| 光谱学与光谱分析 |
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| Experimental Study on the Non-Resonant Signal of the CARS Process in Mixture |
| HOU Guo-hui, YIN Jun, JING Li-qing, LIU Wei, LIN Zi-yang, NIU Han-ben* |
| Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China |
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Abstract Coherent anti-Stokes Raman scattering is a nonlinear coherent four-wave mixing effect. But it is hard to quantitatively spectral analyze material components by detecting coherent signal. In the present paper, the resonant and non-resonant signals of mixture of ethanol and water with different volume ratio were experimentally studied with a single-frequency coherent anti-Stokes Raman scattering spectral method. By analyzing the experimental results, we found that the intensity of resonance signals at frequency 2 876 cm-1 is increased with the increase in volume ratio of ethanol and it is quadratic, but the intensity of non-resonant signal linearly increased with the volume ratio of ethanol. So the non-resonance intensity signal is linear with the concentration of the number of molecules N. Therefore, detecting the non-resonance signal will provide a way for the quantitative spectral analysis of the specific ingredients in the mixture.
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Received: 2012-09-06
Accepted: 2012-12-18
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Corresponding Authors:
NIU Han-ben
E-mail: hbniu@szu.edu.cn
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