| 光谱学与光谱分析 |
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| Preparation of Rubber Accelerator Tetrabenzylthiuramdisulfide and Its Spectral Analysis |
| JIA Tai-xuan1, ZHANG Nan1*, GUO Yao1, LU You-chang1, TIAN Da-yong1, LI Hong-liang2 |
1. College of Chemistry & Environmental Engineering, Anyang Institute of Technology, Anyang 455000, China
2. Hebi Uhoo Chemical Co., Ltd., Hebi 458000, China |
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Abstract In the study, rubber accelerator tetrabenzylthiuramdisulfide (TBzDT) was synthesized with two-step method with hydrogen peroxide as oxidant firstly. TBzDT was detected and characterized with XRD, FT-IR, TG-DTA. Its micro-structure was revealed. Chemical bond types into TBzDT molecule were revealed with FT-IR. TBzDT phase composition and structure were given by crystallographic data from XRD detecting such as cell parameters, crystal face index. The phase composition and qualitative identification of TBzDT structure were completed. Two kinds of information were detected with TG-DTA as to quality change and thermal effect. TBzDT phase transition and decomposition temperature were 142.5, 200.9 ℃ respectively. The decomposition temperature of TBzDT was relevtively high. It could provided reference with research on rubber vulcanizing properties by TBzDT on rubber vulcanizing machine. A little SC2 contained into TBzDT was revealed by FTIR, TG-DTA from different sides.
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Received: 2015-06-29
Accepted: 2016-01-15
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Corresponding Authors:
ZHANG Nan
E-mail: 18738207825@163.com
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