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Reduction of CO2 Effect on Unburned Carbon Measurement in Fly Ash Using LIBS |
NAN Wei-gang1, 2, 3, Yoshihiro Deguchi2*, WANG Huan-ran1, LIU Ren-wei1, 2, Akihiro Ikutomo2, WANG Zhen-zhen1, 2 |
1. School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China
2. Graduate School of Advanced Technology and Science, Tokushima University, Tokushima 770-8501, Japan
3. Hualu Engineering Technology Co. Ltd., Xi’an 710065,China |
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Abstract In thermal power plant, the measurement of unburned carbon in fly ash becomes increasingly important because unburned carbon contents are usually important factors for the operation of power plants and it can be an indicator of the combustion conditions Thus, the goal of combustion optimization and efficiency improvement can be achieved. More specifically, the unburned carbon concentration in fly ash reflects the combustion efficiency of the power generator set. The combustion efficiency decreases with increasing of unburned carbon level in fly ash, which means a loss of fuel energy. Owing to the non-contact, fast response, high sensitivity and online measurement features, LIBS was used to measure the quantitative contents in fly ash in this research. But the carbon emission intensity changed with the fluctuant amount of CO2 in flue gas. In this study, dual-channel spectrometer was utilized to analyze the elemental spectra of C,Si,Mg,Fe,Ca,Al and so on, and the neighboring elemental spectra, such as C and Fe, can be recognized in the high resolution channel, which means sufficient fly ash spectrum information can be gained with enough measurement accuracy at the same time. Cyclone was designed and two-stage cyclone system was proposed into the system of LIBS measurement for unburned carbon contents in fly ash. Fly ash particles from the feeder flow through the two-stage cyclone and went into the chamber. The laser shot on the fly ash through the lens. Plasma was acquired and then recorded and analyzed by spectrometer and ICCD camera. The two-stage cyclone system was proven to be detectable for the unburned carbon in fly ash. In addition, two-stage cyclone system can be able to separate and collect fly ash particles from flow gas to reduce the influence of CO2 in fly ash particle flow, thus, exact data can be got to guide the operation of the thermal power plant, which provide more benefits to the engineering applications of LIBS.
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Received: 2016-08-29
Accepted: 2017-01-30
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Corresponding Authors:
Yoshihiro Deguchi
E-mail: ydeguchi@tokushima-u.ac.jp
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[1] CHENG Qi-ming, HU Xiao-qing, WANG Ying-fei, et al(程启明,胡晓青,王映斐,等). Journal of Shanghai University of Electric Power(上海电力学院学报),2011, 27(5): 519.
[2] Wang Z Z, Deguchi Y, Watanabe Y, et al. Journal of Flow Control, Measurement & Visualization, 2015, 3: 10.
[3] Wang Zhe, Yuan Tingbi, Hou Zongyu, et al. Front. Phys., 2014,9: 419.
[4] Guo L B, Hao Z Q, Shen M, et al. Opt. Express, 2013, 21(15): 18188.
[5] Cremers D A, Radziemski L J. Handbook of Laser-Induced Breakdown Spectroscopy. John Wiley & Sons, New York, NY, USA, 2006.
[6] Miziolek A W, Palleschi V, Schechter I. Laser-Induced Breakdown Spectroscopy (LIBS) Fundamentals and Applications. Cambridge University Press, 2006.
[7] Nicoal G, Matea M P, Yanez A. Appllied Surface Science, 2007, 254(4): 873.
[8] Ferioli Francesco, Buckley Steven G. Combustion and Flame, 2006, 144(3):435.
[9] Deguchi Y. Industrial Applications of Laser Diagnostics. New York:CRC Press, 2011.
[10] BIAN Jin-tian, YIN Ke-jing, YAO Shun-chun, et al(卞进田,殷可经,姚顺春,等). Laser & Optoelectronics Progress(激光与光电子学进展), 2016, 53, 043002.
[11] BAI Kai-jie, TIAN Hao-chen, YAO Shun-chun, et al(白凯杰,田浩臣,姚顺春,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2014, 34(5); 1407.
[12] Noda M, Deguchi Y, Iwasaki S, et al. Spectrochim. Acta Part B, 2002, 57(4): 701.
[13] Wang Z Z, Deguchi Y, Kuwahara M, et al. Spectrochim. Acta Part B, 2013, 87: 130.
[14] Zhang Lei, Hu Zhiyu, Yin Wangbao, et al. Frontiers Physics, 2012, 7(6): 690. |
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