| 光谱学与光谱分析 |
|
|
|
|
|
| In-situ FTIR Study on the Absorption and Transformation of Glyoxal on the Surface of Dust Particles |
| SHEN Xiao-li, CHEN Zhong-ming*, ZHAO Yue, HUANG Dao |
| State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China |
|
|
|
|
Abstract Glyoxal is one of the most important volatile organic compounds in the atmosphere. The reactions of glyoxal in the gaseous and aqueous phases and on the surfaces of secondary inorganic acidic aerosols can lead to atmospheric secondary organic aerosol (SOA) formation. However, up to now, there is no report on the heterogeneous reaction of glyoxal on dust particles. The present work investigated the heterogeneous absorption and transformation mechanisms of glyoxal on SiO2 and α-Al2O3 particles. The progress of heterogeneous reaction conducted in the flow tube reactor was in situ monitored by transmission Fourier transform Infrared (T-FTIR). The reaction products were analyzed by combining T-FTIR with HPLC, IC, and HPLC-MS. It was found that oligomers form after the glyoxal is absorbed onto the particles (SiO2 and α-Al2O3); and for α-Al2O3, organic acids form on the particle surface in absence of illumination and oxidants. Moreover, it was revealed that water vapor favors the formation of oligomers, but suppresses the production of organic acids. These findings help further understand the SOA formation from the heterogeneous reaction of glyoxal on dust in the atmosphere.
|
|
Received: 2012-04-30
Accepted: 2012-07-26
|
|
|
|
Corresponding Authors:
CHEN Zhong-ming
E-mail: zmchen@pku.edu.cn
|
|
[1] Fu T M, Jacob D J, Wittrock F, et al. Journal of Geophysical Research, 2008, 113(D15): D15303.
[2] Ervens B, Volkamer R. Atmospheric Chemistry and Physics, 2010, 10(17): 8219.
[3] Liggio J, Li S M, McLaren R. Journal of Geophysical Research, 2005, 110(D10): D10304.
[4] Corrigan A L, Hanley S W, De Haan D O. Environmental Science & Technology, 2008, 42(12): 4428.
[5] Galloway M M, Chhabra P S, Chan A W H, et al. Atmospheric Chemistry and Physics, 2009, 9(10): 3331.
[6] Trainic M, Riziq A A, Lavi A, et al. Atmospheric Chemistry and Physics, 2011, 11(18): 9697.
[7] Jonas P, Charlson R, Rodhe H. Cambridge, UK: Cambridge University Press, 1995.
[8] Zhao Y, Chen Z M. Applied Spectroscopy Reviews, 2010, 45(1): 63.
[9] Chen Z M, Jie C Y, Li S, et al. Journal of Geophysical Research, 2008, 113(D22): D22303.
[10] Zhao Y, Chen Z M, Zhao J N. Environmental Science & Technology, 2010, 44(6): 2035.
[11] Loeffler K W, Koehler C A, Paul N M, et al. Environmental Science & Technology, 2006, 40(20): 6318.
[12] Wang L, Xu W, Khalizov A F, et al. Journal of Physical Chemistry A, 2011, 115(32): 8940.
[13] Tong S R, Wu L Y, Ge M F, et al. Atmospheric Chemistry and Physics, 2010, 10(16): 7561.
[14] Nozière B, Dziedzic P, Córdova A. Journal of Physical Chemistry A, 2009, 113(1): 231.
[15] Setokuchi O. Physical Chemistry Chemical Physics, 2011, 13(13): 6296. |
| [1] |
WANG Jie1, 2, 3, LIU Wen-qing1, 2, 4, ZHANG Tian-shu1, XIA Jian-dong5, DENG Wei5, HU Wen-jie5. Collaborative Observation of Vertical Structures of Ozone and Aerosol in a Dust Episode Based on Lidar[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2258-2265. |
| [2] |
WU Zhi-yu1, XIN Zhi-ming2, JIANG Qun-ou1*, YU Yang1, WANG Zi-xuan1. Analysis of Dust Source and Dust Transport Path of a Typical Dust Event in Arid Area of Northwest China Based on HYSPLIT Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1862-1868. |
| [3] |
XU Qi-lei, GUO Lu-yu, DU Kang, SHAN Bao-ming, ZHANG Fang-kun*. A Hybrid Shrinkage Strategy Based on Variable Stable Weighted for Solution Concentration Measurement in Crystallization Via ATR-FTIR Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1413-1418. |
| [4] |
KAN Yu-na1, LÜ Si-qi1, SHEN Zhe1, ZHANG Yi-meng1, WU Qin-xian1, PAN Ming-zhu1, 2*, ZHAI Sheng-cheng1, 2*. Study on Polyols Liquefaction Process of Chinese Sweet Gum (Liquidambar formosana) Fruit by FTIR Spectra With Principal Component Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1212-1217. |
| [5] |
YAN Li-dong1, ZHU Ya-ming1*, CHENG Jun-xia1, GAO Li-juan1, BAI Yong-hui2, ZHAO Xue-fei1*. Study on the Correlation Between Pyrolysis Characteristics and Molecular Structure of Lignite Thermal Extract[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 962-968. |
| [6] |
LI Zong-xiang1, 2, ZHANG Ming-qian1*, YANG Zhi-bin1, DING Cong1, LIU Yu1, HUANG Ge1. Application of FTIR and XRD in Coal Structural Analysis of Fault
Tectonic[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 657-664. |
| [7] |
CHENG Xiao-xiao1, 2, LIU Jian-guo1, XU Liang1*, XU Han-yang1, JIN Ling1, SHEN Xian-chun1, SUN Yong-feng1. Quantitative Analysis and Source of Trans-Boundary Gas Pollution in Industrial Park[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3762-3769. |
| [8] |
ZHANG Hao1, 2, HAN Wei-sheng1, CHENG Zheng-ming3, FAN Wei-wei1, LONG Hong-ming2, LIU Zi-min4, ZHANG Gui-wen5. Thermal Oxidative Aging Mechanism of Modified Steel Slag/Rubber Composites Based on SEM and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3906-3912. |
| [9] |
LI Feng1, LIN Jing-jing2, YUN Jie3, ZHANG Shuai4*, WANG He5, ZHANG Hai4, TAO Zong-ming6. Analysis on Variation Characteristics of Air Pollution in Jining City Based on Lidars Networking Observation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3467-3475. |
| [10] |
CHEN Jing-yi1, ZHU Nan2, ZAN Jia-nan3, XIAO Zi-kang1, ZHENG Jing1, LIU Chang1, SHEN Rui1, WANG Fang1, 3*, LIU Yun-fei3, JIANG Ling3. IR Characterizations of Ribavirin, Chloroquine Diphosphate and
Abidol Hydrochloride[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2047-2055. |
| [11] |
MA Fang1, HUANG An-min2, ZHANG Qiu-hui1*. Discrimination of Four Black Heartwoods Using FTIR Spectroscopy and
Clustering Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1915-1921. |
| [12] |
ZHANG Dian-kai1, LI Yan-hong1*, ZI Chang-yu1, ZHANG Yuan-qin1, YANG Rong1, TIAN Guo-cai2, ZHAO Wen-bo1. Molecular Structure and Molecular Simulation of Eshan Lignite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1293-1298. |
| [13] |
WANG Fang-fang1, ZHANG Xiao-dong1, 2*, PING Xiao-duo1, ZHANG Shuo1, LIU Xiao1, 2. Effect of Acidification Pretreatment on the Composition and Structure of Soluble Organic Matter in Coking Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 896-903. |
| [14] |
HU Chao-shuai1, XU Yun-liang1, CHU Hong-yu1, CHENG Jun-xia1, GAO Li-juan1, ZHU Ya-ming1, 2*, ZHAO Xue-fei1, 2*. FTIR Analysis of the Correlation Between the Pyrolysis Characteristics and Molecular Structure of Ultrasonic Extraction Derived From Mid-Temperature Pitch[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 889-895. |
| [15] |
YANG Jiong1, 2, QIU Zhi-li1, 4*, SUN Bo3, GU Xian-zi5, ZHANG Yue-feng1, GAO Ming-kui3, BAI Dong-zhou1, CHEN Ming-jia1. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 446-453. |
|
|
|
|
