Abstract:Application and advanced achievement of surface-enhanced Raman spectroscopy (SERS) in corrosion and inhibition on an iron surface have been reviewed. As a technology providing the molecular information of material structure, SERS is widely applied to the studies of metal corrosion and inhibition, especially for iron. Applications of this spectroscopy technology are showed in three aspects: the SERS enhancement theory of Fe surface, the adsorbent mode of inhibitions on Fe surface, and the structure of oxidation or passivation film on a Fe electrode. Furthermore, the tendency of farther study is prospected.
Key words:Surface enhanced Raman spectroscopy (SERS);Iron;Corrosion;Inhibition;Passivation film
顾 伟,曹佩根,顾仁敖*. 表面增强拉曼光谱在铁腐蚀与防护研究中的应用 [J]. 光谱学与光谱分析, 2005, 25(09): 1412-1417.
GU Wei, CAO Pei-gen, GU Ren-ao*. Surface-Enhanced Raman Spectroscopy in Studies of Corrosion and Inhibition on an Iron Surface. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(09): 1412-1417.
[1] Gutiérrez C, Melendres C. Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry. Kluwer Academic Publishers, 1990. [2] Fleischmann M, Hendra J P, McQuillian A J. Chem. Phys. Lett., 1974, 26: 163. [3] YAN Chuan-wei, YU Jia-kang, LIN Hai-chao, et al(严川伟,余家康,林海潮,等). Corrosion Science and Protection Technology(腐蚀科学与防护技术),1998,10: 163. [4] Mengoli G, Musiani M M, Fleischmann M,et al. Electrochim. Acta, 1987, 32: 1239. [5] Aramaki K, Uehara J. J. Electrochem. Soc., 1991, 138: 3245. [6] Cao P G, Yao J L, Ren B, et al. Chem. Phys. Lett., 2000, 316: 1. [7] GU Ren-ao(顾仁敖). Chinese Chemistry Bulletin(化学通报),1986, (5): 20. [8] Gui J, Devine T M. J. Electrochem. Soc., 1991, 138: 1376. [9] ZHU Zi-ying, GU Ren-ao, LU Tian-hong(朱自莹,顾仁敖,陆天虹). Application of Raman Spectroscopy in Chemistry(拉曼光谱在化学中的应用). Shenyang: Press of Northeast University(沈阳:东北大学出版社),1998,. [10] CAO Pei-gen, YAO Jian-lin, XU Hao-yuan, et al(曹佩根,姚建林,徐浩元,等). Chinese Journal of Light Scattering(光散射学报),2000, 12: 87. [11] Aramaki K. Zairyo to Kankyo(Japanese), 2001, 50: 264. [12] Aramaki K, Ohi M, UeharaJ. J. Electrochem. Soc., 1992, 139: 1525. [13] Aramaki K, Uehara J. J. Electrochem. Soc., 1989, 136: 1299. [14] Aramaki K, Uehara J. J. Electrochem. Soc., 1990, 137: 185. [15] Aramaki K, Fujioka E. Corrosion, 1997, 53: 319. [16] Ohno N, Uehara J, Aramaki K. J. Electrochem. Soc., 1993, 140: 2512. [17] GU Ren-ao, DING Bang-dong(顾仁敖,丁邦东). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1995, 15(1): 39. [18] GU Ren-ao, DENG Zheng-fa, QIAO Zhuan-hong, et al(顾仁敖,邓正发,乔专虹,等). Journal of Suzhou University(苏州大学学报),1995,11: 82. [19] GU Ren-ao, DENG Zheng-fa, SUN Ru(顾仁敖,邓正发,孙 如). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1997, 17(1): 15. [20] GU Ren-ao, DENG Zheng-fa, YAO Jian-lin, et al(顾仁敖,邓正发,姚建林,等). Chinese Journal of Light Scattering(光散射学报),1997, 9: 300. [21] LU Xue-fei, LI Feng-ting(陆雪非,李风亭). Corrosion and Protection(腐蚀与防护),2001, 22: 144. [22] Li F T, Lu Y, Xue G. Appl. Spectrosc., 1997, 51: 804. [23] Cao G, Li F T, Lu Y, et al. Spectrosc. Lett., 1998, 31: 167. [24] ZHA Ying-hua, WEI Bao-ming, TIAN Zhong-qun, et al(查英华,魏宝明,田中群,等). Electrochemistry(电化学),1995, 1: 152. [25] Gu R A, Cao P G, Yao J L, et al. J. Electroanal. Chem., 2001, 505: 95. [26] CAO Pei-gen, YAO Jian-lin, GU Ren-ao, et al(曹佩根,姚建林,顾仁敖,等). Chinese Journal of Light Scattering(光散射学报),1999, 11: 1. [27] Yao J L, Liu H C, Cao P G, et al. Eur. Fed. Corros. Publ., 2000, 28: 37. [28] Cao P G, Yao J L, Zheng J W. Langmuir, 2002, 18: 100. [29] Cao P G, Gu R A, Tian Z Q. Langmuir, 2002, 18: 7609. [30] Cao P G, Yao J L, Ren B. J. Phys. Chem. B, 2002, 106: 10150. [31] Wang G, Shi J, Yang H. J. Raman Spectrosc., 2002, 33: 125. [32] Cao P G, Yao J L, Ren B. J. Phys. Chem. B, 2002, 106: 7283. [33] CAO Pei-gen, BAI Zhi-ming, QIU Li-qun, et al(曹佩根,柏志明,仇立群,等). Chinese Journal of Light Scattering(光散射学报),2003, 15: 68. [34] CAO Pei-gen, XU Hao-yuan, CAO Wen-dong, ZHENG Jun-wei, GU Ren-ao, YAO Jian-lin, XIE Yong, TIAN Zhong-qun(曹佩根,徐浩元,曹文东,郑军伟,顾仁敖,姚建林,谢 泳,田中群). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2000, 20(6): 800. [35] CAO Pei-gen, YAO Jian-lin, ZHENG Jun-wei(曹佩根,姚建林,郑军伟). Electrochemistry(电化学), 2001, 7: 63. [36] Simpson L J, Melendres C A. J. Electrochem. Soc., 1996, 143: 2146. [37] Rubim Joel C, Dünnwald J. J. Electroanal. Chem., 1989, 258: 327. [38] Oblonsky L J, Virtanen S, Schroeder V, et al. J. Electrochem. Soc., 1997, 144: 1604. [39] Shimizu T, Oblonsky L J, Devine T M. Proc. Electrochem. Soc., 1995, 94-26: 114. [40] Schroeder V, Devine T M. J. Electrochem. Soc., 1999, 146: 4061. [41] Kumai C S, Devine T M. Proc. Electrochem. Soc., 1999, 99-27: 35. [42] Odziemkowski M S, Schuhmacher T T, Gillham R W, et al. Corros. Sci., 1998, 40: 371. [43] Iordanes,Thanos C G. Electrochilmica Acta, 1986, 31: 811.