| 光谱学与光谱分析 |
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| Investigation of FTIR spectra Analysis on Carbon Dioxide Absorption with Improved Amine Solution |
| YIN Wen-xuan1,2，LIU Jian-zhou1，GAO Li-ping1，JIANG Jing-liang1，WANG Zhi-hua1 |
1. College of Chemical Engineering, China University of Mining Technology and Engineering, Xuzhou 221116, China
2. Key Laboratory of Coal Processing and Efficient Utililation, China University of Mining Technology and Engineering, Xuzhou 221116, China |
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Abstract Carbon dioxide is a major sort of greenhouse gas as well as important carbon resource. With the developments of industries, emission of carbon dioxide has increased sharply. Hence, controls of carbon dioxide emission and resource transformation have become the hotspot of current study. As a new kind of carbon resource, the fields of CO2 research andapplication are very extensive. Among those methods, the amine absorption has good qualities of faster absorption rate, higher efficiency and so on, so it has been widely studied. But organic amine have such shortcomings: high consumption of heat energy, strong corrosive and easy oxidated, now pursuer mainly focused on the organic amine modified. The results showed that, when the time the amount of antioxidant 1010 is 0.15%, the absorption capacity is 2 503.53 mL. the volume of analysis is 982.00 mL, and the absorption rate changes more slowly, by FTIR, Samples of its renewable-OH associating is not apparent that the antioxidant content in 1010, oxidation products of the MEA is acid or less oxidation and antioxidant 1010 product in early to respond fully to form stable non-radical compounds. Therefore, the best dosage of antioxidant 1010 is 0.15%. When the time that the amount of Na2SO3 is 0.15%, the absorption capacity is 2 922.88 mL. Analysis of the volume is 7 23.00 mL, by FTIR, which reveals the oxidation products of the MEA is amide CO which in alkaline solution can be transiting into primary amine, and be easy absorbing CO2. Comparing the antioxygenic proerty of antioxidant 1010 with Na2SO3, from the absorption rate, the amount of absorption ，Na2SO3’s antioxidant properties is superior than antioxidant 1010; by infrared spectral analysis，1010/20% MEA solution’s oxidation products is the acid, Na2SO3/20% MEA solutions, the oxidation product is amide, amide solution is advantaged for absorbing CO2, So Na2SO3’s antioxidant properties is superior than antioxidant 1010.
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Received: 2010-06-30
Accepted: 2010-10-02
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Corresponding Authors:
YIN Wen-xuan
E-mail: ywx6499@163.com; ywx6499@cumt.edu.cn
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[1] Mustacchi C, Armenante P, Cena V. Environment International, 1979, 2: 453.
[2] Arnold D S, Barren D A, Isom R H. Environmental Progress, 1994, 139(3): 214.
[3] Tomio Mimura, Hidenobu Simayoshi, Taiichiro Suda，et al. Energy Convers and Management, 1997, 38(S1): 57.
[4] Tomio Mimura, Takashi Nojo, Masaki Iijma, et al. Greenhouse Gas Contral Technologies. 6th International Conference, 2003. 1057.
[5] LI Tian-cheng，FENG Xia, LI Xin-gang(李天成，冯 霞，李鑫钢，等). Chemical Industry and Engineering(化学工业与工程)，2002，19(2)：17.
[6] YIN Wen-xuan，LIU Jian-zhou，WANG Zhi-hua，et al. Coal Engineering，2009，5: 79.
[7] LU Jian-gang，CHEN Min-dong，JI-Yan，et al(陆建刚，陈敏东，嵇 艳，等). Journal of Fuel Chemistry and Technology(燃料化学学报), 2009, 37(6): 740.
[8] LI Si-fang，REN Zheng-wei，LI Pan-sheng，et al(黎四芳，任铮伟，李盘生，等). Journal of Chemical Industry and Engineering(化工学报)，1994，45(6)：698.
[9] Alie C，Backham L, Croiset E，et al. Energy Conversion and Management, 2005，46: 475.
[10] SHI Yan, ZHAN Xian-cheng, Lü Tai-ping, et al(史 焱，詹先成，吕太平，等). Acta Chimica Sinica(化学学报)，2006，64(6)：496.
[11] WU Jin-guang(吴瑾光). Modern Fourier Transform Infrared Spectroscopy, Technology and Applications(近代傅里叶变换红外光谱技术及应用). Beijing: Scientific and Technical References Press of China(北京: 科学技术文献出版社), 1994.
[12] WENG Shi-fu(翁诗甫). FTIR Spectrograph(傅立叶变换红外光谱仪). Beijing: Chemical Industry Press(北京：化学工业出版社)，2005.
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