光谱学与光谱分析 |
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Discrimination of Polysaccharides from Angelica Sinensis and Its Different Processed Products Based on Fourier Transform Infrared Spectroscopy |
JI Peng, WEI Yan-ming*, HUA Yong-li, ZHANG Wen-quan |
College of Veterinary Medicine, Gansu Agricultural University, Lanzhou 730070, China |
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Abstract A new rapid and nondestructive method for identifying polysaccharides from Angelica sinensis and its different processed products was developed, and this method was based on Fourier transform infrared spectroscopy (FTIR). In the clinic of traditional Chinese medicine, unprocessed Angelica sinensis(UAS) is of ten used after processed, the common processed products are Angelica sinensis parched with wine(WAS), Angelica sinensis parched with soil(SAS), Angelica sinensis parched with oil(OAS) and Charred Angelica sinensis(CAS). In order to use polysaccharides from Angelica sinensis and its processed products effectively and reasonably in clinic, it is very necessary to identify them. FTIR of polysaccharides from Angelica sinensis and its different processed products was determined, and then it was decomposed by discrete wavelet transform (DWT). The high frequency information in scale 2, 3 and 4 was selected as feature information, from which the each wavelet entropy was extracted as characteristic value. BP neural network was trained with these characteristic values. The trained BP neural network was used to identify polysaccharides from Angelica sinensis and its different processed products. According to 30 prediction samples, the correct rate for recognition was 93.3%, which indicates that: it has better feasibility to identify polysaccharides from Angelica sinensis and its different processed products by this method, which is based on FTIR, discrete wavelet transform and BP neural network.
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Received: 2013-07-02
Accepted: 2013-10-28
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Corresponding Authors:
WEI Yan-ming
E-mail: weiym@gsau.edu.cn
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[1] GUO Yan-sheng, HUA Yong-li, DU Tian-xi, et al(郭延生, 华永丽, 杜天玺, 等). China Journal of Chinese Materia Medica(中国中药杂志), 2010, 35(12): 1551. [2] JIN Feng-yun, TIAN Yuan-hong, YANG Wen-xun(靳凤云, 田源红, 杨文洵). China Journal of Chinese Materia Medica(中国中药杂志), 2000, 25(8): 474. [3] HUA Yong-li, WEI Yan-ming, GUO Yan-sheng, et al(华永丽, 魏彦明, 郭延生, 等). Chinese Journal of Analytical Chemistry(分析化学), 2012, 40(4): 602. [4] GUO Yan-sheng, HUA Yong-li, DU Tian-xi, et al(郭延生, 华永丽, 杜天玺, 等). Acta Pharmaceutica Sinica(药学学报), 2010, 45(9): 1155. [5] WEI Yan-ming, GUO Yan-sheng, QU Ya-ling, et al(魏彦明, 郭延生, 曲亚玲, 等). Natural Product Reseach and Development(天然产物研究与开发), 2010, 22(5): 878. [6] ZHAO Yu-cong, LI Li-hong(赵玉丛, 李利红). Chinese Journal of Veterinary Medicine(中国兽医杂志), 2011, 47(6): 71. [7] FENG Shuai, LIU Yang, WANG Xiao-yan, et al(冯 帅, 刘 杨, 王晓燕,等). Chinese Journal of Experimental Traditional Medical Formulae(中国实验方剂学杂志),2013, 19(9): 143. [8] YU Peng, XU Rui, CHENG Cun-gui(余 鹏, 徐 锐, 程存归). Chinese Journal of Analytical Chemistry(分析化学), 2012, 40(3): 371. [9] SHI You-ming, LIU Gang, LIU Jian-hong, et al(时有明, 刘 刚, 刘剑虹,等). Acta Optica Sinica(光学学报), 2007, 27(1): 129. [10] State Pharmacopoeia Committee of People’s Republic of China(国家药典委员会). Pharmacopoeia Commission of the People’s Republic of China, 2005 Ed. PartⅠ(中国药典2005版一部). Beijing: Chemical Industry Press(北京: 化学工业出版社), 2005. 89. [11] Gansu Province Health Department(甘肃省卫生厅). Gansu Processing Standard of Traditional Chinese Medicine. 1st Ed.(甘肃省中药炮制规范). Lanzhou: Gansu People’s Publishing House(兰州: 甘肃人民出版社), 1999. 53. |
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