光谱学与光谱分析 |
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Study of the Characterization of β-Cyclodextrin-Acetylferrocene- Thiosemicarbazone Inclusion Complex and Micro-Environmental Effects |
ZHANG Jing, LIU Wan-yi*, ZHANG Xia |
Key Laboratory of Energy Sources and Engineering, Ningxia University, Yinchuan 750021, China |
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Abstract Inclusion complex of acetylferrocene-thiosemicarbazone(TAF) with β-cyclodextrin(β-CD) has been prepared by using kneading method. Elemental analysis and the solubility determination proved that 1∶1 inclusion complex has been formed. Characterization of the inclusion complex was studied by UV, FTIR, and X-ray diffractometry. The association constant was calculated to be 227 L·mol-1 from the straight portion of the phase-solubility diagram. Furthermore, the influence of different solvents and pH on UV spectrum of acetylferrocene-thiosemicarbazone and β-CD -TAF was discussed respectively. The results show that different micro-environment has apparently different effects on electric spectra of guest and inclusion complexes.
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Received: 2004-05-16
Accepted: 2004-10-06
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Corresponding Authors:
LIU Wan-yi
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Cite this article: |
ZHANG Jing,LIU Wan-yi,ZHANG Xia. Study of the Characterization of β-Cyclodextrin-Acetylferrocene- Thiosemicarbazone Inclusion Complex and Micro-Environmental Effects [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1568-1572.
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URL: |
https://www.gpxygpfx.com/EN/Y2005/V25/I10/1568 |
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