Application of Fiducial Wavelength Method in Processing Spectra of Turbid Media
LUO Yun-han, GU Xiao-yu, XU Ke-xin*
State Key Laboratory of Precision Measuring Technology and Instruments, College of Precision Instrument and Opto-Electronics Engineering, Tianjin University, Tianjin 300072, China
Abstract:In the present paper, the authors analyzed the absorption and scattering effects of changing the solution concentration on the spectra, and dealed with the wavelength, where the absorption and scattering effects counteract completely, the fiducial wavelength method can eliminate the perturbation from shift of instrument and temperature, and also can improve predicting ability of the model. The result of utilizing this method to process the spectral data of two sample sets, i.e. intralipid solution and plasma solution with different level glucose, has verified that fiducial wavelength method can improve correlation coefficient and decrease RMSEP of predicting model.
[1] Bittner A, Marbach R, Heise H M. Journal of Molecular Structure, 1995, 349: 341. [2] Robinson Mark R. Clinical Chemistry, 1992, 38(9): 1618. [3] Pan Shengtian, Chung Hoeil, Arnold Mark A. Anal. Chem., 1996, 68(7): 1124. [4] Malin Stephen F. Non-Invasive Measurement of Glucose by Near-Infrared Diffuse Reflectance Spectroscopy, 31st Annual Oak Ridge Conference, San Jose, California, April, 1999. 23. [5] Laporte Marie-France, Paquin Paul. Journal of Agricultural Food Chem., 1999, 47: 2600. [6] Albanell Elena, Caceres Paloma, Caja Gerardo, et al. Journal of Association of Official Analytical Chemists International, 1999, 82(3): 753. [7] Minjin Kim, Young-Hak Lee, Chonghun Han. Computers and Chemical Engineering, 2000, 24(2): 513. [8] Maleki M, Petersen J C. Applied Optics, 1997, 36(19): 4451. [9] DeBraekeleer K, Sa'nchez Cuesta F, Hailey P A, et al. Journal of Pharmaceutical and Biomedical Analysis, 1998, 17(1): 141. [10] Luo Yunhan, Liu Rong, Chen Wenliang, et al. Proceeding of SPIE, Photonics West, 2005 (in press). [11] Kohl Matthias, Cope Mark. Opt. Lett., 1994,19(24): 2170.