Abstract:Based on oil samples and rock samples in several petroliferous basins,this paper studied that secondary alterations influence on fluorescence color and spectral parameters of crude oil and oil inclusions by using microscopic fluorescent spectral and geochemical parameters. The results demonstrated that secondary alterations influence on spectral parameters by changing the ratio of saturated hydrocarbon and aromatic hydrocarbon(saturation/aromatics). Biodegradation and water washing lead to redshift of fluorescence parameters while evaporative fractionation and oil cracking lead to blueshift. Beside, mixed oil lead to redshiftand blueshift. The secondary alterations and main period of accumulation in research area were recognized by frequency histogram of crude oil and oil inclusion. The relationship between QF-535 and the parameters measuring the secondary alterations could the extent of secondary alterations from which crude oil suffered. In the microscopic fluorescence test, oil inclusions suffered from stretch or leakage, thermal cracking and photooxidation should be rejected.
[1] Burruss R C. Hydrocarbon Fluid Inclusions in Studies of Sedimentary Diagenesis. In: Applications to Petrology, Short Course in Fluid Inclusions. Hollister L S, Crawford M L.(Eds.), Mineral. Assoc.Canada Short Course Handbook, 1981, 6: 138. [2] Gelfand J C, Lang W H J. The Log Analyst, 1985, 26:13. [3] Bodnar R J. Mineralogical Magazine,1990, 54(375): 295. [4] Stasiuk L D, Snowdon L R. Appl. Geochem., 1997. 12:229. [5] George S C, Ruble T E, Dutkiewicz A. Applied Geochemistry, 2001, 16(4): 451. [6] PING Hong-wei, CHEN Hong-han, SONG Guo-qi, et al(平宏伟, 陈红汉, 宋国奇, 等). Journal of Earth Science(地球科学), 2012, 37(1): 163. [7] Hunt J M. Petroleum Geochemistry and Geology. San Franciso: Freeman, 19791. 617. [8] Chaineau C, Morel J, Oudot J. Environ. Sci. Technol., 1995, 29: 1615. [9] Thompson K F M. Geochimica et Cosmochimica Acta, 1979, 43(5): 657. [10] SU Ao, CHEN Hong-han, WANG Cun-wu, et al(苏 奥, 陈红汉, 王存武, 等). Petroleum Exploration and Development(石油勘探与开发), 2013, 40(5): 521. [11] Dahl J E, Moldowan J M, Peters K E. et al. Nature, 1999, 399(6731): 54. [12] Eadington P J, Lisk M, Krieger F W. United States Patent Application, 1996, 5: 543. [13] Lung Chuan Kuo. Organic Geochemistry, 1994, 21(5): 465.