光谱学与光谱分析 |
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AgBr Colloids Prepared by Electrolysis and Their SERS Activity Research |
SI Min-zhen1,FANG Yan2,DONG Gang1,ZHANG Peng-xiang3 |
1. Department of Physics and Electronic Science, Chuxiong Teacher’s College, Chuxiong 675000, China 2. Beijing Key Lab of Nano-photonics and Nano-Structure(NPNS), Department of Physics, Capital Normal University, Beijing100037, China 3. IAMPE Kunming University of Science and Technology, Kunming 651000, China |
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Abstract Ivory-white AgBr colloids were prepared by means of electrolysis. Two silver rods 1.0 cm in diameter and 10.0 cm long were respectively used as the negative and positive electrodes,the aqueous solution of hexadecyl trimethyl ammonium bromide was used as the electrolyte, and a 7 V direct current was applied on the silver rods for three hours. The obtained AgBr colloids were characterized by UV-Vis spectroscopy, transmission electron microscopy, and SERS using a 514.5 nm laser line on Renishaw 2000 Raman spectrometer. These particles are about nanometer size and their shapes are as spherical or elliptic, with a slight degree of particle aggregation. The UV-Vis spectra exhibit a large plasmon resonance band at about 292.5 nm, similar to that reported in the literature. The AgBr colloids were very stable at room temperature for months. In order to test if these AgBr colloids can be used for SERS research, methyl orange, Sudan red and pyridine were used. It was found that AgBr colloids have SERS activity to these three molicules. For methyl orange, the intense Raman peaks are at 1 123, 1 146, 1 392, 1 448 and 1 594 cm-1;for Sudan red, the intense Raman peaks are at 1 141, 1 179, 1 433 and 1 590 cm-1;and for pyridine, the intense Raman peaks are at 1 003, 1 034 and 1 121 cm-1. It is noticeable that SERS of methyl orange was observed on AgBr colloids, but not on the gray and yellow silver colloids prepared by traditional means. The possible reason was explained. One major advantage of this means is the absence of the spectral interference such as citrate, BH-4 arising from reaction products of the colloids formation process. On AgBr colloids, one can get some molecular SERS impossible to get on the gray and yellow silver colloids.
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Received: 2006-07-10
Accepted: 2006-11-20
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Corresponding Authors:
SI Min-zhen
E-mail: siminzhen@cxtc.edu.cn
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[1] WANG Yu, LI Ying-sing, ZHANG Zheng-xing, et al(王 玉, LI Ying-sing, 张正行, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(11): 1376. [2] QIU Li-qun, GU Ren-ao(仇立群, 顾仁敖). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(5): 547. [3] KE Wei-zhong, WU Jian-zhong(柯惟中, 吴缄中). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(5): 551. [4] ZHOU Hai-hui, WU De-yin, HU Jian-qiang, et al(周海辉, 吴德印, 胡建强, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(7) : 1068. [5] SI Min-zhen, ZI Xing-fa, WU Rong-guo, et al(司民真,自兴发,武荣国, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析) ,2006,26(8): 1472. [6] Lee P C, Meisel D P. J. Phys. Chem., 1982, 86: 3391. [7] Creighton J A. Chem. Soc. Faraday Trans, 1979, 75(2): 790. [8] Munro C H, Smith W E, Garner M, et al. Langmuir, 1995, 11: 3712. [9] Teiten B, Burneau A. Journal of Colloid and Interface Science, 1998,206: 267. [10] Takeshi Tsuji, Kenzo Iryo, Yukio Nishimura, eyt al. Journal of Photochemistry and Photobiology A: Chemistry,2001, 145: 201. [11] Hyeon Suk Shin, Hyun Jung Yang, Seung Bin Kim, et al. Journal of Colloid and Interface Science,2004,274: 89. [12] ZHANG Jian-bing, FANG Yan(张建兵, 方 炎). Journal of Opt. Electronics ·Laser(光电子·激光),2005, 16(7): 845. [13] Yun Xiao, Ying-Sing Li, George H. Swihart. Talanta,2002, 58: 755. [14] Wang Jian, Li Dawei, Xin Houwen, et al. Spectrochimica Acta Part A: Molecular Spectroscopy, 1987, 43(3): 375. [15] ZHANG Ying-hui, CHEN Dong-ming, HE Tian-jing, et al(章应辉, 陈东明, 何天敬, 等). Chin. J. Chem. Phys.(化学物理学报),2001,14(3): 315. [16] ZHANG Ying-hui, LOU Jian-ying, CHEN Dong-ming, et al(章应辉, 楼健英, 陈东明, 等). Chinese Journal of Light Scattering(光散射学报),2002, 14(2): 87. [17] HE Feng, WANG Wu-xiang, HAN Ya-fang, et al(何 峰,汪武祥,韩雅芳,等). Powder Metallurgy Technology(粉末冶金技术),2001, 19(2): 80. [18] ZHAO Jun-wu, WANG Yong-chang, ZHU Jian(赵军武,王永昌,朱 键). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(12): 1609. [19] ZHU Jian, WANG Yong-chang(朱 键,王永昌). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(2): 235. [20] Maen Husein, Eva Rodil, Juan H Vera. Journal of Colloid and Interface Science,2004,273: 426. [21] Ohde H, Rodrignes J M, Ye X R, et al. Chemical Communication,2000, (23): 2353. [22] Correa N M, Zhang H, Schelly Z A. J. Am. Chem. Soc.,2000, 122: 6432. [23] Zhang H, Schelly Z A, Marynick D S. J. Phys. Chem. A,2000, 104: 6287. |
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