| 光谱学与光谱分析 |
|
|
|
|
|
| Absorption Spectra Study of the Association Nanoparticle System of Berberine-[AuI4]- and Its Analytical Application |
| WANG Li-ｓheng1，ZOU Jie-ming1，JIANG Zhi-liang2*，LIAO Zu-he2，PAN Hong-cheng2 |
1. Guilin Sanjin Pharmaceutical Company，Guilin 541004，China
2. Department of Resource and Environmental Science, Guangxi Normal University，Guilin 541004，China |
|
|
|
|
Abstract In 0.008 mol·L-1 HCl medium, [AuCl4]- and I- combine to form [AuI4]-. [AuI4]- reacts with berberine(BB) to form (AuI4-BB) association molecule. The molecules aggregate automatically owing to strong hydrophobic and molecular forces. And (AuI4-BB)n association nanoparticles with orange-yellow color were observed. It exhibits a resonance scattering peak at 520 nm. The absorption peak for the nanoparticle system and the [AuI4]- is at 350 nm. However, the absorbance values for the nanoparticle system increased in the visible light region. Under the conditions chosen, the BB concentration in the range of 0.8×10-6 mol·L-1-20×10-6 mol·L-1 is linear to the A450 nm value. The results show that the formation of (AuI4-BB)n nanoparticles produces the resonance scattering effect and the orange-yellow color.
|
|
Received: 2003-03-16
Accepted: 2003-08-06
|
|
|
|
Corresponding Authors:
JIANG Zhi-liang
|
|
| Cite this article: |
|
WANG Li-ｓheng,ZOU Jie-ming,JIANG Zhi-liang, et al. Absorption Spectra Study of the Association Nanoparticle System of Berberine-[AuI4]- and Its Analytical Application[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1640-1642.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2004/V24/I12/1640 |
[1] LIU Shao-ｐu，JIANG Zhi-ｌiang, KONG Ling. Science in China, Series B，2002，45(6)：614.
[2] JIANG Zhi-ｌiang, FENG Zhong-ｗei, LI Ting-ｓheng et al. Science in China, Series B，2001，44：175.
[3] QIN Ai-ｍiao，JIANG Zhi-ｌiang，ZOU Jie-ｍing, WANG Li-sheng(覃爱苗，蒋治良，邹节明，王力生). Chin J. Appl. Chem.(应用化学)，2002，19(12)：1150.
[4] JIANG Zhi-ｌiang, LIU Shao-ｐu, LIU Qing-ｙe(蒋治良，刘绍璞，刘庆业等). Chin. J. Appl. Chem.(应用化学)，2002，19(1)：22.
[5] JING Zhi-ｌiang, LIU Shao-pu, LIU Qing-ye. Spectrochimica Acta, 2002, 58B: 3121.
[6] CHI Jia-ｐing( 迟家平). Traditional Chinese Medicines Research(中成药研究)，1991，13(11)：17.
[7] GUO Jia-bing, ZHONG Rong(郭家兵，钟 荣). Journal of Guangｄong Medical College(广东医学院学报)，1998，16(3)：289.
[8] LIN Si-lan(林似兰). Acta Pharmaceutica Sinica(药学学报)，1989，24(1)：48.
[9] LIANG Sheng-wang, LIU Wei(梁生旺，刘 伟). The Quantitative Analysis of Traditional Chinese Medicinal Preparation(中药制剂定量分析). Beijing: Press of Traditional Medicine of China (北京：中国中医药出版社)，1997. 143.
[10] JIANG Zhi-liang, LIU Shao-pu, ZHAO Bao-gang, CHEN Sa, LI Jian(蒋治良，刘绍璞，赵保刚，陈 飒，李 键) Spectroscopy and Spectral Analysis (光谱学与光谱分析)，2002，22(4):615.
|
| [1] |
ZHANG Rong1, 2, DUAN Ning1, 3, JIANG Lin-hua1, 3*, XU Fu-yuan3, JIN Wei3, LI Jian-hui1. Study on Optical Path Optimization for Direct Determination of
Spectrophotometry of High Concentration Hexavalent Chromium
Solution by Ultraviolet Visible Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1829-1837. |
| [2] |
YAO Shan1, ZHANG Xuan-ling1, CAI Yu-xin1, HE Lian-qiong1, LI Jia-tong1, WANG Xiao-long1, LIU Ying1, 2*. Study on Distribution Characteristics of Different Nitrogen and
Phosphorus Fractions by Spectrophotometry in Baiyangdian
Lake and Source Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1306-1312. |
| [3] |
LIU Qin-rong1, DU Zi-wei1, LI Jia-zhen1, WANG Yi-shuo1, 3*, GU Xuan2, CUI Xiu-mei2. Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3618-3624. |
| [4] |
LI Zhen-xia1, SHEN Huan-huan1, GAO Miao-miao1, QI Jiao1, LI Qing-yan2*. Analysis of Lycopene in Different Solvents by Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(04): 1114-1117. |
| [5] |
YANG Ze-ming1, 2, LI Cai1*, LU Gui-xin1, CAO Wen-xi1. A Study of Fast Detection of Nitrite in Seawater Based on Sequential Injection Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 589-595. |
| [6] |
LINGYUN Xia-fei1, 2, GAO Chao1, 2, FAN Jing-shuang1, 2, Lü Hai-xia1, 2*, YU Yan1, 2. Synthesis of Hyperbranched Polyamidoamine (PAMAM) Grafted Chitosan and Its Adsorption for Heavy Metal and Dyes Studied with Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3583-3587. |
| [7] |
CHEN Jing1, 2, 4, PENG Jiao-yu1, 2, BIAN Shao-ju1, 3, GAO Dan-dan1, 3, DONG Ya-ping1, 2*, LI Wu1, 3. Optimization of Determination of CO2-3 and HCO-3 in Boron-Containing Brine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2194-2199. |
| [8] |
LI Yun1,2,3, ZHANG Ji1,2, LIU Fei4, XU Fu-rong3, WANG Yuan-zhong1,2*, ZHANG Jin-yu1,2,3*. Prediction of Total Polysaccharides Content in P. notoginseng Using FTIR Combined with SVR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1696-1701. |
| [9] |
WU Xin1，2, LI Guang-lin1*, WEN Zhi-yu3. Study and Determination the Concentration of CNO-Ion of the QPQ with the Sequential Injection Spectrophotometric Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1824-1828. |
| [10] |
CAO Xuan1, 2，ZHANG Shu-wei1, 2，CHU Dong-zhi1, 2，WU Ning1, 2，MA Hai-kuan1, 2，MA Ran1, 2. Development of Lab-on-Chip Spectrophotometric Silicate Sensor in situ Analysis of Seawater[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 895-900. |
| [11] |
HE Qiu-ju1，2, WANG Li-qin1*, ZHANG Ya-xu1. Study of Mechanism of Aluminum Sizing Precipitant on Xuan Paper Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 418-423. |
| [12] |
ZHU Hong-qiu, GONG Juan, LI Yong-gang*, CHEN Jun-ming. A Spectrophotometric Detecting Method of Trace Cobalt under High Concentrated Zinc Solution[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3882-3888. |
| [13] |
GONG Hong-ling1, LIU Yan-hui2*, TANG Yan-lin2*, HU Lin2. Effects of Temperature on DNA Condensation Detected with Temperature-Changed Ultraviolet Spectrum Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1831-1837. |
| [14] |
LIU Qian3, CHEN Wen-juan1,2, JING Bo1,2, ZHANG Jian1,2, YANG Meng-ying3, CHEN Wu3, YIN Xian-qing1,3*. Spectrum Analysis of Trace Hydrogen Peroxide in Electrochemical Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1656-1660. |
| [15] |
XIE Ying-ke1,2,3, WEN Qun1,2*, WEN Zhi-yu1,2, MO Zhi-hong1,2, WEI Kang-lin1,2. On-Line Determination of Chemical Oxygen Demand and Total Phosphorus in Water by Using Fenton Reagents via a Micro-Spectrometer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1642-1648. |
|
|
|
|
