramics(中国陶瓷)，1987，(2): 38.
[11] AO Jing-qiu(敖镜秋). China Ceramics(中国陶瓷)，1987，(2): 45.
[12] SHI Qiu-tong, ZHANG Wen-jiang, WU Sheng-le, et al(史秋童, 张文江, 吴声乐，等). Journal of National Museum of China(中国国家博物馆馆刊), 2023，(6): 99.
[13] SHI Xiao-tao, ZHANG Ting, LU Zi-han, et al(石小涛, 章婷, 鲁子涵，等). Journal of Ceramics(陶瓷学报), 2021, 42(6): 948.
[14] YU Jun-ling, BAO Zhen-hong, MIAO Li-feng, et al(余君玲, 包镇红, 苗立锋，等). Journal of Ceramics(陶瓷学报), 2023, 44(4): 679.
[15] CHEN Xian-qiu, HUANG Rui-fu, CHEN Shi-ping(陈显求, 黄瑞福, 陈士萍). Industrial Technology and Vocational Education(河北陶瓷), 1985，(4): 2.