Abstract:Nickel tetrasulfo-phthalocyanine(NiTSPc) was successfully doped into vinyltriethoxysilane(VTES)modified silicate gel glass by sol-gel technique, IR and UV-Vis spectral examination was carried out. The results show that vinyl has been introduced into SiO2 network, and the structure of gel glass is therefore changed. The encapsulation of NiTSPc does not make any noteworthy changes in the composition and structure of gel glass matrix. NiTSPc molecules are well dispersed in the organic modified matrix, and the phenomenon of aggregation is greatly suppressed.
Key words:Nickel tetrasulfo-phthalocyanine (NiTSPc);Vinyl modified SiO2;Composite gel glass;Spectral properties
[1] ZUO Xia, WEI Yong-de, WU Yi-qun(左 霞,韦永德,吴谊群). Progress in Chemistry(化学进展), 2004, 16(1): 68. [2] Leznoff C C, Lever A B P. Phthalocyanine Properties and Applications. New York: VCH Publishers, Inc. 1989. [3] XU Ming-sheng, JI Zhen-guo, QUE Duan-lin, et al(徐明生,季振国,阙端麟, 等). Materials Science and Engineering(材料科学与工程),1999, 17(2): 1. [4] Zhan H B, Chen W Z, Wang M Q, et al. Chemical Physics Letters, 2004, 389: 119. [5] XIA Hai-ping, ZHANG Jian-li, ZHANG Yue-pin, et al(夏海平,章践立,张约品,等). Journal of the Chinese Ceramic Society(硅酸盐学报),2001, 29(2): 114. [6] Zhan H B, Chen W Z, Li G H, et al. Materials Science and Engineering B, 2003, 100(2): 113. [7] YE Hui, JIANG Zhong-hong(叶 辉,姜中宏). Chinese Journal of Materials Research(材料研究学报), 1999, 13(1): 68. [8] WANG Zhi-yu, et al(王智宇,等). Chinese Journal of Materials Research(材料研究学报), 2000, 14(1): 66. [9] GU Yu-zong, LIANG Zhi-jian, GAN Fu-xi(顾玉宗,梁志坚,干福熹). Acta Optica Sinica(光学学报), 2001, 21(9): 1052. [10] LI Run-qing, FAN Guo-liang, Qü Rong-ling(李润卿,范国梁,渠荣遴). Spectral Analysis of Organic Structures(有机结构波谱分析). Tianjin: Tianjin University Press(天津: 天津大学出版社),2002. [11] HUANG Jin-ling, PENG Yi-ru, CHEN Nai-sheng(黄金陵,彭亦如,陈耐生). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(1): 1. [12] Wu Z J, Ahn Ik-Sung, Lee Chang-Ha, et al. Colloids and Surfaces A, 2004, 240: 157.