1. College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108,China
2. Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University),Fuzhou 350108, China
Abstract:A new type of hyperbranched polyamide grafted chitosan (CS-PAMAM) adsorbent was synthesized using glutaraldehyde (GLA) as the crosslinker. The adsorbent wascharacterized with Field Emission Scanning Electron Microscope and Fourier Transform Infrared. Combined with flame atomic absorption spectroscopy (FAAS) and UV-Vis spectrophotometry, the adsorption of Malachite green (MG), Sunset yellow (SY) and Cu(Ⅱ) by adsorbent were investigated. Experimental conditions affecting the adsorption percentage were discussed and the experimental operation parameters were optimized (pH value were 7.0,2.0 and 6.0, respectively; adsorption time were 60,60 and 30 min, respectively). Under the optimal condition, the maximum adsorption capacity of MG, SY and Cu(Ⅱ) on CS-PAMAM was found to be 515.30, 201.79 and 80.00 mg·g-1, respectively. The advantages are obvious. The adsorption process for MG, SY and Cu(Ⅱ) obeyed Langmuir isother mequation.
凌云霞飞,高 超,范经爽,吕海霞,于 岩. 超支化聚酰胺接枝壳聚糖的制备及其对重金属和染料吸附的光谱分析[J]. 光谱学与光谱分析, 2018, 38(11): 3583-3587.
LINGYUN Xia-fei, GAO Chao, FAN Jing-shuang, Lü Hai-xia, YU Yan. Synthesis of Hyperbranched Polyamidoamine (PAMAM) Grafted Chitosan and Its Adsorption for Heavy Metal and Dyes Studied with Spectroscopy. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3583-3587.
[1] Lei C, Zhu X, Zhu B, et al. Journal of Hazardous Materials, 2017, 321: 801.
[2] SHEN Wang-qing, WANG Miao, YANG Ting(沈王庆, 王 淼, 杨 婷). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2016, 36(3): 788.
[3] Sun X, Li Q, Yang L, et al. Particuology, 2016, 26: 79.
[4] PENG Zhong-liang, YI Dan-qing, KE Yu-cai, et al(彭中樑, 易丹青, 柯毓才, 等). Acta Polymerica Sinica(高分子学报), 2014,(7): 976.
[5] Fujiki J, Yogo K. Energy & Fuels, 2014, 28(10): 6467.
[6] Dai B, Cao M, Fang G, et al. Journal of Hazardous Materials, 2012, 219: 103.
[7] Zhang J, Liu M, Liu Z, et al. Journal of Sol-Gel Science and Technology, 2017, 82(2): 424.
[8] Jiang X, Wang S, Ge L, et al. RSC Advances, 2017, 7(62): 38965.
[9] Zhang F, Wei Z, Zhang W, et al. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2017, 182: 116.
[10] Xie X, Xiong H, Zhang Y, et al. Journal of Environmental Chemical Engineering, 2017, 5(3): 2800.
[11] Wang C, Ge H, Zhao Y, et al. Journal of Magnetism and Magnetic Materials, 2017, 423: 421.
[12] Zhou Q, Liao B, Lin L, et al. Science of The Total Environment, 2018, 615: 115.
[13] Ghaedi M, Mosallanejad N. Journal of Industrial and Engineering Chemistry, 2014, 20(3): 1085.
[14] Roosta M, Ghaedi M, Sahraei R, et al. Materials Science and Engineering: C, 2015, 52: 82.
[15] Maghsoudi M, Ghaedi M, Zinali A, et al. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, 134: 1.