光谱学与光谱分析 |
|
|
|
|
|
Changes in Chemistry Component Structure and Microstructure Characterization of Acetylated Wood Before and After UV Radiation |
FU Zhan, LIU Yi, XING Fang-ru, GUO Hong-wu* |
College of Material Science and Technology, Beijing Forestry University, Beijing 100083, China |
|
|
Abstract The poplar powder was acetylated with different duration as sample, processed ray radiation by using ultraviolet test box, contrasting the influences to lightfastness of wood with different acetylation degree, analyzing changing rules of characteristic peaks’ intensity which belonged to the chemistry components of samples based on FTIR spectra, and the relationship between duration of acetylation and changes of chemistry components was established, The results showed that: Before UV radiation, the characteristic peaks’ intensity of acetylated poplar powder at 1 739 cm-1 which belonged to CO in saturated esters compounds and 1 385 cm-1 which belonged to C—H in acetate were higher than untreated ones’, the poplar powder with 40 min’s acetylation has the highest characteristic peaks’ intensity, highest weight gain rate, remarkable acetylation effect; After UV radiation, characteristic peaks’ intensity of Benzene at 1 504 cm-1 which belonged to lignin of poplar powder was obviously higher than untreated ones’, and characteristic peaks’ intensity of poplar powder with 40 min’s acetylation was the highest, this showed that acetylation could effectively reduce the light degradation of wood chemistry components, in order to improve the lightfastness, especially the poplar powder with 40 min’s acetylation; SEM photos showed that, the fibrous surface of acetylated poplar powder was more smooth and had more narrow particle size than untreated ones’, so acetylation can effectively improve the stability of wood.
|
Received: 2013-11-15
Accepted: 2014-03-09
|
|
Corresponding Authors:
GUO Hong-wu
E-mail: ghw5052@163.com
|
|
[1] GUO Hong-wu, LI Li, WANG Jin-lin, et al(郭洪武, 李 黎, 王金林, 等). Forestry Machinery and Wood Working Equipment(林业机械与木工设备), 2011, 39(6): 15, [2] GUO Hong-wu, LI Li, YAN Hao-peng(郭洪武, 李 黎, 闫昊鹏). Forestry Machinery and Wood Working Equipment(林业机械与木工设备), 2011, 39(1): 35. [3] SUN Li-jun, WANG Hong-li, GAO Jian-min(孙利军, 王宏棣, 高建民). Forestry Science and Technology(林业科技), 2005, 30(3): 60. [4] GUO Hong-wu, YAN Hao-peng, WANG Jin-lin, et al(郭洪武, 闫昊鹏, 王金林, 等). Journal of Beijing Forestry University(北京林业大学学报), 2010, 32(1): 89. [5] ZHANG Shang-zhen(张上镇). China Forest Products Industry(林产工业), 1985, 4(2): 17. [6] Yingchuanzhishita(樱川智史他). Industrial Technology Center, Sizuoka(静冈工业技术中心), 1994, (39): 21. [7] ZHANG Hui-ting, ZHANG Shang-zhen(张惠婷, 张上镇). Quarterly Journal of Chinese Forestry(中华林学季刊), 1999, 32(3): 381 [8] Rowell R M, Simonsen R, Hess S, et al. Wood Fibre Science, 1994, 26(l): 11. [9] Ohkoshi M, Kato A. Mokuzai Gakkaishi, 1997, 43(4): 364. [10] DUAN Xin-fang, LI Jian, LIU Yi-xing(段新芳,李 坚,刘一星). China Wood Industry(木材工业), 1998, 12(5): 15. [11] QU Bao-xue, QIN Te-fu, CHU Fu-xiang, et al(曲保雪, 秦特夫, 储富祥,等). China Wood Industry(木材工业), 2012, 26(3): 25. [12] Mohebby B, Militz H. International Biodeterioration and Biodegradation, 2010, 64(1): 41. [13] Kurimoto Yasuji, Sasaki Sei. Journal of WoodScience, 2013, 59(3): 216. [14] Fojutowski Andrzej, Kozirog Anna, Kropacz Aleksandra, et al. International Biodeterioration and Biodegradation, 2014, 86: 60. [15] NIU Cheng, WU Zhou-xin, WANG Xi-bin, et al(牛 成,吴周新,王锡彬,等). China Synthetic Fiber Industry(合成纤维工业), 2009, 32(4): 21.
|
[1] |
XU Qi-lei, GUO Lu-yu, DU Kang, SHAN Bao-ming, ZHANG Fang-kun*. A Hybrid Shrinkage Strategy Based on Variable Stable Weighted for Solution Concentration Measurement in Crystallization Via ATR-FTIR Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1413-1418. |
[2] |
KAN Yu-na1, LÜ Si-qi1, SHEN Zhe1, ZHANG Yi-meng1, WU Qin-xian1, PAN Ming-zhu1, 2*, ZHAI Sheng-cheng1, 2*. Study on Polyols Liquefaction Process of Chinese Sweet Gum (Liquidambar formosana) Fruit by FTIR Spectra With Principal Component Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1212-1217. |
[3] |
YUE Kong, LU Dong, SONG Xue-song. Influence of Thermal Modification on Poplar Strength Class by Fourier Infrared Spectroscopy Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 848-853. |
[4] |
YAN Li-dong1, ZHU Ya-ming1*, CHENG Jun-xia1, GAO Li-juan1, BAI Yong-hui2, ZHAO Xue-fei1*. Study on the Correlation Between Pyrolysis Characteristics and Molecular Structure of Lignite Thermal Extract[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 962-968. |
[5] |
LI Zong-xiang1, 2, ZHANG Ming-qian1*, YANG Zhi-bin1, DING Cong1, LIU Yu1, HUANG Ge1. Application of FTIR and XRD in Coal Structural Analysis of Fault
Tectonic[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 657-664. |
[6] |
CHENG Xiao-xiao1, 2, LIU Jian-guo1, XU Liang1*, XU Han-yang1, JIN Ling1, SHEN Xian-chun1, SUN Yong-feng1. Quantitative Analysis and Source of Trans-Boundary Gas Pollution in Industrial Park[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3762-3769. |
[7] |
ZHANG Hao1, 2, HAN Wei-sheng1, CHENG Zheng-ming3, FAN Wei-wei1, LONG Hong-ming2, LIU Zi-min4, ZHANG Gui-wen5. Thermal Oxidative Aging Mechanism of Modified Steel Slag/Rubber Composites Based on SEM and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3906-3912. |
[8] |
CHEN Jing-yi1, ZHU Nan2, ZAN Jia-nan3, XIAO Zi-kang1, ZHENG Jing1, LIU Chang1, SHEN Rui1, WANG Fang1, 3*, LIU Yun-fei3, JIANG Ling3. IR Characterizations of Ribavirin, Chloroquine Diphosphate and
Abidol Hydrochloride[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2047-2055. |
[9] |
MA Fang1, HUANG An-min2, ZHANG Qiu-hui1*. Discrimination of Four Black Heartwoods Using FTIR Spectroscopy and
Clustering Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1915-1921. |
[10] |
ZHANG Dian-kai1, LI Yan-hong1*, ZI Chang-yu1, ZHANG Yuan-qin1, YANG Rong1, TIAN Guo-cai2, ZHAO Wen-bo1. Molecular Structure and Molecular Simulation of Eshan Lignite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1293-1298. |
[11] |
WANG Fang-fang1, ZHANG Xiao-dong1, 2*, PING Xiao-duo1, ZHANG Shuo1, LIU Xiao1, 2. Effect of Acidification Pretreatment on the Composition and Structure of Soluble Organic Matter in Coking Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 896-903. |
[12] |
HU Chao-shuai1, XU Yun-liang1, CHU Hong-yu1, CHENG Jun-xia1, GAO Li-juan1, ZHU Ya-ming1, 2*, ZHAO Xue-fei1, 2*. FTIR Analysis of the Correlation Between the Pyrolysis Characteristics and Molecular Structure of Ultrasonic Extraction Derived From Mid-Temperature Pitch[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 889-895. |
[13] |
YANG Jiong1, 2, QIU Zhi-li1, 4*, SUN Bo3, GU Xian-zi5, ZHANG Yue-feng1, GAO Ming-kui3, BAI Dong-zhou1, CHEN Ming-jia1. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 446-453. |
[14] |
HE Xiong-fei1, 2, HUANG Wei3, TANG Gang3, ZHANG Hao3*. Mechanism Investigation of Cement-Based Permeable Crystalline Waterproof Material Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3909-3914. |
[15] |
ZHOU Jing1,2, ZHANG Qing-qing1,2, JIANG Jin-guo2, NIE Qian2, BAI Zhong-chen1, 2*. Study on the Rapid Identification of Flavonoids in Chestnut Rose (Rosa Roxburghii Tratt) by FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3045-3050. |
|
|
|
|