| 光谱学与光谱分析 |
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| Synthesis and Luminescence Properties of Reactive Ternary Europium Complexes |
| GUO Dong-cai1, 2，SHU Wan-gen1，ZHANG Wei2，LIU You-nian1，ZHOU Yue2 |
1．College of Chemistry and Chemical Engineering, Central Southern University, Changsha 410083, China
2.College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China |
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Abstract In this paper, five new reactive ternary europium complexes were synthesized with the first ligand of 1, 10-phenanthroline and the reactive second ligands of maleic anhydride, acrylonitrile, undecenoic acid, oleic acid and linoleic acid, and also characterized by means of elemental analysis, EDTA titrimetric method, FTIR spectra and UV spectra. The fluorescence spectra show that the five new ternary complexes have much higher luminescence intensity than their corresponding binary complexes, and the synergy ability sequence of the five reactive ligands is as follows: linoleic acid＞oleic acid＞acrylonitrile＞maleic anhydride＞undecenoic acid. At the same time, the reactive ternary europium complexes coordinated with the reactive ligands, which can be copolymerized with other monomers, will provide a new way for the synthesis of bonding-type rare earth polymer functional materials with excellent luminescence properties.
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Received: 2003-12-06
Accepted: 2004-03-28
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Corresponding Authors:
GUO Dong-cai
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| Cite this article: |
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GUO Dong-cai,SHU Wan-gen,ZHANG Wei, et al. Synthesis and Luminescence Properties of Reactive Ternary Europium Complexes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(09): 1028-1031.
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| URL: |
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http://www.gpxygpfx.com/EN/Y2004/V24/I09/1028 |
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