光谱学与光谱分析 |
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Study on Sr3LiMgV3O12∶Eu3+ Single-Phase Phosphor for White LED |
XU Guo-tang1, LIANG Pei1*, HUANG Jie1, WANG Le1, DONG Qian-min1, LIU Yang1, HUA You-jie2 |
1. College of Optical and Electronic Science, China Jiliang University,Hangzhou 310018, China2. College of Material Science, China Jiliang University,Hangzhou 310018, China |
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Abstract A novel broadband emission phosphor Sr3-2xLi1+xMgV3O12∶xEu3+ was synthesized by a solid-state reaction method. Then discussed the luminous property under the influence of temperature and doping density of Eu3+, was discussed. X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence spectra were used to characterize the feature of Sr3-2xLi1+xMgV3O12∶xEu3+. The excitation and emission spectra exhibit that the phosphor of Sr<sub>3-2xLi1+xMgV3O12∶xEu3+ matches with nearly ultraviolet chip. The emission band covers from 450 to 630 nm, which shows that the phosphor is promising single-phase phosphors for white LED.
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Received: 2012-07-15
Accepted: 2012-11-25
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Corresponding Authors:
LIANG Pei
E-mail: plianghust@gmail.com
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[1] Zhang R, Wang X. Journal of Alloys and Compounds, 2011, 509: 1197. [2] Mueller A H, Petruska M A, Achermann M, et al. Nano Letters, 2005, 5(6): 1039. [3] Zhang Yan, Xu Jiayue, Zhang Tingting. Journal of Inorganic Materials, 2011, 26(12): 1. [4] Zhang M, Wang J, Zhang Z, et al. Appl. Phys. B, 2008, 93: 829. [5] Ye S, Xiao F, Pan Y X, et al. Materials Science and Engineering R., 2010, 71: 1. [6] Bowers M J, McBride J R, Rosenthal S J. J. Am. Chem. Soc., 2005, 127: 15378. [7] Lee G H, Kim T H, Yoon C, et al. Journal of Luminescence, 2008, 128: 1922. [8] Kim J S, Jeon P E, Park Y H, et al. J. Electrochem. Soc., 2005, 152(2): H29. [9] YAN Xiao-song, LI Wan-wan, LIU Ji, et al(严小松, 李万万, 刘 霁, 等). Chin. J. Lumin.(发光学报),2010, 31: 39. [10] Guo N, Huang Y J, You H P, et al. Inorg. Chem., 2010, 49: 10907. [11] Jiang Z Q, Wang Y H. Electrochem, Solid-State Lett., 2010, 13(5): J68. [12] Yang W J, Luo L, Chen T M, et al. Chem. Mater.,2005, 17:3883. [13] Wang Z, Liang H, Gong M, et al. Electrochem. Solid-State Lett., 2005, 8(4): H33. [14] Blasse G, Bril A. J. Chem. Phys., 1967, 47: 5442. [15] Setlur A A, Comanzo H A, Srivastava A M, et al. J. Electrochem. Soc., 2005, 152(12): H205. [16] Hsiao Y J, Chai Y L, Ji L W. Materials Letters, 2012, 70: 163. [17] Neeraj S, Kijima N, Cheetham A K. Solid State Communications, 2004, 131: 65. [18] Tomohiko Nakajima, Masahiko Isobe, Tetsuo Tsuchiya, et al. J. Phys. Chem. C, 2010, 114: 5160. [19] Zhou Z, Wang F C, Miu S Q, et al. J. Electrochem. Soc., 2011, 158(12): H1238. [20] Nakajimaa T, Isobeb M, Tsuchiya T, et al. Optical Materials, 2010, 32(12): 1618. |
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