| 光谱学与光谱分析 |
|
|
|
|
|
| Experimental Investigation of Quantitatively Analysing Trace Mo in Complex Metallic Alloys by Laser Induced Breakdown Spectroscopy |
| WANG Zhen-nan, LI Ying, ZHANG Qing-yu, LU Yuan, ZHENG Rong-er* |
| Optics and Optoelectronics Laboratory, Ocean University of China, Qingdao 266100, China |
|
|
|
|
Abstract The quantitative analysis using laser induced breakdown spectroscopy (LIBS), lack of appropriate interior label element, is described and applied to trace element molybdenum (Mo) detection in complex metallic alloys. A Q-switched Nd∶YAG laser operating at 532 nm was utilized to generate plasma and the emission was recorded by a grating spectrometer equipped with CCD, boxcar and PMT. The three peak heights of Mo Ⅰ, 550.649, 553.305 and 557.045 nm, changing with Mo mass fraction in metallic alloys were measured to produce calibration curves respectively, and double blind method was used to analyse a test sample. Based on Mo Ⅰ 550.649 nm line, the Mo mass fraction in the test sample was determined to be 2.229% with relative error of 5.57% in comparison with the given value of 2.111%. On using Mo Ⅰ 557.045 nm line, the relative error was found to be doubled due to the overlap with Fe emission lines. While taking the total height of three atomic lines into account in analysis, the resulted error dropped to 7.58%, even better than the average of predicted concentrations based on the above three lines. The obtained results demonstrate that satisfactory precision could be obtained under a consistent experiment condition with the above scheme, even without appropriate interior label element. The methods of maintaining stable laser ablation efficiency on sample are also discussed.
|
|
Received: 2010-09-13
Accepted: 2010-12-06
|
|
|
|
Corresponding Authors:
ZHENG Rong-er
E-mail: rzheng@ouc.edu.cn
|
|
[1] Bustamante M F, Rinaldi C A, Ferrero J C. Spectrochimica Acta Part B, 2002, 57: 303.
[2] Bousquet B, Travalillé G, Ismaёl A, et al. Spectrochimica Acta Part B, 2008, 63: 1085.
[3] García-Ayuso L E, Amador-Hernández J, Fernández-Romero J M, et al. Analytica Chimica Acta, 2002, 457: 247.
[4] Rosenwasser S, Asimellis G, Bromley B, et al. Spectrochimica Acta Part B, 2001, 56: 707.
[5] Death D L, Cunningham A P, Pollard L J. Spectrochimica Acta Part B, 2009, 64: 1048.
[6] Colao F, Fantoni R, Lazic V, et al. Spectrochimica Acta Part B, 2002, 57: 1219.
[7] Louis Barrette, Simon Turmel. Spectrochimica Acta Part B, 2001, 56: 715.
[8] Nilesh K Rai, Awadhesh K Rai, Akshaya Kumar, et al. Applied Optics, 2008, 47(31): 105.
[9] William Pearman, Jon Scaffidi, Michael Angel S. Applied Optics, 2003, 42(30): 6085.
[10] Yueh Fang-yu, Zheng Hongbo, Singh Jagdish P, et al. Spectrochimica Acta Part B, 2009, 64: 1059.
[11] Jens Vrenegor, Reinhard Noll, Volker Sturm. Spectrochimica Acta Part B, 2005, 60: 1083.
[12] Walid Tawfik Y. Mohamed. Optics & Laser Technology, 2008, 40: 30.
[13] CUI Zhi-feng, ZHANG Xian-yi, YAO Guan-xin, et al(崔执凤, 张先燚, 姚关心, 等). Acta Physica Sinica(物理学报), 2006, 55(9): 4506.
[14] XIE Cheng-li, LU Ji-dong., LI Yong, et al(谢承利, 陆继东, 李 勇, 等). Journal of Huazhong University of Science and Technology(Natural Science Edition)(华中科技大学学报·自然科学版), 2008, 29(10): 3375.
|
| [1] |
LIU Jia1, 2, GUO Fei-fei2, YU Lei2, CUI Fei-peng2, ZHAO Ying2, HAN Bing2, SHEN Xue-jing1, 2, WANG Hai-zhou1, 2*. Quantitative Characterization of Components in Neodymium Iron Boron Permanent Magnets by Laser Induced Breakdown Spectroscopy （LIBS）[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 141-147. |
| [2] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1，ZHAO Yan-jie1*，NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
| [3] |
YANG Wen-feng1, LIN De-hui1, CAO Yu2, QIAN Zi-ran1, LI Shao-long1, ZHU De-hua2, LI Guo1, ZHANG Sai1. Study on LIBS Online Monitoring of Aircraft Skin Laser Layered Paint Removal Based on PCA-SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3891-3898. |
| [4] |
LIN Hong-jian1, ZHAI Juan1*, LAI Wan-chang1, ZENG Chen-hao1, 2, ZHAO Zi-qi1, SHI Jie1, ZHOU Jin-ge1. Determination of Mn, Co, Ni in Ternary Cathode Materials With
Homologous Correction EDXRF Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3436-3444. |
| [5] |
HUANG Li, MA Rui-jun*, CHEN Yu*, CAI Xiang, YAN Zhen-feng, TANG Hao, LI Yan-fen. Experimental Study on Rapid Detection of Various Organophosphorus Pesticides in Water by UV-Vis Spectroscopy and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3452-3460. |
| [6] |
LI Zhong-bing1, 2, JIANG Chuan-dong2, LIANG Hai-bo3, DUAN Hong-ming2, PANG Wei2. Rough and Fine Selection Strategy Binary Gray Wolf Optimization
Algorithm for Infrared Spectral Feature Selection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3067-3074. |
| [7] |
SUN Cheng-yu1, JIAO Long1*, YAN Na-ying1, YAN Chun-hua1, QU Le2, ZHANG Sheng-rui3, MA Ling1. Identification of Salvia Miltiorrhiza From Different Origins by Laser
Induced Breakdown Spectroscopy Combined with Artificial Neural
Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3098-3104. |
| [8] |
LIU Shu1, JIN Yue1, 2, SU Piao1, 2, MIN Hong1, AN Ya-rui2, WU Xiao-hong1*. Determination of Calcium, Magnesium, Aluminium and Silicon Content in Iron Ore Using Laser-Induced Breakdown Spectroscopy Assisted by Variable Importance-Back Propagation Artificial Neural Networks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3132-3142. |
| [9] |
KONG De-ming1, LIU Ya-ru1, DU Ya-xin2, CUI Yao-yao2. Oil Film Thickness Detection Based on IRF-IVSO Wavelength Optimization Combined With LIF Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2811-2817. |
| [10] |
ZHAO Yu-wen1, ZHANG Ze-shuai1, ZHU Xiao-ying1, WANG Hai-xia1, 2*, LI Zheng1, 2, LU Hong-wei3, XI Meng3. Application Strategies of Surface-Enhanced Raman Spectroscopy in Simultaneous Detection of Multiple Pathogens[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2012-2018. |
| [11] |
LI Chang-ming1, CHEN An-min2*, GAO Xun3*, JIN Ming-xing2. Spatially Resolved Laser-Induced Plasma Spectroscopy Under Different Sample Temperatures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2032-2036. |
| [12] |
ZHAO Yang1, ZHANG Lei2, 3*, CHENG Nian-kai4, YIN Wang-bao2, 3*, HOU Jia-jia5, BAI Cheng-hua1. Research on Space-Time Evolutionary Mechanisms of Species Distribution in Laser Induced Binary Plasma[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2067-2073. |
| [13] |
WANG Bin1, 2, ZHENG Shao-feng2, GAN Jiu-lin1, LIU Shu3, LI Wei-cai2, YANG Zhong-min1, SONG Wu-yuan4*. Plastic Reference Material (PRM) Combined With Partial Least Square (PLS) in Laser-Induced Breakdown Spectroscopy (LIBS) in the Field of Quantitative Elemental Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2124-2131. |
| [14] |
CHENG Xiao-xiang1, WU Na2, LIU Wei2*, WANG Ke-qing2, LI Chen-yuan1, CHEN Kun-long1, LI Yan-xiang1*. Research on Quantitative Model of Corrosion Products of Iron Artefacts Based on Raman Spectroscopic Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2166-2173. |
| [15] |
HU Meng-ying1, 2, ZHANG Peng-peng1, 2, LIU Bin1, 2, DU Xue-miao1, 2, ZHANG Ling-huo1, 2, XU Jin-li1, 2*, BAI Jin-feng1, 2. Determination of Si, Al, Fe, K in Soil by High Pressure Pelletised Sample and Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2174-2180. |
|
|
|
|
