| 光谱学与光谱分析 |
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| Influence of Pr3+ on Eu3+ Luminescence in Three Component Complex System of Eu(ClO4)3-DPSO-Phen |
| LI Wen-xian，ZHONG Rui-xia，LUO Qing-shan |
| Department of Chemistry, Nei Mongol University, Hohhot 010021, China |
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Abstract Different nuclear [(Eu1-xPrx)(DPSO)(phen)3(ClO4)2]ClO4·nH2O(x=0.000-0.200，DPSO as the abbreviation for diphenyl sulfoxide and phen for 1,10-phenanthroline，n=1-6) coordination compounds were synthesized，and were studied by means of composition analysis, conductance, IR spectra and fluorescence excitation and emission spectra. In the fluorescence spectra it was found that Pr3+ has a great influence on the luminescence of Eu3+. The fluorescence emission intensity of europium perchlorate was enhanced when doped with 0.001→0.100 mol Pr3+. The local symmetry of Eu3+ site is low in this coordination compounds.
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Received: 2003-08-16
Accepted: 2003-12-06
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Corresponding Authors:
LI Wen-xian
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| Cite this article: |
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LI Wen-xian,ZHONG Rui-xia,LUO Qing-shan. Influence of Pr3+ on Eu3+ Luminescence in Three Component Complex System of Eu(ClO4)3-DPSO-Phen [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(11): 1306-1308.
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http://www.gpxygpfx.com/EN/Y2004/V24/I11/1306 |
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