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FTIR Spectra and LA-ICP-MS Research of Growth Zones in Sapphire Bands from Changle, Shandong Province |
LI Xiao-xiao1, YANG Zhi-jun1, 2*, HUANG Shan-shan1, CHEN Yao-ming1, ZENG Xuan1, ZHOU Wen-xiu1 |
1. School of Earth Science and Engineering, Sun Yat-sen University, Guangzhou 510275, China
2. Guangdong Provincial Key Laboratory of Mineral Resource Exploration & Geological Processes, Guangzhou 510275, China |
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Abstract The results of micro-infrared spectra and LA-ICP-MS research of growthzones in sapphire showed that there was an internal relationship between the formationof color of growth zone and —OH content in sapphire. In the sapphire which contained hexagonal growth zones, the content of —OH was similar in the same zone and varied from zone to zone. The content of —OH decreased gradually from dark growth zone to light growth zone. The content of —OH depended on the content of trace element Ti in the zones, which suggested that the content of —OH in the growth zones could be used to reflect the change rules of the formation process of sapphire. In the higher hydrogen condition, more Ti4+/Fe2+ substituted Al3+ into the sapphire crystal lattice. Otherwise, less or no Ti4+/Fe2+ substituted Al3+ into the sapphire crystal lattice. Therefore, systematic research of the distribution characteristic of —OH in the sapphire will be conducive to the formation mechanism of color of sapphire and provide new scientific ideas for high quality sapphire synthesis and optimization.
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Received: 2017-03-03
Accepted: 2017-06-12
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Corresponding Authors:
YANG Zhi-jun
E-mail: yangzhj@mail.sysu.edu.cn
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[1] ZHANG Bei-li(张蓓莉). Systematic Gemology(系统宝石学). Beijing: Geology Press(北京: 地质出版社), 2006. 279.
[2] HU Ke-yan, XU Jun, TANG Hui-li, et al(胡克艳, 徐 军, 唐慧丽, 等). Acta Physica Sinica(物理学报), 2013, 6(6): 363.
[3] ZOU Jin-fu(邹进福). Journal of Guilin Institute of Technology(桂林工学院学报), 1995, 15(3): 252.
[4] CAO Rong-long, CAO Shu(曹荣龙, 曹 姝). Jewellery Science and Technology(珠宝科技), 1997,(1): 42.
[5] CAO Rong-long, CAO Shu(曹荣龙, 曹 姝). Mineral Resource and Geology(矿产与地质), 1997, 6(11): 413.
[6] SUN Hong-juan, MO Xuan-xue, LIN Pei-ying(孙宏娟, 莫宣学, 林培英). Acta Petrologica Sinica(岩石学报), 1998,(3): 381.
[7] ZHANG Pei-qiang(张培强). Shandong Geology(山东地质), 2000, 16(2): 36.
[8] HAN Li, HE Wen, LI Guang-hui(韩 丽, 何 文, 李广慧). Jewellery Science and Technology(珠宝科技), 2001, 41(2): 48.
[9] LI Guang-hui, HAN Li, HE Wen(李广慧, 韩 丽, 何 文). Acta Petrologica et Mineralogica(岩石矿物学杂志), 2002, 21(1): 89.
[10] ZHANG Pei-qiang, MA Yu(张培强, 马 宇). Contributions to Geology and Mineral Resources Research(地质找矿论丛), 2006, 21(2): 115.
[11] LI Jian-jun(李建军). Journal of Gems and Gemmology(宝石和宝石学杂志), 2004, 6(3): 15.
[12] SONG Yu-cai, HU Wen-xuan, JIN Zhi-yun, et al(宋玉财, 胡文瑄, 金之均,等). Geochimica(地球化学), 2006, 35(4): 377.
[13] CHEN Ying, LIAO Zong, XUE Qin-fang(陈 盈, 廖 宗, 薛秦芳). Shanghai Geology(上海地质), 2007, 28(3): 63.
[14] Moon A R, Phillips M R. Journal of the American Ceramic Society. 1994, 77(2): 356.
[15] Beran A. European journal of Mineralogy, 1991, 3: 971.
[16] WENG Shi-fu(翁诗甫). Fourier Transform Infrared Spectrometry Analyses(傅里叶变换红外光谱分析). Beijing: Chemical Industry Press(北京:化学工业出版社), 2010. 325.
[17] PENG Wen-shi, LIU Gao-kui(彭文世, 刘高魁). The Infrared Spectra of Minerals(矿物红外光谱图集). Beijing: Science Press(北京:科学出版社), 1982. 385.
[18] LIANG Wan-xue, ZHANG Zheng-gang, WEN Lu, et al(梁婉学, 章正刚, 闻 辂, 等). The Infrared Spectra of Minerals(矿物红外光谱学). Chongqing: Chongqing University Press(重庆:重庆大学出版社), 1988. 157.
[19] DONG Qing-nian(董庆年). Infrared Spectrometry(红外光谱法). Beijing: Chemical Industry Press(北京:化学工业出版社), 1979. 230.
[20] DING Jing, LI Zi-ming, LI Shui-ping(丁 竞, 李子明, 李水平). Metrology & Measurement Technique(计量与测试技术), 2011, 38(7): 54.
[21] TANG De-ping(汤德平). Bulletin of Mineralogy, Petrology and Geochemistry(矿物岩石地球化学通报), 1999, 18(4): 386.
[22] Peucat J J, Ruffault P, Fritsch E, et al. Lithos, 2007, 98: 261.
[23] Liu Y S, Gao S, Hu Z C, et al. Chemical Geology, 2008, 257: 34. |
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