Rapid FTIR-ATR Method for the Quantification of Bitumen Property
TANG Jie-qiong1, MA Qing-feng2, SHI Jing-tao2, YUAN Hong-fu1*, SONG Chun-feng1, XIE Jin-chun1, LI Xiao-yu1
1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China 2. PetroChina Fuel Oil Company Limited Research Institute, Qingdao 266500, China
Abstract:The quality of bitumen directly affects road performance and road life. Traditional analytical methods for wax content, softening point and penetration of bitumen are tedious and time-consuming. A new fast method, with which the three properties can be determined at same time, is proposed in this paper. The spectra of 220 bitumen were collected and their wax content, softening point and penetration data were determined according to the standard JTJ052—2000. The quantitative calibration models for wax content, softening point and penetration were established using partial least squares (PLS), with SECV 0.13, 0.88, 3.18 and SEP 0.14, 1.06, 3.90, less than the reproducibility error stipulated in the standard method. Three samples were in random selected to test the repeatability, the results met the precision requirement of the standard method. With its advantages of better repeatability, fast, easy operation, the new method can be used as an alternative for the determination of wax content, softening point and penetration of bitumen.
Key words:Attenuated total reflection infrared spectroscopy;Bitumen;PLS
唐洁琼1,马庆丰2,时敬涛2,袁洪福1*,宋春风1,谢锦春1,李效玉1 . 衰减全反射红外光谱法快速检测沥青性质的研究 [J]. 光谱学与光谱分析, 2016, 36(03): 672-675.
TANG Jie-qiong1, MA Qing-feng2, SHI Jing-tao2, YUAN Hong-fu1*, SONG Chun-feng1, XIE Jin-chun1, LI Xiao-yu1 . Rapid FTIR-ATR Method for the Quantification of Bitumen Property . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 672-675.
[1] JTG F40—2004. Technical Specification for Construction of Highway Asphalt Pavements(公路沥青路面施工技术规范), 2004. [2] JTJ 052—2000. Standard Test Methods of Bitumen and Bituminous Mixtures for Highway Engineering(公路工程沥青及沥青混合料试验规程), 2000. [3] CHU Xiao-li(褚小立). Molecular Spectroscopy Analytical Technology Combined with Chemometrics and Its Applications(化学计量学方法与分子光谱分析技术). Beijing: Chemical Industry Press(北京: 化学工业出版社),2011. 160. [4] Aske N, Kallevik H, Sjblom J. Energy & Fuels, 2001, 15(5): 1304. [5] Yuan Hongfu, Chu Xiaoli, Li Haoran, et al. Fuel, 2006, 85(12-13): 1720.